File name: Pandora114s1_BuenosAires_20180716_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040700.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180716_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180716T110346.0Z 6771.460949 479 1 32.00 2 89.77 63.62 122.63 99.81 0.00 1 0.00 1 0 26 2.407e-01 1.946e-01 1.895e-01 1.688e-01 4.377305e+03 1.169257e+04 2.373104e+02 -6.000000e+00 1.312232e+04 282.28 -2.00 20.00 -2.00 505.27 0.00e+00 -2.804741e-04 4.697970e-03 2.229029e-04 -6.000000e+00 6.675822e-03 282.28 -2.00 20.00 -2.00 499.62 0.00e+00 4.759583e+00 3.523204e+00 9.592754e-02 -6.000000e+00 4.736851e+00 225.10 -2.00 3.16 -2.00 501.34 0.00e+00 20.177 0.077 489.00 513.00 1 9.9135e+00 2.7079e-01 3.2135e-02 -6.0000e+00 3.6225e-01 8.4316e-02 6.8696e-02 2.1213e-03 -6.0000e+00 9.5525e-02 3.6019e-06 -1.1743e-02 1.5760e-02 8.3975e-05 -6.0000e+00 2.3703e-02 6.1616e-02 -9.0500e-04 12 9 8 11 8 0 -78.37 20.95 26.47 0.06162 -0.01984 8 2 1 4 0 4000.000 25.17 20.00 20.95 -7645 28155 -11659 36086 5273 2637 -11517 -18183 21416 4940 2107 15828 -8312 7533 -16131 13687 -14065 27809 -1914 11017 568 -3432 20445 -14413 29305 -28915 54198 1242 -8658 23475 -18953 13253 -19553 13049 28216 -19857 -4318 -3116 39800 17030 55785 12825 10567 30199 8778 10812 -22466 30174 12934 1183 -4636 -7205 51842 -21065 25615 -11233 6723 -3174 -3885 -2842 -8518 27145 -2519 49046 -3109 -7943 40585 -3341 59372 -12595 21481 -3501 -7842 -8446 -16867 43780 2662 83864 -12030 38307 -27737 10961 30420 20269 7658 28840 5612 -14843 -15213 42572 8275 38801 -37546 44530 -9873 -13763 15615 -2011 17294 -12067 60935 -475 -16944 -6707 6867 45970 8735 38980 -4126 31741 14940 -15344 45465 5899 6161 -2575 -6808 10220 -4685 9016 -19408 50867 10096 -7660 -3073 -16254 22239 7371 -7452 -36203 33969 15652 5866 22214 -7850 41533 25921 22234 19724 -12554 -949 1166 42358 -5097 16701 -10106 4498 -2057 -37258 6067 -487 40068 24938 -8584 21961 -13779 27294 5609 2961 -15244 -26216 21007 5721 2490 16087 -10609 8101 -21732 13587 -18450 24320 -2307 11978 699 -4421 20779 -19396 27360 -45289 39712 1439 -10983 21233 -25505 12572 -25450 12378 23653 -27816 -5287 -3780 31169 16530 36303 12731 10723 25315 9198 11211 -32710 25960 13125 1331 -5421 -8424 32594 -26720 20060 -12762 6526 -3501 -4414 -3229 -10241 22756 -2834 33000 -3532 -9462 29546 -3721 34709 -14865 17771 -3669 -8476 -9130 -19906 28491 2642 37001 -13667 25774 -35490 9430 21475 15873 6842 20995 5200 -15963 -16518 27705 7576 26107 -50862 28488 -10312 -15086 12756 -1934 13413 -12229 30918 -408 -16821 -5965 5397 25194 7226 24588 -4053 21663 11896 -16343 26328 5124 5415 -2503 -6970 8877 -4748 8018 -23080 29982 8874 -7921 -2987 -17817 16558 6403 -7552 -49042 22832 12624 5217 16769 -7955 25340 18227 16094 14685 -13112 -903 1109 27157 -5324 14162 -11287 4372 -2148 -52217 5834 -493 26517 18825 SO 20180716T110747.0Z 6771.463738 483 1 32.01 2 89.03 63.05 121.84 99.20 0.00 1 0.00 1 0 15 7.621e-02 7.369e-02 7.132e-02 7.010e-02 5.924985e+03 4.613038e+03 3.018566e+02 -6.000000e+00 4.153906e+03 282.28 -2.00 20.00 -2.00 505.24 0.00e+00 6.107753e-04 1.894508e-03 4.941661e-05 -6.000000e+00 2.109020e-03 282.28 -2.00 20.00 -2.00 500.13 0.00e+00 9.551908e-01 1.387795e+00 6.545968e-02 -6.000000e+00 1.490285e+00 225.10 -2.00 3.16 -2.00 501.76 0.00e+00 18.750 0.062 489.00 513.00 1 9.5088e+00 1.0599e-01 2.8793e-02 -6.0000e+00 1.1412e-01 1.0867e-01 2.7317e-02 2.0024e-03 -6.0000e+00 2.9839e-02 9.1018e-06 3.2498e-03 6.5331e-03 3.1202e-05 -6.0000e+00 7.4957e-03 1.6401e-01 -1.0088e-03 12 8 8 10 0 0 -144.53 20.96 -5.08 0.16401 0.18655 8 2 1 4 0 4000.000 25.28 20.00 20.96 -2883 3712 1741 -3861 -12068 1869 -3954 5838 -7683 -9787 8924 -12261 11649 -269 -2823 639 -5668 6979 -2612 5622 1554 -42 8793 -8956 -3533 -1144 9002 -6990 4443 184 6562 6285 -2346 10928 -7618 -1521 10897 -1494 9955 -7157 4422 -7603 13731 -2707 10740 2441 11359 9403 -89 11197 -9519 -1692 3345 -8164 -6371 4169 15602 -1035 3306 4485 -13390 3244 -10835 14019 6332 1850 5225 -5867 -1291 -7567 12492 -1639 6973 6123 -4629 1795 -3665 25411 -2329 -11192 2190 -898 -6096 -5717 13765 -998 5839 3918 1653 -2534 1894 -699 7686 4327 -9008 -3365 4298 1723 1404 3811 7384 -8864 -3250 8204 -12518 1955 2303 7447 -8709 7920 -1277 -8177 5757 -7794 14379 2145 13517 -1044 18247 82 -9826 9164 -5562 434 -310 4840 929 4814 16936 -11954 4094 -456 -2239 -10945 -5176 9348 -14011 5713 -1483 -306 -3285 3148 19610 -6310 -2176 -2074 -2231 6690 4710 -668 -8987 -3914 -4715 -2972 3680 1820 -4396 -14262 2101 -4456 5990 -8974 -11521 8584 -14378 10619 -273 -2935 647 -6231 6938 -2919 5846 1687 -46 8902 -10872 -4079 -1289 9113 -8196 4538 190 6252 6017 -2504 10562 -9108 -1728 10881 -1669 9804 -8295 4558 -8881 13083 -3075 10774 2673 11342 9476 -97 10668 -10857 -1736 3202 -8751 -6829 4144 14222 -1134 3483 4663 -15583 3204 -12376 13357 6091 1843 4958 -6123 -1270 -7831 10461 -1570 6139 5496 -4692 1719 -3683 18769 -2230 -11583 1975 -837 -6021 -5671 11350 -964 5316 3651 1576 -2514 1797 -685 6997 4125 -9864 -3454 4005 1605 1278 3306 6057 -8450 -2945 6799 -13278 1864 2235 6875 -9350 7108 -1251 -8638 5365 -8435 12596 2137 12074 -1085 15750 80 -10564 8540 -5553 402 -286 4265 856 4281 13348 -12562 3657 -426 -2118 -11148 -4895 7557 -14271 4826 -1372 -285 -3213 2927 15614 -6554 -2181 -2088 -2254 6165 4378 -642 -9190 -3749 -4555 SO 20180716T111549.0Z 6771.469317 491 1 32.01 2 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