File name: Pandora114s1_BuenosAires_20180904_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042842.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180904_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180904 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180904T101405.0Z 6821.426447 359 1 32.01 2 89.75 81.17 56.61 11.75 0.00 1 0.00 1 0 15 1.011e-01 9.537e-02 8.099e-02 7.873e-02 -2.660712e+03 4.408219e+03 4.953404e+01 -6.000000e+00 5.517498e+03 282.34 -2.00 20.00 -2.00 505.18 0.00e+00 1.156873e-03 2.111169e-03 1.019360e-04 -6.000000e+00 2.797779e-03 282.34 -2.00 20.00 -2.00 500.11 0.00e+00 2.531349e+00 1.570890e+00 6.107194e-02 -6.000000e+00 1.978757e+00 227.38 -2.00 3.16 -2.00 501.72 0.00e+00 20.124 0.076 489.00 513.00 1 9.3383e+00 1.2021e-01 3.1290e-02 -6.0000e+00 1.5156e-01 1.0546e-01 3.1727e-02 1.9711e-03 -6.0000e+00 3.9518e-02 7.9097e-06 -5.0728e-03 7.6548e-03 4.2505e-05 -6.0000e+00 9.9424e-03 1.0794e-01 -4.9155e-04 12 8 8 10 0 0 99.62 21.06 5.97 0.10794 0.07275 8 2 1 4 0 4000.000 25.28 20.01 21.06 3878 7867 19748 -6342 -2303 342 -9551 9766 13256 19440 6878 2877 14033 -4529 371 -10860 -4127 -8634 16285 658 -3563 -253 -3790 -1146 -6060 12266 5295 3329 -144 -14756 8340 -11602 8859 -2217 9787 -7914 441 3712 -6364 4405 111 11595 -2042 17 -7861 -11019 1692 843 -4335 19291 5626 -842 -58 1192 747 13954 -4970 -1067 -745 -5885 21142 -13470 9324 -8531 15403 -3654 -15601 4531 -20001 1766 10327 22765 1975 5995 1450 -8798 -3315 -5287 13398 -773 -3829 1584 -16058 12538 -17690 11784 2628 26783 -6626 -12085 9631 2172 7470 -5054 21700 2143 -6731 6226 -10895 14474 -6127 12560 -11465 -4733 -10216 285 10022 10707 2792 -8661 4502 -6674 -17298 15125 -5541 15087 2088 284 3408 1763 6328 -11348 16964 -3966 9859 -5405 2484 5383 -9807 11246 4245 6851 5627 -14569 18732 -8450 27659 4968 15624 6623 21507 818 -10613 8053 -13948 12210 3705 9 -5368 -6414 5519 9942 -3943 3697 7371 16981 -7306 -2615 387 -12109 10282 13444 18323 7241 3108 13381 -4799 372 -12235 -4416 -9905 14912 714 -4050 -278 -4328 -1280 -7139 12053 5556 3528 -155 -17839 7809 -13191 8340 -2406 9718 -9527 488 3934 -7366 4532 119 11095 -2258 18 -9423 -13717 1854 924 -4928 16970 5528 -857 -57 1153 734 12347 -5471 -1153 -808 -6721 18381 -16561 9161 -10050 14263 -4060 -18058 4499 -23441 1754 9297 17919 1791 5262 1350 -9165 -3261 -5227 10791 -708 -3601 1413 -17193 10159 -19537 9775 2408 19376 -6710 -12939 8315 2032 6701 -5216 17373 2099 -7175 5765 -11770 11867 -6028 10056 -11611 -4543 -10642 275 8894 9399 2612 -8939 4039 -6727 -19689 12693 -5826 13097 2085 290 3386 1777 6043 -12752 14154 -4036 8702 -5579 2384 5037 -10061 9342 3777 5940 4930 -15474 14029 -8170 19609 4172 11985 5682 16206 769 -11273 7128 -15449 10475 3481 9 -5483 -6493 4835 8168 -3705 SO 20180904T101805.0Z 6821.429225 363 1 32.01 2 88.94 80.60 56.46 10.67 0.00 1 0.00 1 0 15 4.762e-02 4.669e-02 4.544e-02 4.498e-02 5.826467e+03 2.916218e+03 5.219494e+02 -6.000000e+00 2.598486e+03 282.34 -2.00 20.00 -2.00 505.28 0.00e+00 2.651836e-03 1.215072e-03 1.214048e-04 -6.000000e+00 1.317082e-03 282.34 -2.00 20.00 -2.00 500.36 0.00e+00 1.504624e+00 8.794842e-01 2.683743e-02 -6.000000e+00 9.294252e-01 227.38 -2.00 3.16 -2.00 501.94 0.00e+00 18.501 0.059 489.00 513.00 1 9.0320e+00 6.7095e-02 2.8128e-02 -6.0000e+00 7.1222e-02 7.5957e-02 1.7336e-02 1.7025e-03 -6.0000e+00 1.8509e-02 1.4211e-05 1.6681e-04 4.2156e-03 7.6763e-05 -6.0000e+00 4.6743e-03 6.1391e-02 -3.1632e-05 12 9 8 11 8 0 -74.39 21.06 2.87 0.06139 0.06255 8 2 1 4 0 4000.000 25.28 20.01 21.06 7173 -3999 -5548 867 1511 55 6140 -4467 2754 -5317 5682 4906 6446 350 -739 4720 -2100 9587 4950 -1490 327 -914 3810 495 -5059 -4774 7214 -5963 166 -2439 2963 -5453 2794 2751 -1040 -295 5427 -7682 5831 3806 3958 -5326 5959 -2534 -6753 321 -510 1616 -6312 -4385 -2202 -6701 8615 -4143 2365 -3298 4374 -2837 -3997 -5886 -4137 -370 6733 3319 -2658 4073 5669 -3945 1641 5149 4940 204 1423 3761 -3436 10397 -6299 3414 9809 -3828 -1232 -2440 492 -3656 -176 224 -2474 -2817 5357 6569 732 5819 3014 -4703 -3213 10969 1798 -12132 6650 9826 -2960 -1249 -5862 -430 -386 2690 -2204 -1373 2520 2914 -7647 -5708 -4826 -7128 1113 7741 -999 6501 -2878 -830 -3535 -615 14040 148 -1289 -2392 2369 -5040 2592 1696 1076 2376 1474 -223 -4772 7728 122 4021 -968 -2227 5323 -3009 2806 -5508 4509 7982 8968 -292 -5409 1471 -2477 2200 -4251 6550 -4206 -5723 864 1532 57 6136 -4976 2832 -5844 5511 4729 6044 345 -737 4495 -2185 9101 5019 -1625 351 -994 3964 535 -5813 -5472 7294 -6782 173 -2538 2874 -5785 2800 2854 -1149 -325 5631 -8986 5895 3904 4060 -6042 6112 -2867 -8058 359 -572 1757 -7309 -4872 -2330 -7228 7849 -4298 2350 -3577 4512 -2994 -4284 -6422 -4434 -383 6530 3338 -2827 4007 5405 -4076 1583 4738 4505 193 1341 3502 -3484 9224 -6543 3161 8379 -3713 -1161 -2333 460 -3586 -169 215 -2461 -2817 4930 5955 704 5355 2890 -4937 -3337 9792 1724 -13037 5772 8068 -2708 -1112 -5508 -394 -367 2564 -2241 -1381 2409 2746 -8006 -5929 -5053 -7302 1062 6965 -987 6002 -2940 -833 -3621 -603 11687 140 -1230 -2320 2206 -5071 2420 1596 1019 2218 1380 -209 -4616 6533 111 3576 -923 -2194 4941 -3075 2728 -5857 4362 7493 8349 -296 -5709 1419 -2434 2042 -4233 SO 20180904T102204.0Z 6821.431991 367 1 32.00 2 88.13 80.04 56.32 9.60 0.00 1 0.00 1 0 22 7.236e-03 7.166e-03 1.749e-03 1.744e-03 1.204711e+04 1.193350e+02 7.996708e+02 -6.000000e+00 3.950195e+02 282.34 -2.00 20.00 -2.00 505.39 0.00e+00 4.607152e-03 4.783641e-05 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