File name: Pandora114s1_BuenosAires_20180825_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042936.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180825_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180825T102719.0Z 6811.435637 326 1 32.00 2 89.75 76.80 96.51 246.30 0.00 1 0.00 1 0 22 8.033e-02 7.603e-02 6.292e-02 6.151e-02 -2.811224e+03 3.549252e+03 2.427272e+02 -6.000000e+00 4.381599e+03 282.17 -2.00 20.00 -2.00 505.20 0.00e+00 3.084821e-03 1.666245e-03 1.531095e-04 -6.000000e+00 2.224848e-03 282.17 -2.00 20.00 -2.00 500.11 0.00e+00 2.109568e+00 1.250384e+00 2.535081e-02 -6.000000e+00 1.578098e+00 226.92 -2.00 3.16 -2.00 501.72 0.00e+00 20.133 0.076 489.00 513.00 1 9.0851e+00 9.5340e-02 3.1153e-02 -6.0000e+00 1.2074e-01 1.2180e-01 2.5146e-02 1.7021e-03 -6.0000e+00 3.1709e-02 1.0269e-05 -1.4164e-02 5.8708e-03 6.6478e-05 -6.0000e+00 7.9155e-03 3.0694e-02 5.0101e-04 12 8 8 10 0 0 -253.99 20.18 2.29 0.03069 -0.06756 8 2 1 4 0 4000.000 24.46 20.00 20.18 -7127 -4058 -8908 10413 -9336 4285 -4647 3713 2569 -9517 10492 -10240 4654 -539 10551 -2430 -6236 4177 -3108 5684 -7902 4472 6955 5416 -2582 547 3915 7965 5465 -7349 1646 1977 -6093 4782 120 2708 -62 -5373 6464 2418 5741 -2571 8462 -1013 6571 8435 -3401 7985 402 5284 -6037 -3224 -12803 -946 9689 -6462 9815 -11029 2561 -7942 3088 -549 2110 9439 -9 9611 4543 -7621 208 -11452 7515 -6019 9876 -3073 11505 8475 -10209 17353 -3855 20760 2708 13161 -13040 -950 9921 -12106 8227 -12140 11352 -2402 -3028 6891 -4257 14491 -10798 2113 3723 -451 2103 -4063 12335 -8865 22090 1496 -8864 1266 -13138 1163 -2821 5767 6441 7218 11611 -6702 8446 -7061 7355 -3002 -2101 864 -2690 13635 -8465 14273 -7956 8007 4546 -3956 1409 -2452 15811 -9405 16439 -3577 1651 10107 -7936 10468 -914 1164 -2092 9358 -6760 -5051 7779 -13985 2558 -2697 1003 -6684 -12447 18104 900000 -7642 -4317 -10281 10224 -11458 4687 -5643 4173 2910 -11207 10663 -11771 4870 -548 9541 -2510 -6793 4197 -3436 5826 -9305 4655 7072 5617 -2917 600 4139 8003 5513 -8181 1634 1947 -6612 4805 130 2906 -69 -6177 6521 2517 5769 -2821 8401 -1119 6814 8645 -3923 8151 436 5352 -6673 -3369 -14408 -939 8762 -7065 9389 -13253 2707 -9320 3240 -598 2247 9371 -10 9425 4619 -8070 214 -12255 7008 -5965 8891 -2976 9754 7472 -10809 13731 -3704 15410 2398 10513 -13610 -884 8336 -12772 7130 -12945 9582 -2326 -2955 6128 -4282 12285 -11962 2070 3577 -447 1997 -4011 10085 -8785 15981 1347 -9085 1202 -14554 1109 -2753 5085 5606 6283 9844 -6969 7702 -7636 6956 -3167 -2201 875 -2797 11868 -9058 12047 -7871 7211 4265 -3816 1289 -2330 12504 -9572 12884 -3387 1458 8065 -7514 8279 -823 1048 -1980 7998 -6832 -5034 6841 -15375 2395 -2659 942 -6637 -12757 13418 900000 SO 20180825T103118.0Z 6811.438403 330 1 32.00 2 88.95 76.24 97.24 245.73 0.00 1 0.00 1 0 22 3.364e-02 3.316e-02 3.635e-02 3.606e-02 1.709576e+03 2.129807e+03 2.616978e+01 -6.000000e+00 1.834729e+03 282.17 -2.00 20.00 -2.00 505.25 0.00e+00 3.050123e-03 9.755042e-04 1.554811e-04 -6.000000e+00 9.305660e-04 282.17 -2.00 20.00 -2.00 500.23 0.00e+00 2.311038e+00 7.068345e-01 4.403005e-02 -6.000000e+00 6.577009e-01 226.92 -2.00 3.16 -2.00 501.85 0.00e+00 18.545 0.060 489.00 513.00 1 8.7360e+00 5.4105e-02 2.8398e-02 -6.0000e+00 5.0385e-02 7.9424e-02 1.3979e-02 1.6628e-03 -6.0000e+00 1.3122e-02 1.7940e-05 4.8725e-03 3.4290e-03 5.3874e-05 -6.0000e+00 3.3074e-03 1.4789e-02 1.2844e-04 12 8 8 10 0 0 -59.39 20.17 8.15 0.01479 0.04859 8 2 1 4 0 4000.000 24.46 20.00 20.17 1662 -5329 -1695 29 -572 -1970 4249 3490 2649 2287 -3931 -4894 1359 5062 -2689 -305 -2322 383 -417 -2058 -1059 563 2199 -1957 1086 421 -1475 4026 -6629 -86 4838 2167 -4455 2889 1076 3615 971 899 710 -4127 -4132 1213 910 3970 9969 1068 -1006 1005 2111 -1500 2965 -3032 -1060 -5490 -5433 -2788 3067 -1650 -517 -2778 1649 2437 2885 842 -932 29 2394 -1859 4764 501 2379 1320 1688 -413 1955 -1130 -3306 -1091 -834 2636 -1637 -150 2607 -5994 -2279 1316 22 3698 317 -4800 2224 29 66 628 418 -557 2236 2746 -4632 -6576 478 -1381 5644 5564 -2580 3706 -2317 3689 -50 -5159 2259 532 3081 -2457 517 -641 2235 -1438 4347 7083 -3419 160 -6379 -1157 3551 -536 -5882 1268 10661 3085 396 5998 6521 -3059 -2927 -5110 -3138 -3395 -1986 2178 -1901 3287 -5244 -8313 5194 1433 178 3905 6131 -346 -4432 2303 -801 1632 -5399 -1714 29 -603 -2144 4395 3642 2765 2360 -4251 -5269 1358 4830 -2769 -310 -2457 405 -452 -2284 -1166 610 2353 -2195 1187 463 -1644 4183 -7466 -88 4651 2154 -4860 3029 1176 3875 1061 972 761 -4619 -4634 1301 991 4246 10147 1192 -1142 1105 2258 -1626 2990 -3165 -1069 -5808 -5509 -2839 3021 -1728 -537 -2945 1672 2460 2912 869 -974 30 2354 -1877 4441 482 2217 1236 1581 -399 1870 -1119 -3308 -1048 -786 2381 -1540 -139 2372 -5985 -2210 1242 21 3431 304 -4835 2093 28 65 622 418 -560 2153 2578 -4574 -6464 428 -1248 4788 4842 -2519 3487 -2334 3471 -48 -5174 2105 511 2940 -2375 493 -624 2128 -1429 4094 6479 -3440 153 -6419 -1094 3204 -507 -5906 1189 9110 2841 374 5362 5762 -2931 -2756 -4866 -2929 -3219 -1895 2033 -1878 3116 -5451 -8952 4913 1415 178 3751 5672 -333 -4358 2097 -758 SO 20180825T103523.0Z 6811.441238 334 1 32.01 2 88.14 75.65 97.98 245.13 0.00 1 0.00 1 0 15 2.102e-02 2.102e-02 2.146e-02 2.133e-02 5.397850e+03 1.402229e+03 2.807061e+02 -6.000000e+00 1.146496e+03 282.17 -2.00 20.00 -2.00 505.35 0.00e+00 1.534325e-03 5.786371e-04 8.550081e-05 -6.000000e+00 5.813195e-04 282.17 -2.00 20.00 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