File name: Pandora114s1_BuenosAires_20180617_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034825.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180617_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180617T110532.0Z 6742.462176 487 1 32.00 2 89.77 61.01 129.71 96.30 0.00 1 0.00 1 0 29 1.107e-01 1.076e-01 1.001e-01 9.662e-02 3.660877e+03 6.407292e+03 8.460990e+02 -6.000000e+00 6.050328e+03 283.06 -2.00 20.00 -2.00 505.25 0.00e+00 2.308286e-03 2.642601e-03 1.551792e-04 -6.000000e+00 3.074365e-03 283.06 -2.00 20.00 -2.00 499.85 0.00e+00 1.942173e+00 1.985446e+00 1.115757e-01 -6.000000e+00 2.172720e+00 224.19 -2.00 3.16 -2.00 501.52 0.00e+00 20.170 0.077 489.00 513.00 1 9.5425e+00 1.5217e-01 3.2074e-02 -6.0000e+00 1.6625e-01 1.2951e-01 3.9236e-02 1.9937e-03 -6.0000e+00 4.3774e-02 6.4767e-06 1.3074e-02 9.1384e-03 1.1816e-04 -6.0000e+00 1.0903e-02 6.6731e-02 -8.6580e-04 12 8 8 10 0 0 -48.73 20.36 12.08 0.06673 0.15742 8 2 1 4 0 4000.000 24.65 20.01 20.36 1308 -12821 11416 -3597 6784 -345 980 11791 -5954 23617 -434 6754 1610 -9487 106 -8751 5010 -21622 7044 13143 3992 16712 -17158 14646 -3991 13879 -2789 490 5955 -8257 20852 -5210 16989 -2176 28 7591 -5977 6632 -19440 5816 2636 -1530 1817 7238 17975 -8575 2092 -5040 -3354 6961 -14718 3382 -18962 25798 -8316 8207 -8233 12709 16611 1249 -702 -7781 23212 -1044 -2486 17141 -4462 21112 -20901 4463 -7830 6320 -3935 -3028 2607 -15755 1411 16038 2996 21498 4005 14091 -6378 10083 6658 1552 8245 15624 4424 1550 -5326 -6041 535 -4155 4607 14229 -5341 15478 -9474 28297 440 -5784 5353 -1008 13782 -12565 20437 -3934 1659 20102 -181 5174 -4085 9047 -14582 -7147 -6530 -5955 -183 -16809 8753 -15721 11707 6233 4949 3299 -19039 6892 -22112 1745 12181 7325 10292 -2647 19837 -6287 5559 -8359 5470 8172 -1645 11792 4187 10520 8387 8881 24481 -897 9112 -16146 6055 -13114 -3850 1310 -15179 10967 -4136 7206 -402 1141 12364 -7412 21568 -496 7082 1753 -11424 115 -9780 5321 -28670 7161 12697 4235 15617 -22534 14056 -4637 13495 -3187 535 6016 -9332 17247 -5593 14911 -2390 31 7860 -7057 6826 -25654 5912 2763 -1681 1951 7449 16798 -10504 2298 -5887 -3791 6944 -17749 3310 -22748 19710 -9084 7825 -9513 12117 15313 1340 -766 -9138 20079 -1154 -2779 15585 -4958 17863 -26526 4340 -8504 5906 -4075 -3135 2584 -17720 1416 13671 2678 16831 3485 11093 -6191 8356 5754 1424 7125 12578 3981 1432 -5265 -6044 507 -4181 4281 11960 -5375 12369 -9477 18928 380 -5239 4341 -889 10850 -13314 15848 -3889 1532 15231 -167 4563 -4014 7926 -16401 -7531 -6880 -6275 -183 -19900 7979 -18053 10048 5571 4453 3027 -21976 6160 -24885 1642 10311 6504 8834 -2554 15030 -6103 4772 -8313 4825 7159 -1522 10261 3732 8850 7242 7669 18140 -855 7767 -17361 5094 -13151 -3518 SO 20180617T110933.0Z 6742.464965 491 1 32.00 2 89.05 60.44 128.93 95.70 0.00 1 0.00 1 0 15 8.690e-02 8.502e-02 7.262e-02 7.065e-02 6.911892e+03 4.896917e+03 8.371095e+02 -6.000000e+00 4.754121e+03 283.06 -2.00 20.00 -2.00 505.25 0.00e+00 -1.192200e-04 1.916195e-03 4.922976e-05 -6.000000e+00 2.408936e-03 283.06 -2.00 20.00 -2.00 500.01 0.00e+00 -5.114900e-01 1.430317e+00 1.468339e-02 -6.000000e+00 1.684094e+00 224.19 -2.00 3.16 -2.00 501.64 0.00e+00 18.788 0.062 489.00 513.00 1 9.6333e+00 1.0905e-01 2.8398e-02 -6.0000e+00 1.2922e-01 1.6287e-01 2.8359e-02 1.6454e-03 -6.0000e+00 3.3418e-02 8.9603e-06 -1.0633e-02 6.5234e-03 9.7910e-05 -6.0000e+00 8.5181e-03 -3.6461e-02 7.6267e-04 12 9 8 11 8 0 -27.35 20.36 2.33 -0.03646 -0.11021 8 2 1 4 0 4000.000 24.65 20.01 20.36 2702 -10083 5929 -807 -5162 3356 -1077 2174 -12017 10638 -6181 -3100 2975 -8204 13221 -10241 7570 2167 9056 9961 -10776 2812 -2564 11546 -3207 9625 10501 4050 3291 -3114 -347 -4448 14133 11748 -12371 7910 -3263 5391 -8370 20371 -7530 5461 477 -12480 17815 -8615 8758 -13342 7279 9928 -13075 -278 -11334 12522 7493 2516 -6420 1573 1918 -6542 12768 4 -1700 774 12562 11287 -11335 -38 -7914 6181 -8115 4200 -3306 827 3665 7099 9774 11793 3944 7613 -6720 10256 -4746 9050 10056 7696 2027 -20823 9901 -3320 3345 -2172 21978 440 -1977 5357 -3815 -245 10778 20607 19715 -10898 7616 -18333 5957 -11114 10270 -1567 -2031 15169 -14536 1505 -9006 18737 8587 3522 -7661 -4386 5372 -9223 5119 9353 -3365 -1270 -3268 3036 -5514 3234 -1821 211 315 -8683 5640 53 5031 -7160 8829 -10374 8770 -858 -7142 2064 -3178 10752 5996 2753 9402 -3505 -10336 -6117 3262 9504 -3781 2673 -11570 5982 -898 -6154 3752 -1278 2516 -15990 11155 -7552 -3618 3223 -9166 12687 -11630 7304 2261 9031 9979 -13332 3038 -2924 11460 -3702 9776 10520 4282 3433 -3364 -356 -4723 12658 11118 -15363 8143 -3751 5625 -9893 17868 -8691 5547 513 -15441 16449 -10420 8895 -16754 7326 9534 -15392 -280 -12453 10753 6849 2486 -7143 1649 2019 -7490 12025 4 -1860 829 11947 10786 -13396 -39 -8768 5878 -8804 3994 -3388 821 3587 6360 8503 9902 3517 6458 -6544 8434 -4560 7638 8487 6728 1895 -24604 8613 -3291 3098 -2133 17122 431 -1994 4985 -3815 -230 8817 14894 14079 -10424 6065 -19360 5131 -11833 9068 -1567 -2022 12540 -16043 1420 -9550 15245 7805 3384 -8256 -4594 5139 -10259 4919 8501 -3408 -1236 -3211 2799 -5561 2996 -1773 189 281 -8453 4733 47 4377 -6533 7261 -9804 7402 -765 -6895 1841 -3016 8935 5252 2501 8004 -3383 -10568 -5880 2791 7511 -3404 SO 20180617T111340.0Z 6742.467824 495 1 32.00 2 88.32 59.84 128.12 95.09 0.00 1 0.00 1 0 15 5.261e-02 5.017e-02 5.407e-02 5.327e-02 6.303154e+03 3.534213e+03 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