File name: Pandora114s1_BuenosAires_20180824_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042911.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180824_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180824T102833.0Z 6810.436493 340 1 32.00 2 89.76 76.38 103.25 237.17 0.00 1 0.00 1 0 64 1.520e-01 1.359e-01 1.577e-01 1.492e-01 7.065615e+03 1.068869e+04 5.389572e+02 -6.000000e+00 8.287602e+03 282.15 -2.00 20.00 -2.00 505.26 0.00e+00 5.730666e-03 4.016257e-03 3.378609e-04 -6.000000e+00 4.210017e-03 282.15 -2.00 20.00 -2.00 499.98 0.00e+00 1.808422e+00 3.030425e+00 2.623200e-01 -6.000000e+00 2.990114e+00 226.88 -2.00 3.16 -2.00 501.61 0.00e+00 20.143 0.077 489.00 513.00 1 9.9463e+00 2.3147e-01 3.7390e-02 -6.0000e+00 2.2870e-01 1.2733e-01 5.8915e-02 3.9460e-03 -6.0000e+00 6.0211e-02 4.1012e-06 3.1919e-03 1.3933e-02 1.3841e-04 -6.0000e+00 1.4977e-02 1.3448e-01 -2.6032e-04 12 8 8 10 0 0 96.95 20.98 23.91 0.13448 0.15662 8 2 1 4 0 4000.000 25.17 19.99 20.98 15754 -13173 -8232 -7391 7543 2374 -6704 10049 -798 -7817 16797 21044 -9526 -21046 19299 6412 20512 4796 -1448 19551 -3857 -7122 4951 3759 -372 14649 9652 -19195 29153 -7426 12943 10154 -5113 8207 -12165 -12289 -14833 10484 -6166 29693 -4677 995 655 10416 8422 29480 1488 5568 10410 2091 1267 7143 4382 18706 3485 15621 -26332 -12301 6599 -15474 3836 2495 20541 23696 -2522 -13813 -12351 27449 4294 2018 -16803 31050 -16463 13730 13491 -8130 2259 28437 -4012 6332 -13161 15243 4678 -16228 14673 4515 6737 -20755 11217 3362 5625 14200 -9070 -2595 5852 -22273 -24765 33624 46395 4599 22546 -2171 1495 -3718 7240 -17790 5821 -136 -4252 4305 -17435 9978 -6967 -5467 5983 15016 9375 8168 48818 -7107 17966 12946 34149 30536 7328 8047 -4978 9966 43487 -62 21015 -24841 3287 -2335 186 -1392 -3723 -3060 -3969 -12088 -14109 -10695 10155 15821 10970 -7396 -9333 -739 15393 -7687 30681 -8752 900000 13818 -15955 -9799 -8952 8034 2702 -8400 10598 -925 -9550 15785 18678 -11340 -27909 17129 6562 18633 5208 -1694 18578 -4632 -8849 5480 3956 -409 13848 9500 -24693 22445 -8034 11353 9302 -5630 8158 -15057 -15210 -18648 10115 -6970 23439 -5241 1066 715 10456 8701 24708 1639 5807 10145 2160 1285 6683 4185 15678 3498 14310 -37467 -15344 6817 -19906 4075 2700 18618 20784 -2851 -17231 -14926 21936 4268 2026 -20142 22998 -19734 12310 12228 -9111 2246 21340 -4105 5801 -14622 12775 4376 -17644 12584 4312 6303 -23893 9948 3010 4934 12317 -9447 -2561 5293 -26251 -29189 21505 25433 3740 15037 -1845 1243 -3363 6085 -19667 5106 -125 -4040 3737 -18956 8387 -7065 -5544 5466 12622 8394 7462 29884 -7597 14773 11000 23088 21204 6428 7058 -5003 8650 27018 -60 16320 -30412 3004 -2218 170 -1285 -3538 -2935 -3916 -13143 -15856 -11726 9092 13443 9823 -7974 -9630 -736 12798 -7403 21024 -8354 900000 SO 20180824T103233.0Z 6810.439271 344 1 32.00 2 88.96 75.82 103.92 236.53 0.00 1 0.00 1 0 15 8.183e-02 7.911e-02 8.197e-02 8.035e-02 9.885952e+03 5.623739e+03 7.874868e+02 -6.000000e+00 4.461729e+03 282.15 -2.00 20.00 -2.00 505.27 0.00e+00 4.508646e-03 2.185796e-03 1.764770e-04 -6.000000e+00 2.263755e-03 282.15 -2.00 20.00 -2.00 500.18 0.00e+00 -5.728486e-01 1.610809e+00 7.485618e-02 -6.000000e+00 1.602840e+00 226.88 -2.00 3.16 -2.00 501.78 0.00e+00 18.557 0.060 489.00 513.00 1 9.7392e+00 1.2331e-01 2.8994e-02 -6.0000e+00 1.2274e-01 1.3538e-01 3.1376e-02 2.3430e-03 -6.0000e+00 3.2054e-02 7.7868e-06 8.7898e-03 7.4227e-03 1.0385e-04 -6.0000e+00 8.0497e-03 7.4706e-02 -3.8283e-04 12 8 8 10 0 0 63.13 20.97 2.02 0.07471 0.13568 8 2 1 4 0 4000.000 25.17 20.01 20.97 7081 -2870 -1152 -5961 -2289 -9068 2286 -315 -4316 6677 -10472 -3784 -11431 2353 -2599 12351 2527 5372 6954 5859 2264 14742 2664 -231 -7306 4677 -2483 264 3197 -1263 3369 3162 86 14933 4045 -9356 -6034 6706 -2908 7546 4225 -19234 -7038 15124 6582 576 -284 16251 13430 -3937 6813 11294 -2149 -2520 -3075 -4329 -6031 -8750 -5290 9386 7398 13765 7411 -773 4073 2917 3369 -4058 -5318 7359 -5109 -3068 12016 -14509 12144 -3369 -10180 -878 -1939 1958 71 -6906 -761 20848 3013 13467 -10416 -7163 10079 14215 339 -5418 1972 12929 -2801 -13210 -2065 14607 1224 7025 9475 -9262 -19133 2132 4056 9762 11864 -3220 9406 -3149 691 -9771 -8583 6072 1313 11753 5370 1675 4076 -7318 23378 -4310 -500 -9667 -8719 5691 -8577 1391 1981 -207 7408 21636 1941 -11919 7327 1520 11928 12686 3900 10991 -9760 4307 -1861 -1840 -7478 635 -7032 -824 2006 2865 -6671 -8947 -3361 6572 -3035 -1238 -6908 -2614 -11274 2559 -361 -5099 6949 -12724 -4236 -13632 2422 -2620 11603 2494 5274 6828 5844 2341 13467 2755 -247 -8439 4789 -2712 276 3156 -1267 3184 3022 88 13485 4163 -11052 -6843 6620 -3130 7290 4237 -24640 -8092 14134 6774 633 -313 15017 12551 -4279 6474 10021 -2155 -2554 -3213 -4727 -6871 -10382 -6083 9314 7496 13153 7587 -860 4298 3078 3484 -4453 -5835 7032 -5472 -3205 10851 -16212 11222 -3416 -10924 -843 -1851 1783 65 -6867 -716 15906 2773 11269 -11126 -7404 8732 11755 322 -5494 1883 11201 -2840 -14630 -1993 11576 1078 5705 7368 -8616 -19871 1847 3594 8457 10219 -3217 8195 -3084 653 -10389 -9168 5679 1299 10529 5155 1682 4033 -8141 18987 -4540 -498 -10373 -9227 5239 -9161 1349 1911 -203 6746 17040 1735 -12037 6383 1391 9863 10553 3396 9630 -10038 3891 -1802 -1790 -7725 606 -7232 -790 1840 2549 -6397 -8704 -3114 SO 20180824T103636.0Z 6810.442083 348 1 32.00 2 88.15 75.24 104.59 235.87 0.00 1 0.00 1 0 15 4.969e-02 4.846e-02 4.557e-02 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