File name: Pandora114s1_BuenosAires_20180715_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040658.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180715_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180715 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180715T110413.0Z 6770.461262 479 1 32.01 2 89.77 63.41 113.86 87.73 0.00 1 0.00 1 0 22 1.294e-01 1.195e-01 1.256e-01 1.202e-01 5.367359e+03 8.357398e+03 3.516766e+02 -6.000000e+00 7.056997e+03 282.30 -2.00 20.00 -2.00 505.31 0.00e+00 -1.179124e-03 3.343433e-03 1.972200e-04 -6.000000e+00 3.581706e-03 282.30 -2.00 20.00 -2.00 499.92 0.00e+00 3.255650e+00 2.441722e+00 9.445690e-02 -6.000000e+00 2.527362e+00 225.06 -2.00 3.16 -2.00 501.61 0.00e+00 20.174 0.077 489.00 513.00 1 9.7120e+00 1.8834e-01 3.2155e-02 -6.0000e+00 1.9361e-01 9.1867e-02 4.6508e-02 2.4108e-03 -6.0000e+00 5.0502e-02 5.1752e-06 1.7792e-02 1.1083e-02 7.0402e-05 -6.0000e+00 1.2729e-02 4.2672e-02 -1.4961e-04 12 8 8 10 0 0 60.15 21.28 17.22 0.04267 0.16609 8 2 1 4 0 4000.000 25.39 20.01 21.28 13223 1670 -2346 -9215 77 21199 1560 12125 -13578 -1224 3553 -19354 -9009 15267 -7934 11802 -4035 7161 -17219 3565 17778 9851 1295 -9108 -11647 41615 1319 17183 -7328 7158 14790 522 8446 -3998 10912 16931 -903 -10268 2518 -9735 -12737 6862 -6483 6432 -5243 1318 -6681 13113 -5136 -14757 15567 21028 14721 15282 -14734 -6525 10326 8360 23665 9410 3157 -4579 -11869 1809 -6464 32879 27042 -9091 -12477 -1824 9011 22290 11816 8751 -6382 11517 -2716 -18467 -12688 -3227 4411 -1744 15821 12093 -8948 -9498 11826 1700 -87 5597 -10944 -7122 12340 -11318 27981 -23479 16357 -4737 8345 2633 10870 3797 4558 -881 -1766 -9897 23417 21356 20957 -19590 34460 -11711 19529 -8035 18285 3419 -10643 -4316 18612 1648 14247 -3626 -13026 22433 571 -7929 10643 -5301 -10433 9647 -1020 -626 -1798 12750 1243 12481 -17194 8603 -11483 4401 28012 -13061 4689 15090 -11532 -2390 9402 8420 1924 -6777 12226 9745 -17422 11801 1730 -2608 -11249 88 19810 1786 12454 -17832 -1402 3828 -25907 -10770 14267 -9418 11724 -4824 7837 -22730 4111 17811 10698 1537 -11236 -14734 32933 1441 15662 -8292 6862 13133 545 8428 -4650 11061 16097 -1015 -12505 2671 -11627 -15713 7010 -7642 6722 -6179 1450 -7874 12468 -5731 -17625 13333 16688 12377 12968 -17366 -7281 9899 8212 19897 9095 3250 -5109 -14269 1891 -7263 24543 21036 -10001 -14020 -1821 8001 17340 10306 7977 -6820 10226 -2732 -21330 -13659 -3144 3986 -1685 12929 10357 -8965 -9656 10407 1553 -80 4906 -11367 -7188 10363 -12089 21327 -27500 12531 -4362 6578 2153 8087 3049 3727 -791 -1665 -10353 17595 16204 15746 -21935 22592 -12336 15249 -8346 14682 3199 -11525 -4419 15219 1590 11964 -3579 -13913 16691 530 -8061 9017 -5272 -10913 8243 -969 -591 -1695 10238 1108 9930 -18619 7352 -12266 4085 20841 -14818 4490 13117 -13167 -2500 8727 7815 1871 -6625 10357 7973 -18964 SO 20180715T110817.0Z 6770.464086 483 1 32.02 2 89.02 62.83 113.06 87.20 0.00 1 0.00 1 0 15 9.814e-02 9.223e-02 8.416e-02 8.182e-02 7.158682e+03 5.493021e+03 2.976280e+02 -6.000000e+00 5.351371e+03 282.30 -2.00 20.00 -2.00 505.17 0.00e+00 1.485916e-03 2.216705e-03 1.109508e-04 -6.000000e+00 2.715401e-03 282.30 -2.00 20.00 -2.00 500.03 0.00e+00 -2.437060e+00 1.654917e+00 8.402233e-02 -6.000000e+00 1.912626e+00 225.06 -2.00 3.16 -2.00 501.64 0.00e+00 18.727 0.061 489.00 513.00 1 9.9104e+00 1.2644e-01 2.9130e-02 -6.0000e+00 1.4657e-01 2.0269e-01 3.3147e-02 2.1741e-03 -6.0000e+00 3.8140e-02 7.7134e-06 -8.4892e-03 7.8474e-03 3.9254e-05 -6.0000e+00 9.6431e-03 6.7494e-02 -1.6633e-04 12 8 8 10 0 0 77.59 21.27 2.45 0.06749 0.00861 8 2 1 4 0 4000.000 25.47 20.01 21.27 -1172 11816 -4277 9051 -2703 4918 -561 -15553 13914 4654 15608 -9365 4612 1686 -10242 3554 -11325 24897 9837 1302 6759 -5581 9890 814 5204 -4410 4439 -2965 -2998 14588 6618 -3512 -8783 9359 1808 -4229 -2763 -6995 10997 -11589 -4071 -8110 -7741 1146 -4949 10932 1706 10905 -7488 -7981 18628 4052 9216 -8796 25436 2226 11473 245 -7862 9300 -8334 4487 -6338 -2566 -2980 -4069 9004 -9672 15849 -8473 8287 4547 -1053 21534 -8892 2379 1363 -3533 6447 -4146 4470 -18312 2144 -3494 22654 3348 -8818 -10080 -4662 17098 -11714 7268 -17188 -3961 2508 -2772 1060 610 20149 -4763 -3783 -8134 5724 3245 -4843 4064 166 23935 10042 -15611 9463 -11383 22955 -1153 19774 -437 10320 -8718 -9915 1413 7907 11609 11392 -260 -5689 -3018 9732 -7839 24148 11481 -5103 10707 -18141 -521 3081 2570 -4360 9066 8065 -278 2879 347 10038 -2333 8669 -169 -12127 -389 -7854 3606 6843 19825 -12003 -1208 10897 -4777 9125 -3143 5409 -662 -21472 14268 5172 15289 -11588 4888 1815 -11500 3477 -13018 21821 9572 1400 6902 -6445 9783 884 5426 -5069 4651 -3313 -3285 13025 6227 -3623 -9674 8857 1904 -4816 -3103 -8115 10524 -13755 -4462 -9279 -8898 1219 -5663 10754 1843 10670 -8687 -9132 15935 3899 8229 -9312 19311 2189 10612 260 -9122 9099 -9713 4606 -7286 -2853 -3330 -4569 8762 -11169 13981 -9422 7709 4352 -1064 17500 -9315 2404 1305 -3506 5687 -4011 3943 -20285 1945 -3380 17033 3088 -9282 -10813 -4744 13969 -12741 6557 -19988 -4090 2451 -2848 1030 581 15351 -4536 -3489 -7705 4705 2781 -4660 3728 163 18715 8959 -17762 8300 -12324 17834 -1156 16254 -443 9415 -9657 -11182 1431 7491 10474 10107 -254 -5788 -2980 8487 -8173 18276 9840 -4839 9177 -19427 -462 2749 2267 -4087 7453 6792 -259 2641 311 8240 -2179 7279 -155 -12586 -358 -7707 3096 5553 13842 -11438 SO 20180715T111226.0Z 6770.466968 487 1 32.01 2 88.27 62.24 112.24 86.67 0.00 1 0.00 1 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