File name: Pandora114s1_BuenosAires_20180723_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T040852.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180723_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180723 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180723T105959.0Z 6778.458322 400 1 32.01 2 89.76 65.25 123.33 207.43 0.00 1 0.00 1 0 27 9.764e-02 9.212e-02 9.306e-02 9.037e-02 8.460659e+02 5.388174e+03 3.063197e+02 -6.000000e+00 5.326535e+03 282.22 -2.00 20.00 -2.00 505.33 0.00e+00 -1.870534e-03 2.439412e-03 1.548803e-04 -6.000000e+00 2.705504e-03 282.22 -2.00 20.00 -2.00 500.13 0.00e+00 3.998569e+00 1.800666e+00 5.247081e-02 -6.000000e+00 1.914297e+00 225.42 -2.00 3.16 -2.00 501.79 0.00e+00 20.164 0.077 489.00 513.00 1 9.3898e+00 1.3754e-01 3.1355e-02 -6.0000e+00 1.4651e-01 6.2174e-02 3.5539e-02 1.7806e-03 -6.0000e+00 3.8442e-02 6.9540e-06 2.9639e-03 8.4916e-03 6.1390e-05 -6.0000e+00 9.6216e-03 -1.9057e-02 8.2947e-04 12 8 8 10 0 0 95.76 20.14 4.79 -0.01906 0.00150 8 2 1 4 0 4000.000 24.46 20.00 20.14 -5481 -3400 23314 -7227 -9726 1845 5097 6257 -12489 9539 -8352 -2408 -3387 6314 14703 1361 -2191 12664 -7457 -4357 -2089 721 3765 10409 -1684 2671 8462 -24887 14150 13121 25325 -14018 4703 2183 -35 893 3112 -9606 3468 8146 3583 -5014 2873 4332 14756 1257 -7529 -8129 8570 16099 -3636 33410 14025 -5134 -15341 412 -7037 5253 -2300 8309 -10560 -3467 -4332 -1850 -8105 3772 -279 9273 4814 14205 11893 6450 7336 4243 -854 -12871 -6870 -4134 41 12909 2888 -2116 -3101 4650 3183 4776 1678 10155 4475 5256 3307 6121 4275 -6306 -3813 6024 7907 14375 -8178 -5652 2976 -17671 38847 12246 5972 -18658 -2136 -3961 -7145 12042 4109 19295 -5239 2882 2089 -3402 5000 -744 -3310 8039 -3531 -15838 -652 11722 -11139 9490 7334 12490 -16157 -8653 -2631 11546 7377 -4218 11097 2405 931 -3921 -419 2718 -7076 309 3251 9696 -6759 -5658 3220 9102 16389 7406 92 -17874 900000 -5722 -3592 19469 -8412 -11875 2042 5514 6690 -15959 9655 -9986 -2681 -3772 6351 13673 1473 -2355 12899 -8806 -5016 -2356 792 4024 10449 -1909 2886 8544 -34385 12866 11776 20038 -16720 4804 2359 -40 991 3344 -11571 3624 8081 3723 -5714 3054 4578 14114 1373 -8891 -9504 8299 14069 -3757 23278 11759 -5275 -17935 424 -7937 5273 -2486 8046 -12346 -3787 -4783 -1988 -9189 3741 -283 8432 4519 11994 10182 5827 6627 4008 -857 -14515 -7180 -4125 38 10671 2643 -1921 -2867 4015 2819 4204 1533 8544 3988 4655 3002 5455 3928 -6493 -3821 5402 6828 11379 -7922 -5225 2487 -18194 23224 9897 5323 -21689 -2105 -3925 -7199 9932 3685 15060 -5307 2728 2012 -3484 4733 -749 -3426 7387 -3597 -17973 -628 9928 -11901 8300 6577 10647 -18335 -9100 -2607 9906 6534 -4133 9215 2170 860 -3885 -410 2633 -7225 315 3048 9124 -7114 -5925 3087 8156 13405 6483 85 -19835 900000 SO 20180723T110359.0Z 6778.461100 404 1 32.01 2 89.02 64.68 123.68 206.42 0.00 1 0.00 1 0 8 7.161e-02 6.943e-02 7.506e-02 7.387e-02 2.547763e+02 4.154682e+03 1.665089e+02 -6.000000e+00 3.905590e+03 282.22 -2.00 20.00 -2.00 505.26 0.00e+00 1.847479e-03 1.999154e-03 5.411437e-05 -6.000000e+00 1.980458e-03 282.22 -2.00 20.00 -2.00 500.24 0.00e+00 5.801089e-01 1.466402e+00 4.273337e-02 -6.000000e+00 1.390739e+00 225.42 -2.00 3.16 -2.00 501.86 0.00e+00 18.713 0.061 489.00 513.00 1 9.5955e+00 1.1222e-01 2.8443e-02 -6.0000e+00 1.0665e-01 1.2519e-01 2.9101e-02 1.6321e-03 -6.0000e+00 2.7606e-02 8.5741e-06 -3.3296e-03 7.0627e-03 3.8919e-05 -6.0000e+00 7.0191e-03 -8.4530e-03 5.7942e-04 12 8 8 10 0 0 -22.10 20.13 -11.41 -0.00845 -0.03155 8 2 1 4 0 4000.000 24.46 20.00 20.13 296 -3529 -4063 -6256 -1167 1692 3366 -3613 -9447 -3587 -3354 -2501 944 11848 4642 16858 -12517 6870 -7218 6725 -123 8380 -2982 4709 81 -1299 -2362 5399 -4526 -2910 3616 7653 -1355 7310 -1388 6716 -3856 3526 -10394 -2919 8991 -4454 4866 7536 6644 7997 -2360 -4327 7780 -6520 4787 9982 -6775 -2832 2208 5783 -4717 -1426 24347 -4700 1015 -6594 17691 -10879 9751 15366 -6754 -5679 -4738 -3140 4535 922 6878 1483 -1956 -7320 -5058 6295 650 -1163 -10256 13355 284 1054 952 -536 7110 1962 12254 -4554 11468 -13377 -10350 1728 6367 14658 -7367 -1177 408 -5725 -4097 6947 4855 1061 10487 -15284 6247 156 -1373 4106 3972 15557 -12160 6628 -5566 -666 -896 6845 1134 10611 -4176 -33 3566 1583 3817 2398 -837 5923 -2531 -1386 7996 4422 8187 -8292 7999 -1799 6932 -10575 474 4333 -6478 -5880 -14291 -1030 -5358 -3154 549 9876 13903 -5669 2131 -8779 2859 291 -3705 -4434 -7184 -1304 1873 3708 -4279 -11776 -4155 -3817 -2781 1000 11152 4681 15171 -14380 6666 -8223 6720 -131 8252 -3296 4842 88 -1423 -2600 5421 -4894 -3006 3439 7019 -1393 7128 -1514 6808 -4318 3625 -12142 -3142 8594 -4902 4933 7530 6767 8068 -2631 -4867 7623 -7207 4598 8866 -6999 -2816 2131 5555 -5169 -1535 20333 -5241 1068 -7512 15884 -13023 9461 13944 -7531 -6168 -5031 -3244 4290 899 6341 1460 -2020 -7520 -5035 5865 591 -1069 -10304 10637 259 963 879 -507 6274 1829 10314 -4534 9756 -14711 -11194 1682 5965 12604 -7802 -1150 384 -5596 -3856 5784 4152 965 8969 -17361 5767 152 -1335 3735 3613 12743 -13372 6149 -5919 -681 -925 6567 1155 9797 -4422 -33 3389 1519 3576 2290 -829 5495 -2554 -1380 7237 4142 7336 -8123 6950 -1702 5991 -10360 450 4040 -6428 -5861 -15582 -987 -5386 -3117 524 8539 11369 -5505 1869 -8488 2472 SO 20180723T110758.0Z 6778.463866 408 1 32.00 2 88.28 64.11 124.02 205.41 0.00 1 0.00 1 0 15 6.316e-02 6.211e-02 5.424e-02 5.344e-02 -3.608815e+03 3.016226e+03 8.711856e+01 -6.000000e+00 3.443384e+03 282.22 -2.00 20.00 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