File name: Pandora114s1_BuenosAires_20180528_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034859.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180528_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180528T105530.0Z 6722.455208 367 1 32.00 2 89.77 63.41 104.95 241.55 0.00 1 0.00 1 0 50 1.547e-01 1.363e-01 1.375e-01 1.313e-01 2.321128e+03 7.790418e+03 3.063493e+02 -6.000000e+00 8.488723e+03 284.02 -2.00 20.00 -2.00 505.32 0.00e+00 -1.718354e-03 3.557606e-03 1.338062e-04 -6.000000e+00 4.311952e-03 284.02 -2.00 20.00 -2.00 500.45 0.00e+00 -6.811700e-02 2.530384e+00 2.723891e-02 -6.000000e+00 3.041795e+00 224.46 -2.00 3.16 -2.00 502.06 0.00e+00 20.143 0.077 489.00 513.00 1 1.0070e+01 1.9368e-01 3.1076e-02 -6.0000e+00 2.3272e-01 9.4257e-02 5.0544e-02 1.6912e-03 -6.0000e+00 6.1433e-02 4.6937e-06 1.1774e-02 1.2426e-02 5.6791e-05 -6.0000e+00 1.5207e-02 2.9826e-02 -8.3582e-04 12 8 8 10 0 0 83.26 22.22 6.55 0.02983 0.11149 8 2 1 4 0 4000.000 26.21 20.00 22.22 4711 4712 4887 -5899 -1476 -1839 -9111 -4132 -7341 8109 1337 944 14092 8020 819 4943 20878 -7480 11765 7870 12156 6011 4408 4702 1699 23113 14811 31583 -15968 -25639 13806 -2816 4039 -5695 -1624 -15550 -24709 25294 -26786 1337 -4144 25833 1629 -3911 377 13239 13266 14404 3160 16966 3145 -7406 17652 19994 -10519 10122 -14819 8826 -3039 9041 -3095 -3796 5896 -10545 -18292 2426 -16560 34955 -5711 15937 5226 28377 -14906 3516 9736 -3097 2133 -6604 23746 -15797 -7522 -5632 -3183 25194 29755 39532 3219 7647 1183 -11930 30692 -6623 8418 26080 6514 -16085 -10187 26361 -3538 -3366 -2943 13088 -257 -11628 6006 -10205 48824 1565 21830 -3861 -9402 -15689 -17956 23067 16755 -9467 7006 387 8037 -12925 -14530 -6055 23290 20799 -5712 3736 -5977 -7835 5454 11351 16555 885 33511 -3379 3126 -5651 1688 50120 425 5146 -11260 -6152 -28222 3212 -1520 2128 6552 2760 -2374 22594 -2546 10152 51365 4114 4201 4492 -6236 -1533 -1961 -10635 -4633 -8502 7976 1388 971 12565 7519 821 4771 17463 -8526 11355 8029 11956 6299 4700 5014 1874 20608 13341 25547 -19041 -32773 11607 -2778 3777 -6058 -1713 -19210 -33492 20615 -36308 1353 -4409 20389 1649 -4227 395 12266 12291 13098 3172 14555 3022 -7687 13932 15266 -11009 8858 -17162 8253 -3233 8532 -3292 -4070 5766 -12212 -22911 2456 -20031 24890 -6026 13399 4842 20693 -16752 3318 8770 -3215 2105 -7025 18334 -17889 -7808 -5750 -3194 19236 21953 26792 3176 7282 1208 -13049 23434 -6925 8161 21479 6182 -19147 -11306 19929 -3528 -3276 -2793 10421 -234 -12064 5410 -11245 30629 1586 17908 -4036 -10284 -18297 -21662 18737 14688 -10888 6875 407 7886 -15697 -17880 -6769 19106 17230 -6110 3636 -6442 -8633 5264 10316 14246 890 24257 -3505 2992 -5818 1602 29426 417 4925 -12950 -6828 -39494 3307 -1650 2242 6640 2908 -2616 19080 -2544 9308 30984 SO 20180528T105939.0Z 6722.458090 371 1 32.00 2 89.01 62.82 105.66 240.87 0.00 1 0.00 1 0 36 1.192e-01 1.124e-01 9.571e-02 9.277e-02 2.388115e+03 5.668170e+03 1.997187e+02 -6.000000e+00 6.541437e+03 284.02 -2.00 20.00 -2.00 505.36 0.00e+00 1.849618e-03 2.493863e-03 1.135666e-04 -6.000000e+00 3.312168e-03 284.02 -2.00 20.00 -2.00 500.32 0.00e+00 5.039665e+00 1.804141e+00 3.434773e-02 -6.000000e+00 2.318844e+00 224.46 -2.00 3.16 -2.00 501.93 0.00e+00 18.670 0.061 489.00 513.00 1 9.4997e+00 1.3809e-01 2.8380e-02 -6.0000e+00 1.7784e-01 3.7013e-03 3.5186e-02 1.6857e-03 -6.0000e+00 4.6238e-02 6.7297e-06 7.3826e-03 8.7982e-03 5.1752e-05 -6.0000e+00 1.1714e-02 -2.6985e-02 4.0991e-04 12 9 8 11 8 0 -201.88 22.23 -1.37 -0.02698 0.02422 8 2 1 4 0 4000.000 26.21 20.00 22.23 -17847 8425 22490 11964 8282 -16685 220 4004 -366 19139 535 14413 -8823 6498 -11034 -2768 19394 2222 14818 -12193 6898 -10187 2796 5187 -1200 18189 14894 6376 -13042 -2534 -10456 -190 2728 -1422 17110 -11917 13516 -9322 5146 10203 7316 7522 -4963 10534 -16732 13500 6285 -9153 14290 -13919 19352 -6919 12656 -16923 -1157 2462 125 5343 -5262 13907 5136 -8417 7008 -8069 10652 -12594 11503 -58 2193 -302 -10157 -2553 -10734 13312 -21860 9097 197 8524 6933 -5349 -8493 2307 19083 16022 -632 5263 -10922 18338 -5858 -3086 12588 -2584 3608 588 15623 1192 42413 -13096 -2761 -25 -24001 27408 -14810 9590 -1224 13672 -11609 -10286 -7194 5909 -2534 -17642 5631 -6153 16541 5927 4881 5604 6140 25713 1042 9858 -2233 14358 -6632 -7988 -1209 -4712 22303 8393 1374 4371 3762 14428 -1255 11093 22044 5675 -6245 -9306 -7090 -19103 7476 9932 -8880 -1206 -910 35621 3528 12429 -22072 5922 5848 -20286 7607 18260 11113 8177 -21567 243 4265 -404 17155 570 13200 -10086 6331 -12828 -3002 17258 2410 14437 -14636 7349 -12042 2915 5314 -1317 16430 13815 6339 -15338 -2611 -11537 -191 2745 -1543 15766 -14738 12865 -11020 5210 9773 7229 7478 -5656 10409 -21909 13094 6515 -10932 13254 -16708 16190 -7341 10895 -19698 -1178 2493 133 5442 -5966 12984 5231 -9848 7053 -9441 10268 -15117 10669 -59 2167 -302 -11083 -2569 -11779 11622 -27432 8383 196 7648 6221 -5383 -8804 2154 15155 13210 -582 4607 -11298 14174 -5760 -2947 10302 -2482 3302 562 12875 1125 26034 -13695 -2542 -22 -26190 17758 -14814 7739 -1141 11267 -12404 -10757 -7196 5138 -2405 -19753 5089 -6365 13820 5558 4660 5351 5863 20167 1036 8853 -2233 12078 -6898 -8490 -1209 -4901 17746 7680 1351 4173 3592 12218 -1227 9520 17039 5257 -6673 -10472 -7938 -22992 7394 9653 -9880 -1252 -944 27128 3434 10837 -26683 5385 5380 SO 20180528T110338.0Z 6722.460856 375 1 32.00 2 88.28 62.24 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