File name: Pandora114s1_BuenosAires_20180714_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040706.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180714_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180714 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180714T110437.0Z 6769.461539 480 1 32.00 2 89.77 63.22 103.99 77.06 0.00 1 0.00 1 0 15 1.978e-01 1.551e-01 1.683e-01 1.544e-01 -3.436352e+03 8.963791e+03 3.086498e+02 -6.000000e+00 1.079167e+04 282.32 -2.00 20.00 -2.00 505.27 0.00e+00 1.496038e-03 4.192585e-03 6.631737e-05 -6.000000e+00 5.472085e-03 282.32 -2.00 20.00 -2.00 500.15 0.00e+00 6.599974e+00 3.017145e+00 3.128432e-02 -6.000000e+00 3.836989e+00 225.03 -2.00 3.16 -2.00 501.78 0.00e+00 20.177 0.077 489.00 513.00 1 9.6890e+00 2.3144e-01 3.1081e-02 -6.0000e+00 2.9430e-01 2.0414e-02 5.8484e-02 1.8364e-03 -6.0000e+00 7.6116e-02 3.9752e-06 8.3827e-03 1.4630e-02 4.5464e-05 -6.0000e+00 1.9384e-02 -6.2513e-03 6.0087e-04 12 9 8 11 8 0 96.98 21.27 0.24 -0.00625 0.05189 8 2 1 4 0 4000.000 25.39 19.99 21.27 9022 51264 -17431 -4903 -768 1820 9580 14658 2121 3713 -5341 -22871 5501 11744 -365 15418 -8103 -5728 -16890 42466 17839 -3547 2427 -3344 19393 -26183 22457 9433 6556 22417 -10987 40318 8553 25726 -3234 5548 5429 -15780 446 3063 29727 -2099 24560 -18754 27252 11773 -5101 13224 -9801 18218 -23656 -2900 -11098 -43 -1208 -11229 -2461 -15675 -2219 -10484 -18597 14713 -3949 9136 18926 2380 21426 9433 18458 26017 21077 -4892 49656 2160 -9883 17883 -11452 -2603 4789 15001 -18513 13168 8969 -14125 22627 -7182 11163 4502 1274 -14998 -3058 -4869 -5307 4862 156 21725 12242 -14578 35345 -18436 19913 -14806 10124 -14067 20199 56659 -1202 -7785 -7324 16529 -22238 5334 -4785 3160 1684 -16985 14872 5584 13709 13893 1041 -2092 -11134 6485 18492 33323 -8116 -4186 39820 -10246 27971 -21681 53130 5679 26674 103765 -14247 4897 -6184 19028 2782 -11349 4225 7811 8694 -14838 44320 -16533 -20841 33562 14154 2060 889 8193 31591 -22049 -5619 -864 2026 9943 14421 2339 3974 -6178 -31155 5590 11173 -395 14502 -9899 -6998 -23373 32597 17550 -4333 2808 -4121 19079 -37780 21122 9233 6417 19631 -12528 30076 8458 22065 -3753 5878 5698 -20222 482 3214 23997 -2351 21313 -25358 23374 11761 -5971 12677 -11571 15809 -30315 -2956 -12206 -43 -1255 -13257 -2707 -19771 -2441 -12483 -24020 13658 -4423 8942 16615 2425 17728 8661 15273 19689 16589 -4986 29562 2093 -10870 14797 -12480 -2548 4301 12109 -20923 10896 7783 -15536 17352 -7464 9687 4180 1222 -16950 -3085 -5061 -5623 4710 159 17756 10871 -15583 23896 -19532 14128 -14846 8045 -14638 15286 30015 -1126 -7659 -7067 12509 -25033 4642 -4708 2929 1609 -19763 12662 5230 11801 11828 995 -2038 -11797 5766 14694 23012 -8522 -4237 25991 -11049 20639 -26252 30156 5104 19177 34356 -15499 4493 -6494 15840 2763 -13098 4196 7537 8389 -18247 30187 -20488 -26418 24129 12184 2007 891 SO 20180714T110844.0Z 6769.464398 484 1 32.01 2 89.02 62.63 103.20 76.55 0.00 1 0.00 1 0 22 1.005e-01 9.284e-02 9.959e-02 9.732e-02 1.043349e+04 6.820054e+03 4.591121e+02 -6.000000e+00 5.480200e+03 282.32 -2.00 20.00 -2.00 505.33 0.00e+00 5.583220e-03 2.666626e-03 3.111729e-04 -6.000000e+00 2.781738e-03 282.32 -2.00 20.00 -2.00 500.33 0.00e+00 1.070989e+00 1.939711e+00 1.218303e-01 -6.000000e+00 1.963776e+00 225.03 -2.00 3.16 -2.00 501.94 0.00e+00 18.714 0.061 489.00 513.00 1 9.7644e+00 1.4890e-01 3.0747e-02 -6.0000e+00 1.5042e-01 7.7008e-02 3.7758e-02 2.6998e-03 -6.0000e+00 3.9263e-02 6.4553e-06 -1.1059e-03 9.0058e-03 1.1222e-04 -6.0000e+00 9.8821e-03 -2.4100e-02 2.1368e-04 12 8 8 10 0 0 -340.74 21.26 -0.48 -0.02410 -0.03177 8 2 1 4 0 4000.000 25.39 20.00 21.26 9360 -3080 8905 1575 -7764 1801 -3452 6591 2967 1651 -2543 -4095 1581 -234 -896 -14829 2084 -7058 -3632 8504 -6203 3632 -7639 -1188 7763 -1177 3563 35964 3257 -2820 -9008 582 -3626 -1035 -3925 2551 6944 411 3706 -3790 6236 -608 89 9839 11312 -77 -7116 5572 -2275 7532 2570 -4400 -10012 7262 5182 20301 21134 -15216 13687 -7269 10494 -4837 -10707 13118 -1556 37691 -4763 6818 4091 369 18159 -15051 -14142 -14483 -8234 12778 3205 -9677 -6922 4967 -2253 -501 6443 -1606 27466 -11339 2048 -8041 14296 -7147 27211 2474 10234 11732 -3905 -14500 5373 -3288 863 -7015 -1954 6473 14097 -8663 -7543 -2781 6590 7474 -1476 3885 -1625 1119 -12520 -417 -3814 10628 -9077 702 16379 9405 -6266 -2872 7986 12141 -7513 831 6626 11923 8322 7839 24612 11041 18323 -18704 -4589 4072 -11322 -1154 -3026 8204 -9082 -1614 -15851 11104 1949 2364 12879 -7643 8461 5431 -13083 11399 -5446 8035 -3064 8130 1599 -8887 1915 -3928 6826 3174 1766 -2790 -4492 1616 -241 -922 -17580 2116 -8031 -4083 8576 -6785 3860 -8501 -1247 7504 -1250 3603 26072 3210 -2870 -9509 555 -3666 -1053 -4243 2628 6845 428 3700 -4049 6028 -634 93 9511 10935 -84 -8371 5740 -2503 7376 2583 -4617 -10887 6604 4877 16912 18010 -19063 12969 -8506 10277 -5537 -13073 12680 -1742 28284 -5391 6763 4111 380 15474 -17707 -16457 -17039 -9216 11701 3220 -10893 -7439 4675 -2264 -494 5941 -1513 20785 -11965 1905 -8293 11762 -7244 20765 2272 8786 10072 -3957 -16251 4837 -3136 767 -6566 -1700 5094 10254 -8057 -7195 -2636 5854 6640 -1426 3520 -1550 1047 -13659 -411 -3933 9568 -10012 708 14257 8859 -6911 -3031 7428 10640 -7928 807 6123 10520 7641 7244 19222 9873 15185 -22191 -4651 3739 -12082 -1121 -3049 7533 -10071 -1684 -18144 10393 2010 2295 11273 -8191 7643 4967 -14095 9466 -5348 SO 20180714T111254.1Z 6769.467292 488 1 32.13 2 88.26 62.03 102.40 76.03 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