File name: Pandora114s1_BuenosAires_20180813_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042743.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180813_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180813T104132.0Z 6799.445509 455 1 32.00 2 89.76 71.99 109.74 93.65 0.00 1 0.00 1 0 22 8.717e-02 8.346e-02 6.808e-02 6.655e-02 1.405322e+04 4.797156e+03 7.542990e+02 -6.000000e+00 4.749204e+03 282.03 -2.00 20.00 -2.00 505.23 0.00e+00 7.655738e-04 1.796686e-03 1.065376e-04 -6.000000e+00 2.410452e-03 282.03 -2.00 20.00 -2.00 500.17 0.00e+00 6.391206e-01 1.316488e+00 1.297845e-01 -6.000000e+00 1.706129e+00 226.37 -2.00 3.16 -2.00 501.77 0.00e+00 20.153 0.077 489.00 513.00 1 9.2630e+00 1.0066e-01 3.2741e-02 -6.0000e+00 1.3065e-01 1.0797e-01 2.5693e-02 3.1675e-03 -6.0000e+00 3.4121e-02 9.5425e-06 4.5347e-03 5.7908e-03 7.7260e-05 -6.0000e+00 8.5745e-03 1.1850e-01 -6.5417e-04 12 9 8 11 8 0 -667.52 21.35 8.39 0.11850 0.14995 8 2 1 4 0 4000.000 25.47 20.00 21.35 -10571 10796 -7245 12587 -7915 858 478 2859 9970 -9393 3204 1426 4584 6873 7143 22588 -5699 9573 -665 1841 -6842 -1805 3618 -3421 -711 -4585 -5938 1204 -2069 13532 -15058 -1564 -9437 1847 10315 4786 2595 -2473 1536 4550 13351 -7518 11389 8664 -8640 9207 -1587 12103 -2418 1353 -5438 -3221 10378 -13183 8272 -13983 6004 2113 -3021 11301 -4011 8473 -6932 7080 -13096 6972 2505 -3930 12439 -7165 16564 -5214 998 46 13989 5863 -17321 11379 -8653 3356 3799 -6908 4929 877 6031 -14682 -1393 -3189 -3866 6217 -5037 7784 -8637 7548 12327 -5222 -6030 -7980 7097 -8413 9689 -10867 482 558 -10929 21580 -7380 14508 -5181 1104 6934 -6444 12191 -9884 6916 15617 14464 162 -6638 9842 -8755 10466 -14747 5502 14138 852 1478 1457 -454 -7644 8747 4144 15825 27920 -6956 6031 3648 -104 3682 545 -1481 6516 -1155 -13268 -1143 -7752 13924 2191 -4351 -5033 -4602 10242 -4076 -11674 9910 -8237 12082 -8916 967 511 2997 10360 -10907 3233 1445 4446 6456 6679 18272 -6246 9242 -726 1978 -8035 -2018 3839 -3912 -795 -5324 -6947 1293 -2241 12182 -17747 -1619 -10836 1960 10318 5100 2811 -2786 1644 4690 12600 -8796 11145 8817 -10558 9450 -1809 11896 -2702 1424 -5960 -3362 9298 -14965 7735 -16845 6084 2261 -3416 11058 -4571 8549 -7688 6842 -15432 6652 2462 -4054 10752 -7449 13439 -5230 944 45 11920 5450 -20127 9743 -8891 3024 3392 -6873 4381 819 5410 -16402 -1374 -3211 -3909 5653 -5114 6982 -9226 6925 10756 -5323 -5999 -7809 5787 -7821 7388 -10102 405 484 -11184 16718 -7854 12481 -5387 1066 6304 -6752 10737 -10962 6514 13499 12679 165 -6903 9310 -9373 9687 -16185 5138 11990 778 1350 1337 -425 -7685 7452 3689 12449 19178 -6673 5046 3136 -95 3278 510 -1438 5926 -1148 -15020 -1153 -8389 12129 2136 -4474 -5118 -4574 8686 -4004 SO 20180813T104531.0Z 6799.448275 459 1 32.00 2 88.98 71.43 108.94 93.10 0.00 1 0.00 1 0 22 4.125e-02 4.122e-02 3.788e-02 3.755e-02 7.991900e+03 2.524047e+03 5.610938e+02 -6.000000e+00 2.247990e+03 282.03 -2.00 20.00 -2.00 505.34 0.00e+00 1.188775e-03 1.015790e-03 4.471316e-05 -6.000000e+00 1.140724e-03 282.03 -2.00 20.00 -2.00 500.39 0.00e+00 2.590671e+00 7.312268e-01 4.466918e-02 -6.000000e+00 8.063509e-01 226.37 -2.00 3.16 -2.00 501.99 0.00e+00 18.618 0.060 489.00 513.00 1 8.7571e+00 5.5939e-02 2.8376e-02 -6.0000e+00 6.1767e-02 3.7248e-02 1.4228e-02 1.9429e-03 -6.0000e+00 1.6097e-02 1.7267e-05 4.9929e-03 3.4545e-03 6.5949e-05 -6.0000e+00 4.0565e-03 8.9653e-03 1.2649e-04 12 8 8 10 0 0 89.80 21.35 4.52 0.00897 0.04360 8 2 1 4 0 4000.000 25.47 19.99 21.35 -3224 4118 3239 -5510 -909 3566 -1346 -994 -3001 2541 1403 5158 -5326 -5888 7362 446 4646 5050 1095 -1430 -7694 158 -6332 6432 -2052 10579 6583 4476 -5367 2863 -342 -5116 -2239 982 -4073 -529 2013 -6119 1654 3852 -6239 7056 887 -2523 -430 -3918 4042 1330 1459 5092 5058 230 5239 -83 -328 1095 -1151 3500 -1173 -1548 397 -8320 2577 -3239 2793 -1039 -103 -750 -3209 4724 4897 -113 -1153 -2546 -57 855 6477 -1271 1181 -4868 -1562 -4927 -4996 6992 -764 3989 -3170 -8097 -3093 3502 5035 -623 3937 6051 4917 884 348 2186 -4485 3146 -4390 847 959 -2045 -918 1388 -2791 -3512 3083 3770 1321 -2951 -3660 2465 1086 9452 2664 2571 -4699 3796 -4533 496 -4521 2406 5381 960 -1500 -2856 -659 4617 452 6721 -7800 -4433 -6900 4153 -4582 5613 -334 3523 -2032 -6590 1956 421 11083 6866 408 -3267 -6313 5242 -4023 1210 1908 -3204 3919 3004 -5746 -928 3553 -1427 -1054 -3225 2550 1405 4910 -5568 -6141 6720 441 4503 5006 1153 -1558 -8949 170 -7302 6566 -2291 10409 6704 4591 -5926 2831 -344 -5436 -2373 1043 -4667 -590 2173 -7087 1753 3970 -7119 7099 960 -2860 -483 -4566 4334 1449 1561 5136 4964 231 4924 -83 -334 1134 -1173 3454 -1217 -1609 404 -9283 2591 -3457 2795 -1068 -103 -745 -3226 4336 4438 -107 -1109 -2513 -56 830 5885 -1225 1092 -4737 -1466 -4794 -4896 6128 -731 3680 -3165 -8512 -3088 3263 4621 -609 3723 5665 4660 860 333 1992 -4251 2700 -3989 725 829 -1881 -872 1337 -2857 -3619 2944 3539 1270 -2994 -3797 2295 1035 8329 2526 2461 -4883 3641 -4701 482 -4541 2225 4812 902 -1455 -2819 -638 4239 432 6039 -8055 -4367 -6872 3677 -4444 4995 -322 3341 -2072 -7134 1965 433 10318 6705 426 -3523 -6930 5028 -4155 1176 1855 SO 20180813T104933.0Z 6799.451076 463 1 32.00 2 88.19 70.85 108.14 92.55 0.00 1 0.00 1 0 22 1.497e-02 1.484e-02 1.198e-02 1.193e-02 1.203387e+04 8.351517e+02 8.615693e+02 -6.000000e+00 8.161511e+02 282.03 -2.00 20.00 -2.00 505.39 0.00e+00 2.003745e-03 3.242959e-04 1.174674e-04 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