File name: Pandora114s1_BuenosAires_20180812_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042738.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180812_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180812T104237.0Z 6798.446262 456 1 32.00 2 89.76 71.62 101.19 82.05 0.00 1 0.00 1 0 43 4.986e-02 4.886e-02 4.907e-02 4.859e-02 2.004261e+03 2.914142e+03 2.217067e+02 -6.000000e+00 2.717059e+03 282.04 -2.00 20.00 -2.00 505.30 0.00e+00 1.264701e-03 1.317366e-03 5.702858e-05 -6.000000e+00 1.379679e-03 282.04 -2.00 20.00 -2.00 500.29 0.00e+00 3.277694e+00 9.453763e-01 3.687142e-02 -6.000000e+00 9.782138e-01 226.33 -2.00 3.16 -2.00 501.91 0.00e+00 20.154 0.077 489.00 513.00 1 8.7603e+00 7.2488e-02 3.1106e-02 -6.0000e+00 7.4874e-02 5.1314e-02 1.8525e-02 1.8551e-03 -6.0000e+00 1.9611e-02 1.3256e-05 1.8077e-02 4.5994e-03 2.9351e-05 -6.0000e+00 4.9107e-03 5.9820e-02 -4.6005e-04 12 8 8 10 0 0 34.31 21.28 8.48 0.05982 0.18521 8 2 1 4 0 4000.000 25.47 20.00 21.28 -1378 4423 898 -4890 1674 4331 -3639 5025 -4828 6121 290 11780 8646 1056 -2954 -8513 -313 -2634 916 -1809 -3347 -2844 -4645 5561 -977 465 1333 -901 5588 -3405 -3877 -999 705 2371 2542 -676 -1893 687 -551 1226 -4797 -152 10862 -7537 309 4689 3608 704 501 1894 -4579 -5327 -215 958 -10066 7670 1330 -769 10563 3756 5062 676 3991 1206 1598 4470 -5798 -2316 -5929 11458 -500 -977 129 -8158 -3636 -10465 4951 1797 10003 -4202 -1303 -3000 -2278 4679 -2988 8180 2131 -851 4 -3952 1401 2429 2291 2163 -5698 817 -724 -3859 -958 12274 11 -5449 2818 -2381 -1338 11047 4463 -9 5205 1597 -6046 212 -9516 7624 -301 3453 10910 4443 6584 -3038 2674 -9214 186 -7584 -5020 -3439 1460 3499 -2305 -2918 -3402 212 -5530 8342 -3795 -6408 152 4143 3362 -1379 5069 4398 -5353 9307 9108 2769 -4646 4098 -3968 -10384 1569 7352 2256 -1369 4289 931 -5155 1690 4332 -3974 5026 -5274 5909 293 10473 7852 1029 -3011 -9325 -324 -2860 975 -1987 -3741 -3170 -5295 5757 -1083 506 1426 -967 5465 -3557 -4050 -1031 739 2522 2744 -753 -2115 739 -595 1296 -5407 -165 10691 -9022 344 5002 3860 764 535 1942 -4871 -5582 -212 946 -11410 7501 1415 -842 10330 3679 4897 686 3932 1220 1598 4285 -6057 -2302 -6036 9686 -471 -925 121 -8475 -3647 -11214 4480 1647 8337 -4015 -1210 -2849 -2163 4179 -2909 7183 1998 -823 4 -3941 1331 2306 2209 2112 -6021 800 -707 -3802 -896 9829 9 -5109 2474 -2275 -1310 9767 4224 -9 4772 1507 -6191 207 -10424 7149 -291 3240 10165 4182 6087 -3081 2532 -9680 175 -7691 -4979 -3382 1374 3235 -2260 -2877 -3374 203 -5547 7175 -3636 -6265 140 3737 3127 -1371 4800 4238 -5729 8657 8548 2785 -5038 4041 -4169 -11375 1499 6612 2161 SO 20180812T104637.0Z 6798.449039 460 1 32.00 2 88.98 71.05 100.40 81.53 0.00 1 0.00 1 0 15 3.088e-02 3.159e-02 3.407e-02 3.383e-02 1.196778e+04 2.383758e+03 8.282713e+02 -6.000000e+00 1.682656e+03 282.04 -2.00 20.00 -2.00 505.35 0.00e+00 -1.878354e-04 9.315644e-04 4.696562e-05 -6.000000e+00 8.535303e-04 282.04 -2.00 20.00 -2.00 500.52 0.00e+00 1.283918e+00 6.642038e-01 7.475834e-02 -6.000000e+00 6.020862e-01 226.33 -2.00 3.16 -2.00 502.12 0.00e+00 18.615 0.060 489.00 513.00 1 8.7590e+00 5.1106e-02 2.8828e-02 -6.0000e+00 4.6137e-02 4.5190e-02 1.2772e-02 2.4543e-03 -6.0000e+00 1.1993e-02 1.9265e-05 -1.2511e-03 3.0163e-03 9.2587e-05 -6.0000e+00 3.0313e-03 1.0131e-01 -2.9314e-04 12 8 8 10 0 0 89.73 21.28 1.56 0.10131 0.09263 8 2 1 4 0 4000.000 25.47 20.01 21.28 10 4140 -866 -2155 2130 1135 2114 -2472 3891 4472 -1272 -3370 -2785 154 -1102 807 -570 -2516 -722 1589 -1163 2739 2179 -820 3104 6717 298 -13255 207 5099 2996 1913 -1246 -4715 2820 1089 6213 -1856 -562 -886 -1555 241 1052 3 -4642 -544 -845 -2871 3842 595 2830 -1143 686 3479 -978 -3153 3589 4561 1671 134 262 -1615 1328 1005 -2849 2839 -1095 -146 -1408 -4965 -1820 3322 3267 -932 3317 573 -6117 2789 -920 1106 -3635 -606 -1024 -284 -2273 -2834 -402 2533 -4003 -4564 1571 2522 -3027 4214 2029 -3409 -742 733 2801 -235 5102 -4678 53 -4726 -1807 -3652 4214 5638 -120 1296 4838 -1635 3764 3800 -2209 -4442 349 953 2962 2665 -2472 -3232 -3279 -2540 3556 3848 1622 -7121 6646 1222 3381 2466 3765 2006 -2657 2057 945 -610 4270 1250 -1476 -2915 -3114 -865 2121 1334 -2341 2246 -689 -3899 4198 -3741 1885 9 3642 -829 -2153 2091 1149 2150 -2645 3887 4389 -1304 -3486 -2832 151 -1091 792 -580 -2680 -773 1679 -1267 2876 2307 -899 3287 6859 323 -16233 217 4937 2914 1890 -1303 -5284 3010 1194 6441 -2064 -610 -958 -1691 258 1133 3 -5069 -573 -889 -3052 4008 627 2840 -1090 631 3115 -935 -3176 3473 4442 1683 137 267 -1683 1351 1029 -3023 2818 -1114 -145 -1398 -5052 -1777 3064 3026 -912 3155 564 -6389 2618 -881 1026 -3526 -572 -976 -271 -2242 -2848 -398 2446 -4123 -4710 1523 2436 -3124 4087 2010 -3504 -721 679 2467 -208 4219 -4237 47 -4485 -1749 -3547 3887 5158 -115 1216 4369 -1588 3509 3580 -2223 -4583 344 943 2906 2645 -2579 -3353 -3338 -2521 3295 3565 1547 -7445 6066 1178 3185 2342 3510 1878 -2570 1885 879 -586 3990 1229 -1518 -3087 -3347 -918 2201 1403 -2556 2335 -729 -4190 4086 -3903 1867 SO 20180812T105041.0Z 6798.451863 464 1 32.00 2 88.19 70.47 99.60 81.01 0.00 1 0.00 1 0 29 1.085e-02 1.074e-02 1.092e-02 1.089e-02 9.326462e+03 7.337548e+02 6.530380e+02 -6.000000e+00 5.915549e+02 282.04 -2.00 20.00 -2.00 505.39 0.00e+00 1.366595e-03 2.971852e-04 7.780217e-05 -6.000000e+00 3.001269e-04 282.04 -2.00 20.00 -2.00 500.71 0.00e+00 1.642122e+00 2.098365e-01 6.120368e-02 -6.000000e+00 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