File name: Pandora114s1_BuenosAires_20180708_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040718.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180708_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180708T110632.0Z 6763.462870 403 1 32.00 2 89.77 62.20 46.39 9.97 0.00 1 0.00 1 0 57 6.671e-01 3.564e-01 5.543e-01 3.833e-01 3.472020e+03 2.597048e+04 2.120305e+03 -6.000000e+00 3.691201e+04 282.49 -2.00 20.00 -2.00 505.11 0.00e+00 -9.567536e-03 1.053622e-02 6.197803e-04 -6.000000e+00 1.855288e-02 282.49 -2.00 20.00 -2.00 499.82 0.00e+00 5.988670e+00 8.025055e+00 1.928206e-01 -6.000000e+00 1.308296e+01 224.85 -2.00 3.16 -2.00 501.49 0.00e+00 20.172 0.077 489.00 513.00 1 1.0714e+01 6.1341e-01 3.7769e-02 -6.0000e+00 1.0001e+00 2.2499e-02 1.6453e-01 4.6488e-03 -6.0000e+00 2.6206e-01 1.4544e-06 -9.8812e-02 3.4024e-02 4.1525e-04 -6.0000e+00 6.5853e-02 1.8252e-02 -1.3315e-04 12 12 8 10 0 0 -138.40 20.96 26.87 0.01825 -0.66715 8 2 1 4 0 4000.000 25.17 20.00 20.96 106951 -29921 26235 54601 35661 -28043 58622 81129 -9455 18114 38990 -27929 22335 274708 -14087 189656 46653 8727 -26185 40726 22402 -1055 66361 34714 9568 74163 16591 12341 -39994 17041 6027 121999 45505 5923 71096 -29663 -20055 5816 122323 6679 14071 47211 -23956 -10216 -15253 22953 35634 -18285 44365 5231 105141 -30562 16377 91933 113680 -9147 38883 -7123 14806 25593 -9593 62316 -37426 -4981 24822 -22651 218331 38900 108313 12808 -20096 68683 -20801 117992 78538 900000 20932 -13084 6116 2057 108573 -17693 -3024 34655 5621 38407 24087 90474 -37463 20072 301753 -8088 30566 -14250 61962 -295 900000 -27760 -7831 -34907 25142 120115 -1662 62729 -9253 17122 35376 124341 -13257 1949 63812 3748 109626 -1745 4029 -8629 21677 10638 30997 14558 65287 -5952 -28545 -3294 71123 74 22192 70337 34464 127897 -9449 9308 -56944 50558 -24383 54341 119573 46521 119477 45571 179321 -7643 102223 -16840 47257 29958 -38485 37370 48752 49983 21501 -8083 13652 43046 -47368 23231 35162 26792 -39127 34605 39184 -11670 17497 31386 -44964 22174 103195 -20412 71245 36303 9836 -41454 32783 21639 -1303 42735 31670 11553 47759 19143 14902 -81558 19661 7763 49103 39073 7470 45784 -47543 -30673 6867 45951 8244 16613 40537 -38997 -14328 -22155 22418 32509 -26560 36903 6026 47960 -50515 16815 46869 45754 -11454 29213 -8206 13348 20510 -11051 35894 -59985 -5863 21757 -31766 82016 29226 40688 12509 -27176 37842 -27609 44324 37370 900000 17299 -15073 5820 2061 40786 -22154 -3256 25169 5349 25970 18700 36253 -54416 16588 113354 -9115 23730 -17486 35690 -318 900000 -39627 -9218 -54200 21408 45121 -1790 34561 -10196 14151 23921 46709 -13695 1784 35158 3696 41181 -1885 4068 -9725 17812 9741 23288 12988 35255 -6568 -39541 -3558 36737 78 18757 36330 25084 48045 -10427 8523 -101608 30862 -31486 31896 44918 29490 44882 28888 67362 -8075 38400 -19769 29957 23211 -60538 28077 33193 34032 19687 -10059 13783 SO 20180708T111040.0Z 6763.465741 407 1 32.00 2 89.02 61.61 46.27 8.60 0.00 1 0.00 1 0 42 6.426e-01 2.900e-01 3.943e-01 2.780e-01 -9.965779e+03 1.558876e+04 6.290457e+02 -6.000000e+00 3.509639e+04 282.49 -2.00 20.00 -2.00 505.15 0.00e+00 8.240774e-03 7.566686e-03 4.749366e-04 -6.000000e+00 1.781567e-02 282.49 -2.00 20.00 -2.00 500.18 0.00e+00 3.594014e+00 5.569662e+00 9.104442e-02 -6.000000e+00 1.255801e+01 224.85 -2.00 3.16 -2.00 501.77 0.00e+00 18.716 0.061 489.00 513.00 1 1.0574e+01 4.2699e-01 3.1187e-02 -6.0000e+00 9.6183e-01 9.4705e-02 1.1112e-01 2.0676e-03 -6.0000e+00 2.5144e-01 2.1003e-06 1.5490e-02 2.6222e-02 1.8308e-04 -6.0000e+00 6.3254e-02 -4.6423e-02 1.1686e-03 12 9 8 11 8 0 -1386.54 20.96 -2.36 -0.04642 0.06102 8 2 1 4 0 4000.000 25.17 20.00 20.96 42173 5843 14116 5295 15802 73251 -11979 191686 5245 44073 53664 -1010 -20614 -11592 68750 10503 22476 36983 3203 17754 14087 217102 -4934 -5902 -27726 -15591 33931 10011 19337 6571 36151 21012 -6194 -22807 -30304 28946 44328 -12007 -21745 -24828 48479 35436 -10890 480 23421 -24697 27519 10217 -18737 14447 18412 68114 -49301 72156 788 15064 41083 -12756 48435 -8453 254473 -7681 11243 8608 5419 26423 2094 247503 15838 -6867 44364 7106 -4023 -19849 24521 -31120 70833 53242 -20918 56024 -45869 27212 45193 51144 48462 109616 86205 -20876 35294 -25485 34984 -2656 2988 -17782 4332 8009 -13025 180918 -5975 29544 -5176 -11442 29552 15450 45108 -28730 1332 3371 4911 57893 -8997 123401 -21953 90468 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-9973 38231 -7924 10676 25156 -5358 16634 -15294 36123 -430 34159 32629 4577 -10045 4211 32786 -15415 15351 -6621 -27957 -6210 -116 20951 27262 33869 15298 900000 SO 20180708T111442.0Z 6763.468542 411 1 32.00 2 88.29 61.03 46.17 7.27 0.00 1 0.00 1 0 22 3.554e-01 2.654e-01 2.931e-01 2.406e-01 1.467036e+04 1.723483e+04 1.816825e+03 -6.000000e+00 1.939752e+04 282.49 -2.00 20.00 -2.00 505.15 0.00e+00 2.459348e-03 6.532388e-03 1.556999e-04 -6.000000e+00 9.851414e-03 282.49 -2.00 20.00 -2.00 500.37 0.00e+00 -5.429919e+00 4.725045e+00 4.381839e-02 -6.000000e+00 6.963078e+00 224.85 -2.00 3.16 -2.00 501.88 0.00e+00 16.839 0.045 489.00 513.00 1 1.1409e+01 3.5820e-01 2.5353e-02 -6.0000e+00 5.3313e-01 1.9841e-01 9.5003e-02 1.6658e-03 -6.0000e+00 1.3964e-01 2.4806e-06 -1.2037e-02 2.0843e-02 3.0071e-04 -6.0000e+00 3.5019e-02 -5.7595e-02 2.1403e-04 12 8 8 10 0 0 97.09 20.96 5.58 -0.05760 -0.14109 8 2 1 4 0 4000.000 25.17 20.00 20.96 -7410 -14761 82686 -13599 42320 -2563 6922 68649 13573 14706 -17943 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