File name: Pandora114s1_BuenosAires_20180820_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042812.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180820_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180820T103330.0Z 6806.439931 397 1 32.00 2 89.75 74.73 125.46 194.05 0.00 1 0.00 1 0 15 7.732e-02 7.315e-02 6.634e-02 6.482e-02 1.797688e+03 3.914697e+03 2.263065e+02 -6.000000e+00 4.214853e+03 282.09 -2.00 20.00 -2.00 505.25 0.00e+00 -8.629271e-04 1.745857e-03 7.674246e-05 -6.000000e+00 2.138003e-03 282.09 -2.00 20.00 -2.00 500.04 0.00e+00 2.782890e+00 1.286742e+00 1.245394e-02 -6.000000e+00 1.509919e+00 226.69 -2.00 3.16 -2.00 501.67 0.00e+00 20.141 0.076 489.00 513.00 1 9.1332e+00 9.8116e-02 3.0957e-02 -6.0000e+00 1.1568e-01 9.5405e-02 2.5645e-02 1.7017e-03 -6.0000e+00 3.0101e-02 9.7402e-06 -6.2293e-03 6.1358e-03 3.7204e-05 -6.0000e+00 7.5974e-03 2.1153e-02 1.4204e-04 12 8 8 10 0 0 86.12 20.05 10.78 0.02115 -0.02206 8 2 1 4 0 4000.000 24.46 20.00 20.05 -7153 -630 -4284 -7179 7084 5840 179 -7287 -218 760 -9022 3373 5530 7113 -3215 -337 -5505 2635 -3105 2657 3960 3702 7857 9821 -4910 -1139 -2683 -1049 1232 10575 -7158 -5764 4794 -251 -2499 3299 10899 2604 -1007 5828 -3770 -1347 -7386 16173 -5077 4953 -3214 -7378 1185 -3222 8130 4745 615 -9028 -14112 6062 -14683 2018 -2759 11144 6081 7342 5558 -2600 -812 4418 16825 -3957 -2653 1945 -1393 3288 -3343 20948 2681 3286 -2427 -11449 9169 3618 13152 -8469 15341 -809 -772 7383 -11263 8940 -11189 14383 -1662 -2844 17311 8278 -2945 10372 5582 -9015 1334 5677 -10410 -1330 -2301 20369 -1339 9815 -1342 -7365 4850 -12628 -1797 2339 7110 -3923 -3366 8723 -12534 2699 -7934 5089 186 -11554 13628 -7523 20785 4130 2577 850 6447 4218 -12097 3595 836 14580 -5777 -10288 14472 -7855 960 -4908 8169 -691 8556 6303 -5178 1952 -223 7333 -8008 5969 -5462 -11678 7202 -7596 -641 -4666 -8307 7298 6228 206 -9094 -253 866 -10432 3643 5772 7231 -3363 -344 -6016 2723 -3485 2858 4226 3967 8087 9941 -5781 -1293 -3079 -1173 1320 10033 -7913 -6250 4751 -270 -2837 3591 10987 2823 -1118 5974 -4231 -1478 -8665 15138 -5935 5266 -3703 -8781 1275 -3548 7783 4562 602 -9636 -16019 5777 -17724 2103 -3038 10668 6104 7277 5626 -2863 -877 4491 14894 -4240 -2764 1911 -1399 3119 -3173 16769 2449 3014 -2351 -11956 7646 3146 10341 -8273 11878 -742 -714 6362 -11807 7703 -11819 11765 -1597 -2778 13954 7396 -2970 9143 5098 -9343 1219 4847 -10210 -1173 -2047 14721 -1244 8457 -1321 -7720 4449 -13588 -1719 2155 6324 -3957 -3421 7932 -14184 2636 -8663 4890 187 -12892 11635 -7826 16177 3805 2425 768 5517 3689 -12432 3157 753 11333 -5419 -9958 10871 -7427 847 -4695 6991 -656 7482 5676 -5263 1861 -219 6660 -8410 5354 -5369 -12002 6109 SO 20180820T103729.0Z 6806.442697 401 1 32.00 2 88.96 74.16 125.64 192.97 0.00 1 0.00 1 0 15 4.133e-02 4.090e-02 3.993e-02 3.952e-02 2.527126e+03 2.421632e+03 8.149713e+01 -6.000000e+00 2.252454e+03 282.09 -2.00 20.00 -2.00 505.28 0.00e+00 7.958143e-04 1.077966e-03 7.120197e-05 -6.000000e+00 1.142939e-03 282.09 -2.00 20.00 -2.00 500.25 0.00e+00 2.735305e+00 7.799179e-01 4.110272e-02 -6.000000e+00 8.084223e-01 226.69 -2.00 3.16 -2.00 501.88 0.00e+00 18.573 0.060 489.00 513.00 1 8.8258e+00 5.9750e-02 2.8230e-02 -6.0000e+00 6.1918e-02 6.1606e-02 1.5345e-02 1.6859e-03 -6.0000e+00 1.6148e-02 1.6304e-05 5.8575e-04 3.7501e-03 2.4743e-05 -6.0000e+00 4.0645e-03 6.4275e-02 -2.4359e-04 12 8 8 10 0 0 46.30 20.05 4.81 0.06427 0.06834 8 2 1 4 0 4000.000 24.35 20.01 20.05 -4396 1014 5528 -4765 5128 -1106 3066 -2658 -1195 1469 -2413 -2517 -8529 2684 -3280 -2520 -1582 -1400 5792 -2252 176 -5637 4382 -1104 1938 367 1526 3472 -5644 -1437 -2444 -2085 -1886 -2334 5536 1139 278 2978 5716 4620 1018 3453 -2481 3873 -277 2762 -39 1037 3500 120 4150 -5614 1499 -2695 -1506 6902 4744 540 585 -745 -4632 911 -2417 -1487 4694 -4825 1469 -1873 3730 2517 -4443 8933 -92 928 2291 -1968 1901 -2829 1797 2564 5762 -5867 7998 2448 -6768 2491 -4228 5304 -8236 -3844 4325 -6719 -293 83 7934 -6609 1205 3707 1875 -3094 -5472 3945 3458 5181 -2612 993 -1241 7132 9357 1967 5960 -2673 -3047 4256 -971 1161 -1932 2437 -4134 367 -1389 -4553 5360 -2016 1939 -10227 3540 2670 4295 4512 -1891 2222 -2931 4198 1868 -2310 1668 -3499 6278 1688 -1485 -10402 -3218 -5194 -3699 277 929 5631 -1634 5719 8253 -10310 4481 -4212 946 5097 -5021 5019 -1177 3175 -2931 -1294 1529 -2574 -2653 -9428 2627 -3397 -2610 -1654 -1500 5908 -2518 192 -6552 4617 -1235 2112 406 1663 3667 -6384 -1515 -2550 -2171 -2002 -2574 5805 1261 310 3192 5890 4773 1089 3620 -2787 4131 -311 3024 -44 1141 3697 128 4148 -6017 1467 -2742 -1541 6684 4827 546 595 -767 -4946 922 -2540 -1552 4592 -5141 1447 -1877 3486 2353 -4400 7678 -87 874 2158 -1949 1800 -2760 1645 2303 4994 -5725 6836 2229 -6817 2310 -4228 4842 -8615 -3844 3990 -6963 -288 82 7338 -7041 1170 3438 1730 -2929 -5194 3362 2972 4478 -2530 959 -1247 6579 8338 1863 5397 -2660 -3091 3841 -936 1106 -1911 2321 -4230 359 -1377 -4597 4825 -1929 1776 -10627 3227 2465 3905 4093 -1827 2061 -2852 3759 1686 -2147 1486 -3317 5508 1585 -1465 -11378 -3308 -5481 -3869 281 937 5415 -1672 5330 7335 -10878 4085 SO 20180820T104135.0Z 6806.445544 405 1 32.00 2 88.15 73.58 125.81 191.85 0.00 1 0.00 1 0 22 9.987e-03 9.962e-03 8.173e-03 8.145e-03 6.771502e+03 5.343079e+02 4.860816e+02 -6.000000e+00 5.443440e+02 282.09 -2.00 20.00 -2.00 505.38 0.00e+00 3.111608e-03 2.211565e-04 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