File name: Pandora114s1_BuenosAires_20180816_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042756.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180816_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180816T103811.1Z 6802.443184 452 1 32.12 2 89.76 73.14 127.68 134.40 0.00 1 0.00 1 0 15 7.039e-02 6.988e-02 5.579e-02 5.496e-02 5.858851e+03 3.588618e+03 1.201816e+02 -6.000000e+00 3.835472e+03 282.02 -2.00 20.00 -2.00 505.28 0.00e+00 5.193425e-04 1.489292e-03 6.181911e-05 -6.000000e+00 1.945259e-03 282.02 -2.00 20.00 -2.00 500.32 0.00e+00 1.270894e+00 1.079794e+00 1.009146e-01 -6.000000e+00 1.371685e+00 226.51 -2.00 3.16 -2.00 501.93 0.00e+00 20.149 0.077 489.00 513.00 1 9.0409e+00 8.2563e-02 3.1914e-02 -6.0000e+00 1.0512e-01 9.4623e-02 2.1202e-02 2.4011e-03 -6.0000e+00 2.7301e-02 1.1626e-05 -1.5068e-03 5.1894e-03 2.2104e-05 -6.0000e+00 6.9091e-03 1.3352e-01 -4.4465e-04 12 9 8 11 8 0 -300.79 21.05 -5.15 0.13352 0.12307 8 2 1 4 0 4000.000 25.39 20.00 21.05 -6944 -5114 2681 7104 -7381 9222 -11005 2547 6847 13032 -172 -798 15535 -13158 6521 -9078 2623 1036 -8285 4310 -8681 2276 -6791 4687 4055 -656 14085 -10168 12869 -3380 8056 -576 231 14990 -8315 3495 256 5850 -3965 -5627 5743 -2791 5285 -5317 7428 8828 7393 202 -5335 3002 -4534 75 -848 4503 5861 -1784 5369 5 -2894 -10754 1793 -1524 6365 1458 -6587 4089 -5725 7823 3255 4292 3224 -570 -1930 -7440 10944 2636 14963 -21 3388 -2613 -11004 7475 -12564 -1689 -989 3324 10102 -7072 8165 -14111 1926 -1542 -3983 -467 -12973 11915 5337 4576 1985 -4346 -1495 -7842 8790 -1412 8657 1330 10217 1216 392 6631 -1002 -68 2088 100 -2171 -924 -103 226 8342 -11151 13361 1794 -2233 3053 -4424 13195 -6282 13308 -2418 2450 6861 861 1951 -3799 -3356 -9533 8199 -214 -2486 6698 -6711 11089 -5663 -1318 -4375 -2643 4799 -14053 8145 -14339 13380 7126 10465 -7322 -5451 2734 7135 -8191 8843 -13083 2653 6787 11983 -178 -819 13391 -14981 6090 -10010 2629 1083 -9701 4490 -10320 2428 -7952 4916 4296 -728 13406 -12161 11925 -3581 7494 -587 240 13890 -9975 3754 282 6030 -4457 -6386 5816 -3097 5467 -6188 7684 9036 7647 222 -6094 3083 -4886 75 -843 4253 5579 -1890 5438 5 -3040 -12203 1793 -1580 6129 1478 -7208 3979 -6053 7112 3058 3945 2964 -541 -1865 -7691 9544 2512 12495 -20 3069 -2490 -11375 6443 -13326 -1621 -952 3101 8878 -7406 7341 -15822 1842 -1537 -4117 -471 -14896 10552 4942 4161 1804 -4112 -1349 -7473 7163 -1312 7579 1299 9289 1208 388 6095 -992 -67 2053 102 -2147 -908 -101 222 7613 -12404 11559 1717 -2186 2797 -4347 10914 -6351 11091 -2360 2275 6088 810 1806 -3672 -3180 -9516 6860 -197 -2395 6007 -6997 9804 -5976 -1340 -4617 -2756 4654 -16389 7512 -16223 11237 6301 8988 SO 20180816T104211.0Z 6802.445961 456 1 32.00 2 88.97 72.57 127.11 133.45 0.00 1 0.00 1 0 22 3.431e-02 3.429e-02 3.173e-02 3.155e-02 7.745380e+03 2.087871e+03 6.667734e+02 -6.000000e+00 1.869813e+03 282.02 -2.00 20.00 -2.00 505.30 0.00e+00 1.702921e-03 8.615441e-04 7.328532e-05 -6.000000e+00 9.489382e-04 282.02 -2.00 20.00 -2.00 500.43 0.00e+00 1.073385e+00 6.188667e-01 2.338902e-02 -6.000000e+00 6.711656e-01 226.51 -2.00 3.16 -2.00 502.03 0.00e+00 18.593 0.060 489.00 513.00 1 8.6861e+00 4.7570e-02 2.8200e-02 -6.0000e+00 5.1407e-02 6.8833e-02 1.2012e-02 1.7696e-03 -6.0000e+00 1.3404e-02 2.0696e-05 6.4684e-03 2.9305e-03 8.9313e-05 -6.0000e+00 3.3748e-03 3.6485e-03 1.3235e-04 12 9 8 11 8 0 -162.13 21.05 3.52 0.00365 0.04852 8 2 1 4 0 4000.000 25.28 20.00 21.05 1617 -5215 938 4915 -419 4597 146 573 2610 406 -440 -3566 2839 -4989 4082 -5568 -3202 2767 -1780 8381 -1151 1680 1613 1008 -246 1805 2159 2652 1304 -7534 137 -2145 -629 -2220 -183 12388 -8123 1546 2250 -1205 2854 -3813 3056 -5486 1920 -1575 1547 -691 -1250 -79 -3954 2768 1336 -1965 2204 -1247 1163 -3043 3892 3592 346 -2025 -3317 4160 2403 738 -2289 -182 527 -6908 8783 -882 3283 -1872 440 -126 -6620 625 -6081 5925 -5419 509 -2253 -1594 -1128 -2385 -87 535 3584 4523 4837 3942 676 6015 -520 791 356 -1436 -3294 1744 -699 3893 -6650 -1615 203 -3745 -1896 4286 -6295 2201 -3915 263 1438 -1337 1815 -40 3862 -3733 2733 -187 -2963 5636 -1423 -3179 -174 2246 -712 1879 1057 28 -1350 574 987 -1052 3139 -978 3491 3995 103 3735 2118 306 -1762 4675 -3562 -1755 6543 -5089 5733 3486 -1592 -5289 -3692 1447 -5150 902 4672 -430 4577 153 603 2669 418 -451 -3720 2745 -5173 3862 -5866 -3367 2812 -1931 8276 -1253 1780 1716 1085 -269 1935 2293 2760 1341 -8232 136 -2206 -655 -2430 -201 12080 -9662 1651 2361 -1302 2966 -4268 3232 -6001 1971 -1681 1593 -719 -1288 -83 -3981 2711 1309 -1873 2062 -1246 1165 -3223 3858 3568 355 -2137 -3564 4157 2433 752 -2367 -181 515 -7197 7741 -853 3058 -1860 433 -125 -6948 600 -6135 5256 -5373 477 -2186 -1549 -1103 -2388 -86 526 3408 4249 4534 3756 675 5755 -532 787 347 -1387 -3158 1554 -627 3311 -6362 -1517 196 -3659 -1848 3921 -6333 2014 -3810 249 1363 -1320 1753 -40 3695 -3884 2690 -190 -3078 5290 -1408 -3157 -167 2116 -696 1795 1019 28 -1331 554 942 -1011 2849 -918 3143 3633 100 3546 2077 309 -1837 4600 -3830 -1861 6392 -5554 5538 3373 -1590 -5436 -3761 SO 20180816T104615.0Z 6802.448785 460 1 32.00 2 88.17 71.99 126.51 132.50 0.00 1 0.00 1 0 22 1.217e-02 1.213e-02 8.454e-03 8.426e-03 8.109073e+03 5.641866e+02 5.156849e+02 -6.000000e+00 6.634685e+02 282.02 -2.00 20.00 -2.00 505.40 0.00e+00 2.209491e-03 2.296551e-04 1.308835e-04 -6.000000e+00 3.365117e-04 282.02 -2.00 20.00 -2.00 500.73 0.00e+00 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