File name: Pandora114s1_BuenosAires_20180827_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042931.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180827_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180827T102444.0Z 6813.433843 318 1 32.00 2 89.75 77.66 82.69 264.57 0.00 1 0.00 1 0 29 9.447e-02 9.398e-02 1.026e-01 1.005e-01 -1.300853e+03 5.734966e+03 1.630938e+02 -6.000000e+00 5.151032e+03 282.20 -2.00 20.00 -2.00 505.32 0.00e+00 1.409819e-03 2.765092e-03 2.550670e-05 -6.000000e+00 2.611834e-03 282.20 -2.00 20.00 -2.00 500.29 0.00e+00 2.676896e+00 1.977200e+00 4.672074e-02 -6.000000e+00 1.843790e+00 227.02 -2.00 3.16 -2.00 501.94 0.00e+00 20.136 0.076 489.00 513.00 1 9.5648e+00 1.5244e-01 3.1092e-02 -6.0000e+00 1.4127e-01 7.7115e-02 3.8522e-02 1.7909e-03 -6.0000e+00 3.6745e-02 6.1947e-06 1.9997e-02 9.7375e-03 3.4813e-05 -6.0000e+00 9.2755e-03 1.4321e-01 -5.7499e-04 12 8 8 10 0 0 56.80 21.10 8.27 0.14321 0.28191 8 2 1 4 0 4000.000 25.28 20.00 21.10 -11139 7942 2258 2571 -5674 -1536 18449 265 1427 -3839 4755 -1806 -13755 2196 5515 -4145 10354 -2844 -9161 3014 -5382 15670 10607 8309 -16886 -8414 -3602 2562 -198 589 7067 -7619 10464 -4409 -1635 -7044 5773 5351 15924 3008 1849 2347 -5462 1348 18845 1045 3519 1719 1897 -18162 2580 2601 -6220 10517 3113 8224 15050 3056 -1504 -5733 9735 -1404 -1333 14535 17701 -8864 3941 -15704 12800 4453 2599 -948 -4861 -3623 4480 1333 -5042 4927 -8492 12376 -30504 8285 6857 8447 -8545 9239 -4524 705 772 10141 6836 21519 -5584 44 -7400 -3136 13908 -2577 11671 3751 -22209 2933 6153 4454 14366 -9195 25194 8432 17694 -4515 -21962 1843 -49 6627 -1030 903 4443 309 1658 14922 -8579 6054 -2905 -3948 -845 943 3694 10379 6922 -703 15212 -9013 1627 -6217 2116 8238 4097 -6248 -2398 21973 -17746 -17617 -6677 6267 -9727 9136 129 2152 19136 3230 6899 -10702 11508 -12380 7541 2335 2712 -6626 -1739 17129 293 1536 -4294 4817 -1930 -16448 2240 5509 -4665 10342 -3081 -10645 3107 -6042 14299 10237 8237 -21505 -9777 -3925 2557 -198 577 6541 -8403 9961 -4979 -1803 -8139 5799 5340 14217 3060 1918 2450 -6239 1452 17073 1125 3650 1784 1918 -21819 2456 2442 -6411 9390 3086 7936 13734 3150 -1620 -6436 9395 -1521 -1444 13359 15572 -10009 3855 -18454 11176 4180 2474 -939 -5074 -3781 4323 1313 -5196 4529 -8310 10481 -37360 7397 5867 7174 -8678 7904 -4455 659 722 8676 6101 16820 -5808 43 -7879 -3165 11641 -2490 9553 3255 -24740 2563 5339 4057 12114 -9847 18917 7369 13940 -4446 -26087 1758 -49 6240 -1059 917 4375 318 1674 13041 -9346 5626 -2932 -4033 -843 928 3547 9327 6433 -705 13014 -9763 1562 -6351 1967 7199 3783 -6537 -2465 17987 -20559 -20511 -7000 5809 -10649 8309 128 2057 15075 2919 5954 -11096 9733 SO 20180827T102843.0Z 6813.436609 322 1 32.00 2 88.95 77.09 83.49 264.05 0.00 1 0.00 1 0 22 5.744e-02 5.665e-02 5.534e-02 5.463e-02 4.527622e+03 3.432978e+03 2.005632e+02 -6.000000e+00 3.132164e+03 282.20 -2.00 20.00 -2.00 505.28 0.00e+00 -8.057534e-04 1.469353e-03 4.551733e-05 -6.000000e+00 1.588721e-03 282.20 -2.00 20.00 -2.00 500.28 0.00e+00 1.268661e+00 1.067302e+00 5.804145e-02 -6.000000e+00 1.123534e+00 227.02 -2.00 3.16 -2.00 501.90 0.00e+00 18.546 0.060 489.00 513.00 1 9.2917e+00 8.1301e-02 2.8341e-02 -6.0000e+00 8.6058e-02 8.4238e-02 2.1250e-02 1.8738e-03 -6.0000e+00 2.2436e-02 1.1653e-05 -4.1370e-03 5.1028e-03 1.6959e-05 -6.0000e+00 5.6475e-03 7.6001e-02 -2.9481e-04 12 8 8 10 0 0 99.15 21.10 2.46 0.07600 0.04730 8 2 1 4 0 4000.000 25.28 20.01 21.10 1301 9726 4867 -8184 -119 2787 5885 -4795 -4942 4810 -3782 4994 -5691 -5051 -4881 4895 6231 -7338 -5483 -5586 -2904 1451 7033 -49 -4404 -2110 -6270 8197 -7739 4079 -1099 6473 1249 2390 3451 -1529 8346 2586 17 3354 3270 1442 1194 -1051 -3205 8993 7850 5598 5492 2084 1205 1180 -9361 6772 93 -2736 -9867 884 -9494 -3944 8780 -821 11141 1624 -781 106 -5485 -1489 10075 9685 9749 993 -10642 -4062 3740 -10940 2124 -55 988 2652 9519 -643 -4266 2327 -8753 565 1636 -4535 2888 5745 2899 -463 6499 -5131 5356 3558 3343 6444 -5272 -1069 -2798 -1648 -7297 9172 389 6189 4850 -2977 -1284 -9980 4042 1591 -8611 507 6791 1742 -1664 -1148 5758 12522 -1231 -1777 427 4634 -1048 52 -1723 4752 -9780 10512 -7304 9121 -1937 -11191 -1901 229 11608 -7554 13456 -5074 15 -5147 5945 10508 -1096 782 -6667 -4957 -9290 810 5273 2544 6434 1249 8779 4766 -9422 -129 2815 5861 -5358 -5522 4825 -4077 4867 -6095 -5319 -5105 4666 5961 -8251 -6205 -6421 -3266 1565 7181 -53 -5078 -2380 -7342 8222 -8924 4063 -1126 6124 1266 2474 3646 -1725 8521 2769 18 3484 3385 1523 1275 -1160 -3649 9117 8042 5815 5627 2164 1230 1171 -10092 6164 92 -2852 -11377 934 -11218 -4407 8619 -832 10067 1619 -797 107 -5745 -1475 8767 8363 8320 917 -11041 -3983 3442 -11789 2004 -53 912 2378 7932 -594 -4112 2118 -8993 535 1550 -4598 2725 5268 2736 -454 6003 -5392 5109 3441 3189 5823 -5223 -991 -2584 -1483 -6960 7582 364 5696 4642 -3098 -1302 -10888 3801 1538 -9338 509 6477 1760 -1749 -1135 5685 11609 -1229 -1764 407 4175 -990 49 -1650 4281 -10197 8940 -7408 7843 -1855 -11632 -1772 206 9287 -7377 10851 -5034 15 -5285 5524 9400 -1108 781 -7203 -5262 -10212 791 4817 2348 5694 SO 20180827T103249.0Z 6813.439456 326 1 32.00 2 88.13 76.50 84.31 263.50 0.00 1 0.00 1 0 22 3.321e-02 3.308e-02 2.885e-02 2.866e-02 2.801748e+02 1.574450e+03 2.958976e+01 -6.000000e+00 1.811380e+03 282.20 -2.00 20.00 -2.00 505.26 0.00e+00 1.389897e-03 7.777850e-04 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