File name: Pandora114s1_BuenosAires_20180705_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040736.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180705_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180705T110706.0Z 6760.463264 370 1 32.00 2 89.77 61.80 41.07 315.82 0.00 1 0.00 1 0 145 7.425e-01 4.268e-01 6.587e-01 4.745e-01 -7.943367e+04 2.266131e+04 2.396868e+03 -6.000000e+00 4.101961e+04 282.57 -2.00 20.00 -2.00 505.31 0.00e+00 1.907462e-02 1.384052e-02 5.146781e-04 -6.000000e+00 2.077418e-02 282.57 -2.00 20.00 -2.00 500.90 0.00e+00 2.398958e+01 9.080537e+00 1.138778e+00 -6.000000e+00 1.482418e+01 224.75 -2.00 3.16 -2.00 502.35 0.00e+00 20.174 0.077 489.00 513.00 1 9.3651e+00 7.1878e-01 8.8788e-02 -6.0000e+00 1.1331e+00 -2.5805e-01 1.6177e-01 1.5969e-02 -6.0000e+00 2.9599e-01 1.1294e-06 1.2005e-01 1.6848e-02 5.7043e-04 -6.0000e+00 7.4597e-02 2.7670e-01 -2.7175e-04 12 13 8 11 8 0 71.40 20.96 2.69 0.27670 1.10942 8 2 1 4 0 4000.000 25.17 20.01 20.96 33062 -19910 29577 -34539 -51801 61493 61875 57515 140650 94021 1863 68430 -19329 39255 7636 6267 -11602 -13594 218567 25644 112436 23866 92684 4316 -30861 -6510 -5027 40727 2044 34776 -12478 1642 150880 24235 123382 55994 900000 20045 52396 24386 19122 -1060 -13963 -35838 5024 9222 18192 77594 -13523 58669 -10878 -13619 91549 154418 98190 -29941 -1356 24485 147526 3667 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-50681 39995 -2284 -6029 -8956 -29749 84262 17671 30968 690 -21409 10335 -80725 9728 -9485 20848 13362 47212 -10232 9161 900000 -14943 62571 34563 -15235 -81644 5911 49222 42126 28760 12135 37062 25545 -19638 25516 5231 9539 3043 -7637 18099 36126 -13319 -51654 13742 88943 55631 -44419 -18969 30787 59830 36550 -3408 900000 47519 43704 84761 -8749 47072 -4617 -41228 37634 33334 54885 -38114 173269 71360 36106 38563 35667 20550 77301 -15267 37172 65429 22686 -9835 24533 -83506 14397 -95155 29151 37483 -33609 14888 900000 900000 SO 20180705T111107.0Z 6760.466053 374 1 32.00 2 89.05 61.23 41.66 314.61 0.00 1 0.00 1 0 38 8.026e-01 4.192e-01 5.970e-01 4.090e-01 7.817375e+04 4.231983e+04 5.263529e+03 -6.000000e+00 4.446243e+04 282.57 -2.00 20.00 -2.00 505.28 0.00e+00 2.408793e-03 1.118716e-02 1.772989e-04 -6.000000e+00 2.280969e-02 282.57 -2.00 20.00 -2.00 499.75 0.00e+00 -1.672537e+01 8.926196e+00 1.236015e-01 -6.000000e+00 1.623519e+01 224.75 -2.00 3.16 -2.00 501.46 0.00e+00 18.777 0.062 489.00 513.00 1 1.2362e+01 6.7420e-01 3.0105e-02 -6.0000e+00 1.2447e+00 4.3111e-01 1.7780e-01 4.7732e-03 -6.0000e+00 3.2665e-01 1.2954e-06 -2.0460e-02 2.1279e-02 2.4613e-04 -6.0000e+00 8.0978e-02 1.3640e-01 -1.7542e-03 12 8 8 10 0 0 -148.87 20.96 16.52 0.13640 -0.00552 8 2 1 4 0 4000.000 25.17 20.01 20.96 900000 11297 -21588 -660 -13299 107884 2523 78258 58170 5969 383821 -43964 85865 12007 156801 49068 27082 9528 -35321 -2476 -36366 35721 46012 79358 -14514 -29085 89857 79382 217532 -9704 61850 1039 51690 42544 -29493 372263 -27073 51590 8730 -10321 26018 10992 37711 -10143 58104 -9822 89719 30244 -20334 900000 10275 900000 180883 83933 7104 -30668 45428 21573 31151 9160 60206 30044 -6213 153234 -29858 900000 -3057 91613 -9876 -30312 33177 10639 81812 -10246 173203 -16697 1021 35811 -41774 44637 78257 172664 95627 94379 13370 6284 115467 38576 154208 39094 67270 21932 -2500 148311 6987 32230 34361 17428 -22958 76388 73712 25524 129518 -43327 108163 -26232 10849 18761 -11837 67528 -33909 72375 30100 900000 12297 -11217 25558 -12514 94236 -16962 68887 49027 5719 900000 -46283 219192 -17249 47655 34696 7054 22106 -40387 98026 31118 7901 14114 -34324 3791 -31311 3182 -3036 107825 144617 51321 57554 -11804 14830 -8200 148720 48170 38094 -32615 39758 900000 11960 -31505 -793 -18647 46306 3177 47026 43277 7516 153760 -89320 46683 13400 62815 36506 24798 10360 -60642 -3117 -65558 31686 36865 45416 -21181 -49102 46282 45430 87144 -12440 40705 1220 35498 31652 -42534 149130 -40490 38382 9327 -13231 22930 11155 29207 -12731 37243 -12591 43130 26655 -29869 900000 10976 900000 72463 40348 7209 -45048 31544 19589 26622 10031 40198 27281 -8131 61386 -50237 900000 -4000 46487 -13715 -51002 29240 11650 43699 -13682 69386 -24080 1255 31561 -80327 35763 43890 69170 43416 42850 13569 6881 46257 31937 61776 33411 43118 21672 -3072 59414 7651 27544 28448 16291 -27591 32641 29529 15678 51885 -48816 43330 -26272 8149 14562 -13929 38887 -56035 41678 26377 900000 12931 -14885 23037 -15979 40111 -21659 37945 34371 6443 900000 -86911 87809 -21594 29829 24324 6535 17711 -60672 39270 22594 7121 11662 -44689 3322 -39198 2868 -2965 43195 57934 29554 31703 -13300 12996 -9033 59578 28946 24799 -42463 24886 SO 20180705T111512.0Z 6760.468889 378 1 32.00 2 88.31 60.64 42.26 313.42 0.00 1 0.00 1 0 56 6.056e-01 3.745e-01 5.635e-01 3.965e-01 7.079071e+04 3.999612e+04 1.687020e+03 -6.000000e+00 3.377798e+04 282.57 -2.00 20.00 -2.00 505.02 0.00e+00 -9.041782e-03 1.071696e-02 5.960156e-04 -6.000000e+00 1.716481e-02 282.57 -2.00 20.00 -2.00 499.90 0.00e+00 -2.201632e+01 8.474041e+00 6.387577e-01 -6.000000e+00 1.230839e+01 224.75 -2.00 3.16 -2.00 501.46 0.00e+00 16.892 0.045 489.00 513.00 1 1.3165e+01 6.3516e-01 5.6899e-02 -6.0000e+00 9.4768e-01 5.2123e-01 1.6880e-01 1.0870e-02 -6.0000e+00 2.4438e-01 1.3992e-06 -2.1931e-02 1.9138e-02 2.5600e-04 -6.0000e+00 5.9997e-02 2.1512e-01 -1.7579e-03 12 9 8 11 8 0 -16.62 20.96 16.14 0.21512 0.06300 8 2 1 4 0 4000.000 25.17 19.99 20.96 68849 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