File name: Pandora114s1_BuenosAires_20180817_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042810.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180817_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180817T103702.0Z 6803.442384 450 1 32.00 2 89.76 73.53 130.02 149.90 0.00 1 0.00 1 0 29 6.415e-02 6.392e-02 6.265e-02 6.183e-02 7.827656e+03 4.143050e+03 3.602438e+02 -6.000000e+00 3.494390e+03 282.04 -2.00 20.00 -2.00 505.28 0.00e+00 1.239338e-04 1.676012e-03 6.881253e-05 -6.000000e+00 1.773553e-03 282.04 -2.00 20.00 -2.00 500.35 0.00e+00 1.388500e+00 1.207848e+00 9.089861e-02 -6.000000e+00 1.255279e+00 226.55 -2.00 3.16 -2.00 501.94 0.00e+00 20.148 0.077 489.00 513.00 1 9.1551e+00 9.2093e-02 3.1787e-02 -6.0000e+00 9.6127e-02 8.0862e-02 2.3783e-02 2.4290e-03 -6.0000e+00 2.5099e-02 1.0313e-05 -2.2103e-03 5.6420e-03 4.3947e-05 -6.0000e+00 6.3089e-03 1.3930e-01 -7.6179e-04 12 8 8 10 0 0 7.30 21.28 12.47 0.13930 0.12397 8 2 1 4 0 4000.000 25.47 20.00 21.28 -3140 619 -2838 6671 3303 258 -1220 15119 -731 -2215 -5493 -3788 6755 -7918 278 1684 2240 6079 1705 2677 -6420 7586 -6428 4246 -5899 -4359 3293 17050 4093 -6382 5160 -10659 12447 -1429 2383 -1333 -3985 10974 363 6412 9804 3324 -4001 -16568 -4237 1021 7372 -648 8611 9050 -2293 -7343 -15259 7763 -6442 -1239 171 1388 3684 -5563 5428 -519 11320 1814 -1611 11211 -818 10789 -6745 2034 -6047 -7977 -1844 -1665 6231 414 115 5421 -493 9651 -8507 608 -7493 -3983 12071 3402 -724 -3210 5517 -15009 3170 -3420 605 2240 3261 5683 -7752 6243 -10400 -1594 5463 15645 -876 -4753 7696 -10648 9358 3742 2252 -2395 -5662 -3350 1705 9841 1819 922 -4070 440 -10049 6166 4991 -3005 -75 -3246 6427 2926 -1767 4005 6943 4574 6395 4358 5615 9831 4584 -9782 -5739 5272 -11020 -1067 -1430 -977 -2587 5832 36 3836 646 -7180 -2722 -5420 2400 3096 10825 -3127 608 -2985 6585 3230 266 -1297 13745 -776 -2363 -5971 -3994 6333 -8510 274 1646 2218 5945 1784 2813 -7419 7633 -7455 4444 -6865 -5003 3486 15569 4168 -7014 4941 -11931 11266 -1536 2542 -1497 -4589 10775 392 6451 9507 3451 -4511 -21422 -4896 1126 7626 -720 8594 8813 -2436 -7981 -17572 7057 -6846 -1287 181 1475 3855 -5985 5223 -530 10335 1828 -1678 10192 -827 9563 -7027 1919 -6116 -8158 -1774 -1615 5664 403 112 4928 -467 8152 -8572 560 -7522 -3893 10151 3157 -707 -3234 5099 -17000 2990 -3459 593 2189 3175 5360 -8193 5581 -10676 -1461 4574 11675 -773 -4465 6647 -11536 8543 3643 2209 -2431 -5898 -3427 1679 9058 1833 887 -4136 430 -10998 5781 4733 -3053 -73 -3194 5683 2681 -1707 3669 6188 4175 5723 3977 5045 8377 4053 -9870 -5545 4605 -11551 -1035 -1418 -979 -2666 5572 37 3788 661 -7936 -2854 -5739 2302 2903 9378 SO 20180817T104101.0Z 6803.445150 454 1 32.00 2 88.97 72.97 129.61 148.80 0.00 1 0.00 1 0 22 3.710e-02 3.678e-02 3.561e-02 3.536e-02 6.316678e+03 2.304007e+03 5.665246e+02 -6.000000e+00 2.022495e+03 282.04 -2.00 20.00 -2.00 505.32 0.00e+00 8.758096e-05 9.602466e-04 5.752463e-05 -6.000000e+00 1.025926e-03 282.04 -2.00 20.00 -2.00 500.47 0.00e+00 1.669373e+00 6.876866e-01 1.884693e-02 -6.000000e+00 7.242942e-01 226.55 -2.00 3.16 -2.00 502.06 0.00e+00 18.595 0.060 489.00 513.00 1 8.7861e+00 5.2609e-02 2.8145e-02 -6.0000e+00 5.5498e-02 5.4323e-02 1.3382e-02 1.7042e-03 -6.0000e+00 1.4431e-02 1.8375e-05 1.8574e-03 3.2994e-03 7.0823e-05 -6.0000e+00 3.6456e-03 -3.9230e-02 5.3970e-04 12 8 8 10 0 0 -88.47 21.28 6.63 -0.03923 -0.02635 8 2 1 4 0 4000.000 25.47 20.00 21.28 -5190 2443 -7144 1896 -5220 638 -4754 -2582 1978 737 -408 -1223 1325 1188 1512 1553 -1615 -38 -286 4269 -4031 -2206 -2358 5260 4128 1708 -2033 -2930 5988 -1868 5599 -512 6918 2513 7844 3367 -3448 -1874 1255 -7229 -1890 406 -1770 4129 3590 -3126 2336 392 -4191 2837 3777 5667 -10371 -1386 231 1946 3504 -1288 3649 4177 -3416 696 1620 2067 3688 -3745 1380 -2984 -4687 -1879 1854 6338 5777 -3559 1639 -673 6982 -380 -7339 2393 -3204 -3325 1320 -2134 1012 -757 8234 -1037 6724 -5901 1167 -805 -4080 933 5611 5360 -1088 4491 -463 789 -1505 -5603 -1427 1907 -3234 -3595 -936 -1656 -437 5792 2421 4505 -3332 -733 1904 3558 -3384 1812 172 2375 -6174 -682 -4222 2160 -4570 5550 4835 1661 5266 2550 122 -3883 7606 -4201 2296 -3555 -307 -2281 9236 2203 979 -1288 -2830 -711 369 -4250 961 2357 694 -1897 1011 -2204 -6788 -4892 2196 -7312 1827 -5536 652 -5195 -2773 2020 752 -415 -1240 1294 1153 1460 1514 -1660 -39 -305 4388 -4517 -2431 -2610 5420 4320 1831 -2250 -3229 5894 -1934 5291 -517 6649 2613 7937 3593 -3919 -2074 1331 -8283 -2053 433 -1950 4340 3832 -3582 2525 428 -4705 2904 3726 5342 -11285 -1380 231 1973 3370 -1319 3573 4062 -3581 703 1628 2073 3626 -3926 1354 -3012 -4751 -1832 1722 5601 5155 -3530 1565 -662 6307 -363 -7392 2166 -3060 -3191 1217 -2057 955 -737 7384 -1024 6146 -6110 1128 -798 -4233 932 5359 5073 -1074 4085 -431 709 -1360 -5231 -1292 1722 -3208 -3714 -959 -1708 -440 5419 2339 4303 -3287 -714 1824 3373 -3457 1770 172 2334 -6569 -677 -4269 2021 -4556 5023 4435 1578 4831 2401 118 -3895 6761 -4145 2092 -3406 -285 -2195 8096 2115 968 -1321 -2977 -737 382 -4627 995 2397 708 -1949 989 -2206 -7154 SO 20180817T104504.0Z 6803.447963 458 1 32.00 2 88.17 72.39 129.18 147.71 0.00 1 0.00 1 0 15 1.560e-02 1.547e-02 1.525e-02 1.518e-02 6.641665e+03 1.000312e+03 4.795579e+02 -6.000000e+00 8.500352e+02 282.04 -2.00 20.00 -2.00 505.34 0.00e+00 1.660111e-03 4.107514e-04 1.043149e-04 -6.000000e+00 4.311218e-04 282.04 -2.00 20.00 -2.00 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