File name: Pandora114s1_BuenosAires_20180811_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042742.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180811_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180811T104341.0Z 6797.447002 457 1 32.00 2 89.76 71.25 92.01 70.92 0.00 1 0.00 1 0 25 6.706e-01 3.950e-01 5.789e-01 3.868e-01 -5.423861e+03 2.070472e+04 1.542642e+03 -6.000000e+00 3.679606e+04 282.05 -2.00 20.00 -2.00 504.97 0.00e+00 2.289944e-02 1.038705e-02 1.743585e-03 -6.000000e+00 1.863055e-02 282.05 -2.00 20.00 -2.00 500.47 0.00e+00 3.337856e+00 7.629301e+00 3.538181e-01 -6.000000e+00 1.343263e+01 226.28 -2.00 3.16 -2.00 501.84 0.00e+00 20.154 0.077 489.00 513.00 1 1.0442e+01 5.8556e-01 5.7719e-02 -6.0000e+00 1.0241e+00 1.0555e-01 1.5230e-01 4.1820e-03 -6.0000e+00 2.7259e-01 1.4211e-06 -2.1872e-03 3.1452e-02 6.5647e-04 -6.0000e+00 6.5994e-02 2.0116e-01 -2.1254e-03 12 8 8 10 0 0 -525.67 21.25 -27.06 0.20116 0.18599 8 2 1 4 0 4000.000 25.39 20.01 21.25 900000 19472 935 64894 -15126 113713 -6805 98352 23504 122064 31050 22760 139065 59180 57682 48626 37382 22099 -11045 63842 -45548 37436 -13882 157947 138985 -14804 -20909 -16871 20250 -11965 98735 142793 63028 26928 99316 149448 -9833 22984 86057 42998 27018 51114 -17997 -7819 168379 47199 55730 56704 -5482 34198 -63240 17756 31407 224379 29459 64570 100397 -53887 45511 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48792 39236 47287 42477 -17411 6793 -51932 44361 11102 -8219 27330 -22207 48713 -52150 42708 -40844 23605 17374 32643 39025 -64118 900000 -37517 55703 14370 14529 13696 -80226 35761 -50929 52856 3677 -4294 62851 -23818 11639 -29292 7525 -46645 51154 41819 -30834 -991 -7378 31163 33745 11383 10778 18375 9658 -3524 42914 23906 42944 8678 40168 39428 24645 34621 -8144 44351 38887 45089 37900 22508 17245 26406 34574 -29431 49294 22423 5581 28532 35780 2011 40384 9878 44271 24554 32065 -22971 -71174 -38807 37632 11351 2124 SO 20180811T104740.0Z 6797.449769 461 1 32.00 2 88.98 70.68 91.26 70.39 0.00 1 0.00 1 0 40 4.908e-01 2.906e-01 4.802e-01 3.600e-01 3.377072e+04 3.263700e+04 1.284724e+03 -6.000000e+00 2.678949e+04 282.05 -2.00 20.00 -2.00 505.39 0.00e+00 -3.504320e-03 1.001234e-02 3.202919e-04 -6.000000e+00 1.366149e-02 282.05 -2.00 20.00 -2.00 500.46 0.00e+00 -2.222383e+00 7.291915e+00 6.217684e-01 -6.000000e+00 9.650444e+00 226.28 -2.00 3.16 -2.00 502.11 0.00e+00 18.628 0.060 489.00 513.00 1 1.1368e+01 5.6153e-01 5.3975e-02 -6.0000e+00 7.3878e-01 9.5983e-02 1.3832e-01 8.8387e-03 -6.0000e+00 1.9392e-01 1.5722e-06 -2.0857e-02 2.7814e-02 3.6048e-04 -6.0000e+00 4.9553e-02 1.4664e-01 7.5621e-04 12 9 8 11 8 0 91.37 21.25 10.41 0.14664 0.00197 8 2 1 4 0 4000.000 25.39 20.00 21.25 5076 900000 53290 -21045 -24157 48779 -4078 -6032 45620 37721 18812 4947 900000 -19867 -9519 53498 35417 -19615 -708 28721 -17020 4543 -13084 44559 -1178 4696 49906 -32655 45352 -9464 35823 -33479 50848 209 -25195 105890 32811 34504 17171 48769 -7622 -10857 -17191 110849 62906 105372 16565 -2653 20834 52466 45981 -3761 23434 182693 43422 -9926 -25636 -12499 -14270 68519 28146 34416 9160 41126 -2064 -23526 -10704 22027 111312 86790 -16410 14441 26380 50339 -2273 205593 11915 5137 3493 -25638 -32745 2580 70641 76921 25010 -29230 -3261 -16732 44863 22982 17467 900000 -38493 47394 -18081 19873 -19796 14727 104799 26680 6914 66528 25044 58407 3569 60178 11051 3223 -1494 30635 30719 4621 37125 -11708 61982 61117 23518 2117 114540 -5534 -4173 170695 -2060 44273 -29368 -49436 -16519 128073 -17833 47749 1254 25054 13035 66831 96629 56 -343 41399 -30670 16977 18787 62528 -5044 42369 -3525 14393 9397 -23864 -18593 12853 19045 900000 900000 4859 900000 33556 -28623 -34681 34401 -4931 -7444 33322 29453 17532 5234 900000 -26520 -11508 35034 28546 -28160 -856 26043 -24434 5263 -18125 34791 -1453 5441 36453 -53462 33126 -11680 27971 -49583 35860 253 -37314 45340 28924 29548 17299 35622 -9138 -13527 -23036 44672 38449 45118 15966 -3057 18612 35680 30266 -3978 18730 64421 29602 -11900 -36762 -15866 -18451 38658 23820 27508 9475 30937 -2377 -33183 -13085 19159 39251 38765 -20445 13240 21705 33135 -2565 72497 11484 5192 3530 -34354 -46957 2608 36534 37973 21166 -43290 -3756 -22026 31640 19990 16014 900000 -62438 32310 -22952 16351 -22803 11425 36954 17561 5526 29715 17662 31580 3382 36782 10716 3409 -1646 24306 24373 4787 27819 -14192 35516 35021 19696 2240 40389 -6586 -4874 60191 -2224 29272 -40129 -82803 -20023 45161 -22009 30518 1272 19878 11491 33876 36203 56 -348 28284 -43936 15340 16976 37207 -6003 31748 -4196 14274 9733 -34186 -24996 12464 17209 900000 900000 SO 20180811T105142.0Z 6797.452569 465 1 32.00 2 88.20 70.11 90.50 69.85 0.00 1 0.00 1 0 22 2.966e-01 2.210e-01 3.030e-01 2.594e-01 -7.068407e+03 1.380365e+04 1.329012e+03 -6.000000e+00 1.617223e+04 282.05 -2.00 20.00 -2.00 505.24 0.00e+00 1.532649e-04 6.987537e-03 4.618207e-04 -6.000000e+00 8.211483e-03 282.05 -2.00 20.00 -2.00 500.26 0.00e+00 -3.804283e-01 5.039811e+00 1.253865e-01 -6.000000e+00 5.810647e+00 226.28 -2.00 3.16 -2.00 501.91 0.00e+00 16.594 0.043 489.00 513.00 1 1.1249e+01 3.8103e-01 2.7310e-02 -6.0000e+00 4.4482e-01 1.3901e-01 1.0160e-01 1.6371e-03 -6.0000e+00 1.1646e-01 2.3072e-06 -6.9504e-04 2.5326e-02 4.0127e-04 -6.0000e+00 2.9199e-02 2.4950e-02 6.8321e-04 12 9 8 11 8 0 -420.20 21.25 -11.82 0.02495 0.02013 8 2 1 4 0 4000.000 25.39 19.99 21.25 15858 -18710 -23866 -20028 -5162 -520 4985 -9045 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