File name: Pandora114s1_BuenosAires_20180622_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T034856.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180622_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180622T110648.0Z 6747.463056 459 1 32.00 2 89.77 60.95 140.36 190.66 0.00 1 0.00 1 0 36 1.497e-01 1.324e-01 1.214e-01 1.160e-01 7.168328e+03 7.644897e+03 7.280026e+02 -6.000000e+00 8.178960e+03 282.92 -2.00 20.00 -2.00 505.22 0.00e+00 -9.243364e-05 3.187966e-03 1.478176e-05 -6.000000e+00 4.149516e-03 282.92 -2.00 20.00 -2.00 500.17 0.00e+00 -2.900857e+00 2.284340e+00 1.010023e-02 -6.000000e+00 2.922127e+00 224.35 -2.00 3.16 -2.00 501.80 0.00e+00 20.170 0.077 489.00 513.00 1 1.0109e+01 1.7514e-01 3.0957e-02 -6.0000e+00 2.2388e-01 1.9326e-01 4.5755e-02 1.7913e-03 -6.0000e+00 5.8467e-02 5.3687e-06 9.4048e-03 1.1041e-02 7.3148e-05 -6.0000e+00 1.4721e-02 1.0692e-01 -6.2279e-04 12 8 8 10 0 0 61.57 20.70 8.14 0.10692 0.17215 8 2 1 4 0 4000.000 24.96 20.00 20.70 -2314 -11313 19209 20933 -489 4948 -11957 -1343 11165 2696 2674 2758 -15478 10253 2829 -6494 3057 -11287 14367 5581 15027 10223 707 2470 -8886 7499 15355 -229 7659 -6480 2040 -10964 21061 -17697 5112 427 -1763 7242 -16510 -1207 -15832 12571 -140 -1811 17271 -23613 13672 -5252 33191 -5936 11360 16883 -24951 36705 -9350 11344 -5069 -5805 14609 6567 25938 4841 5390 15809 7455 7926 3421 4314 -16312 32513 -12995 3416 -5592 -485 29968 -19905 -7466 897 30274 2663 -4938 11370 4060 4337 -17957 38800 -10092 -7729 -13538 8048 -12730 -1915 -617 -2302 13862 -368 33280 18187 -18829 12488 -5480 -1353 -5203 -5451 39064 14600 10559 -4761 6663 -5160 11609 42099 -333 19808 -18696 10374 -16371 27677 -5453 -1479 -6947 -9979 -35 4923 7413 4588 -5106 7947 -15038 28871 -10109 -16248 23278 -17142 29549 -16655 -5587 8863 9133 6064 16331 4658 -2539 38120 -10921 7152 1152 15667 8407 52 34832 -8872 -17059 -2369 -13051 16854 18537 -548 5346 -15445 -1560 11338 2935 2868 2913 -19365 9828 2919 -7439 3254 -13265 14240 5670 14894 9922 755 2603 -10511 7506 14088 -241 7259 -6878 1964 -12138 17407 -22276 5233 460 -1925 7139 -20406 -1272 -19328 11629 -148 -1977 15715 -32407 12855 -5893 24915 -6436 10078 13826 -30648 24492 -10138 10322 -5573 -6515 13403 6523 21241 4919 5476 14504 7405 7753 3450 4252 -19542 23667 -14780 3290 -5936 -497 22950 -23630 -8265 898 22266 2564 -4809 10087 3665 3946 -20679 27361 -10976 -8242 -15302 7323 -14298 -1946 -627 -2406 12318 -371 23421 14480 -21148 10031 -5181 -1222 -4956 -5386 25825 12766 9758 -5110 6299 -5428 10316 27831 -341 16756 -23391 9735 -20132 22035 -6086 -1587 -7803 -11350 -36 4655 6797 4338 -5336 7288 -17317 21344 -10994 -17611 17871 -18235 20585 -18232 -5480 7623 7986 5561 13698 4437 -2463 26285 -11618 6364 1087 12683 7199 48 21906 -8547 -17919 SO 20180622T111054.0Z 6747.465903 463 1 31.99 2 89.04 60.36 140.49 189.14 0.00 1 0.00 1 0 29 8.511e-02 8.261e-02 6.733e-02 6.615e-02 8.049421e+03 4.367045e+03 5.097252e+02 -6.000000e+00 4.649632e+03 282.92 -2.00 20.00 -2.00 505.26 0.00e+00 -6.077529e-04 1.780300e-03 7.547672e-05 -6.000000e+00 2.361161e-03 282.92 -2.00 20.00 -2.00 500.33 0.00e+00 8.134159e-02 1.286761e+00 6.555527e-02 -6.000000e+00 1.667857e+00 224.35 -2.00 3.16 -2.00 501.93 0.00e+00 18.752 0.062 489.00 513.00 1 9.5248e+00 9.8383e-02 2.8876e-02 -6.0000e+00 1.2767e-01 9.2442e-02 2.5434e-02 2.1121e-03 -6.0000e+00 3.3527e-02 9.6583e-06 8.7074e-03 6.0755e-03 6.5502e-05 -6.0000e+00 8.3805e-03 1.5604e-01 -1.2252e-03 12 9 8 11 8 0 -231.69 20.70 -5.99 0.15604 0.21644 8 2 1 4 0 4000.000 24.96 20.01 20.70 7830 -17316 4020 -3690 18273 2111 -4674 1513 6626 9911 -11470 5382 6914 3231 13945 -3613 10447 -9673 7604 -7822 5162 -3593 -11209 22334 -5689 6624 -3231 2732 -2025 101 372 -1969 -1799 -7891 3982 1796 -199 714 -11848 7924 -11447 11307 -1355 7185 13458 -2272 17802 -2365 7 -915 3592 5343 -7810 13888 -11788 4944 4725 1847 5769 2341 -214 -8775 7225 -16707 1947 4796 8155 6191 -3529 8350 -210 7178 -11454 6365 -367 -7482 14310 -10391 3108 -16566 -7640 -259 3998 981 -5355 12022 -8466 8585 2186 -6424 11755 -5092 14311 -4737 24164 -7297 -565 6060 -4100 900 -6235 -3776 -3034 6653 2355 -4474 11421 -183 16073 -13812 -2461 8094 -5997 5901 -10442 5945 2248 495 2925 -3270 7297 -3706 12245 9200 -2083 15170 -4130 6691 -10047 2473 -6350 -4221 -4321 -8995 17559 -8660 19831 -6951 9126 3106 4415 8332 253 12783 2089 -8267 -3816 2204 4290 -2150 1157 -16031 12393 6999 -20450 3966 -4050 16502 2288 -5132 1570 6502 9296 -13139 5141 6425 3087 11935 -3717 9528 -11081 7494 -9095 5288 -4023 -13566 19404 -6566 6757 -3617 2846 -2162 103 370 -2009 -1874 -9039 4165 1941 -218 769 -14289 7775 -13607 10753 -1476 7267 12914 -2563 16391 -2637 7 -969 3540 5035 -8237 11766 -13146 4809 4738 1940 5860 2458 -230 -9673 6822 -20108 1941 4606 7468 5695 -3532 7342 -199 6283 -12115 5700 -357 -7883 12062 -11033 2834 -18193 -7647 -241 3597 918 -5403 10328 -9023 7758 2109 -6742 10289 -5303 12411 -5029 19291 -7896 -558 5452 -3971 809 -5913 -3459 -2779 5688 2195 -4659 10413 -188 13939 -15952 -2523 7511 -6489 5739 -12060 5854 2305 519 2845 -3404 6819 -3816 11215 8035 -2018 12382 -4112 5997 -10653 2311 -6466 -4202 -4285 -9228 13595 -8621 14824 -6866 7831 2890 4125 7595 253 11360 2080 -9176 -4061 2202 4156 -2181 1112 -18037 10493 SO 20180622T111503.0Z 6747.468785 467 1 31.99 2 88.30 59.76 140.60 187.59 0.00 1 0.00 1 0 15 4.357e-02 4.306e-02 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