File name: Pandora114s1_BuenosAires_20180814_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042809.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180814_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180814 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180814T104026.0Z 6800.444745 454 1 32.00 2 89.76 72.37 117.25 106.10 0.00 1 0.00 1 0 39 1.069e-01 1.046e-01 1.152e-01 1.115e-01 1.437430e+04 8.542460e+03 5.810186e+02 -6.000000e+00 5.829566e+03 282.02 -2.00 20.00 -2.00 505.43 0.00e+00 -3.507187e-03 3.064967e-03 3.196127e-04 -6.000000e+00 2.956710e-03 282.02 -2.00 20.00 -2.00 500.18 0.00e+00 3.306866e+00 2.237296e+00 1.774737e-01 -6.000000e+00 2.084652e+00 226.42 -2.00 3.16 -2.00 501.87 0.00e+00 20.152 0.077 489.00 513.00 1 9.6598e+00 1.7123e-01 3.4700e-02 -6.0000e+00 1.5977e-01 4.1233e-02 4.2651e-02 3.6544e-03 -6.0000e+00 4.1476e-02 5.5632e-06 2.2327e-03 9.5256e-03 9.9455e-05 -6.0000e+00 1.0498e-02 -3.9218e-02 6.2790e-04 12 8 8 10 0 0 87.45 20.93 10.85 -0.03922 -0.02373 8 2 1 4 0 4000.000 25.17 20.01 20.93 -1731 -2718 7883 -17325 -12284 9786 -1330 -4865 2350 -2937 2316 7269 -6226 -1955 14658 12624 510 -6115 -2570 -10919 10736 23546 -11890 19220 -10714 10052 -8626 9397 -5561 13572 747 6009 -4046 -7684 3829 7920 5861 -16547 -686 1131 1551 1866 -9095 21595 5572 -3680 22563 3005 2539 -2705 -14184 -4231 2274 14847 -9093 10786 -228 7513 -11333 119 4893 2944 6199 -3522 44 5304 16299 12217 -1415 15669 -5741 4288 4040 -702 -1522 16939 7549 3211 16426 -23060 6363 8287 -11405 -5414 10665 18971 1261 -8947 9917 -451 3190 -9787 15729 -4422 13549 -15339 6417 2674 -6043 10672 -1400 -3138 8615 4166 3975 11207 7565 -6851 8642 -20646 12848 20300 6571 18349 618 9417 12010 10637 20970 -18070 5226 -9741 -9274 -19731 4309 -6089 36115 -4424 2101 -20713 3446 11016 2606 3504 184 7706 -1959 -19457 13153 -18938 -3062 -1988 4794 -3822 -9547 -2412 -7161 11973 10175 8557 16021 -1041 11688 -1676 -2738 7388 -21513 -14869 9705 -1496 -5699 2551 -3326 2460 7266 -7050 -2107 13393 11929 558 -7354 -3050 -14240 11319 21882 -14732 18762 -13198 10037 -10312 9247 -6202 12168 752 5781 -4424 -9017 4103 8197 6151 -21468 -750 1203 1639 1972 -10806 19046 5808 -4211 19735 3154 2628 -2878 -16439 -4317 2138 12337 -9809 9828 -238 7338 -13382 125 4886 3004 6145 -3851 46 5219 14138 10863 -1423 13134 -5901 3970 3770 -696 -1542 14322 6933 3019 13290 -27397 5612 7188 -12136 -5485 9328 15487 1240 -9171 8963 -422 2877 -10099 13528 -4382 11110 -16351 5306 2211 -5285 7730 -1129 -2574 6417 3387 3422 9420 6772 -7116 7618 -24125 10711 15813 5927 14796 595 8301 10341 9377 16909 -21732 4964 -10584 -9822 -22786 3887 -6117 23938 -4413 1967 -24344 3178 9409 2404 3161 170 6582 -1861 -22470 11235 -22776 -3202 -2092 4783 -4205 -11221 -2654 -7783 11372 9734 7705 14013 -1011 10073 SO 20180814T104425.0Z 6800.447512 458 1 32.00 2 88.98 71.81 116.49 105.46 0.00 1 0.00 1 0 22 5.058e-02 4.983e-02 4.478e-02 4.442e-02 9.251724e+03 2.996234e+03 5.736420e+02 -6.000000e+00 2.755214e+03 282.02 -2.00 20.00 -2.00 505.34 0.00e+00 4.383355e-03 1.212001e-03 2.399512e-04 -6.000000e+00 1.397710e-03 282.02 -2.00 20.00 -2.00 500.60 0.00e+00 1.031299e+00 8.690217e-01 8.199232e-02 -6.000000e+00 9.868198e-01 226.42 -2.00 3.16 -2.00 502.16 0.00e+00 18.612 0.060 489.00 513.00 1 9.0003e+00 6.6668e-02 2.9446e-02 -6.0000e+00 7.5604e-02 5.4665e-02 1.6910e-02 2.2985e-03 -6.0000e+00 1.9676e-02 1.4499e-05 -2.4323e-03 4.1461e-03 9.8901e-05 -6.0000e+00 4.9668e-03 1.9204e-01 -9.0809e-04 12 8 8 10 0 0 -111.89 20.93 1.01 0.19204 0.17517 8 2 1 4 0 4000.000 25.17 20.00 20.93 -8642 2048 1424 7636 9476 -4098 -1716 -7016 9596 -5160 9734 1830 -2960 14442 -77 7554 2582 1797 1800 -1477 1236 -7223 6038 -5957 3350 -1367 -1227 3672 -2335 -4684 -11139 4334 2768 -4994 1557 -4336 -276 -734 2134 4173 9745 2775 285 -7496 -4189 5718 -5287 5082 -175 -323 164 -3473 5981 1211 -1376 -1804 3835 4518 1368 -5766 -7933 3721 1932 -1075 7236 -2961 6566 -7196 4850 5153 75 6006 -2069 1773 -9312 3536 -732 3721 1711 -4948 -925 -7428 -4242 -7039 -726 4829 -3088 6941 -2589 -339 -1330 -2161 -4601 7566 4208 -2680 5020 187 2355 -2439 -2096 2797 -7581 2311 -2478 4593 -111 -2434 10840 -1300 -2209 -2436 -8353 -8414 11894 3708 1166 5680 216 2961 696 5402 -1584 2032 4593 120 921 1222 1002 1871 -1785 -5054 -3531 847 -9600 8310 -4145 1498 2086 4845 1450 -6241 5679 -154 8038 870 -5585 3667 -4745 3961 -7069 13115 -1629 -8378 1837 1331 6915 8637 -4366 -1809 -7821 8997 -5527 8844 1774 -2973 12073 -74 6797 2489 1789 1829 -1565 1277 -8135 5976 -6692 3452 -1480 -1321 3720 -2454 -4895 -12190 4076 2708 -5465 1641 -4896 -298 -788 2205 4204 9307 2867 306 -8282 -4537 6025 -5827 5340 -191 -346 171 -3421 5625 1121 -1333 -1811 3747 4463 1403 -6355 -8937 3747 1993 -1147 7089 -3183 6325 -7833 4620 4838 74 5492 -2055 1713 -10187 3426 -735 3514 1621 -4955 -886 -7601 -4226 -7260 -709 4507 -3143 6403 -2621 -334 -1321 -2176 -4808 7103 4111 -2778 4713 179 2147 -2277 -1911 2398 -7241 2050 -2400 4312 -105 -2369 9734 -1229 -2104 -2352 -8708 -8922 10418 3552 1153 5412 220 2950 707 5175 -1598 1946 4258 117 896 1193 983 1821 -1802 -5268 -3608 817 -10130 7258 -4098 1416 1998 4604 1449 -6826 5570 -161 7802 912 -6251 3729 -5189 3896 -7605 11387 -1644 SO 20180814T104829.0Z 6800.450336 462 1 32.00 2 88.18 71.22 115.70 104.82 0.00 1 0.00 1 0 29 8.426e-03 8.344e-03 3.410e-03 3.395e-03 9.731030e+03 2.243845e+02 6.693475e+02 -6.000000e+00 4.591578e+02 282.02 -2.00 20.00 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