File name: Pandora114s1_BuenosAires_20180905_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042843.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180905_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180905 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180905T101244.0Z 6822.425509 377 1 32.00 2 89.75 81.62 61.15 27.04 0.00 1 0.00 1 0 22 6.993e-02 6.872e-02 7.000e-02 6.880e-02 3.672142e+03 4.335482e+03 7.553632e+01 -6.000000e+00 3.816677e+03 282.36 -2.00 20.00 -2.00 505.26 0.00e+00 1.613606e-04 1.859006e-03 9.133148e-05 -6.000000e+00 1.934151e-03 282.36 -2.00 20.00 -2.00 500.30 0.00e+00 1.070532e+00 1.367403e+00 5.565736e-02 -6.000000e+00 1.362709e+00 227.43 -2.00 3.16 -2.00 501.89 0.00e+00 20.117 0.076 489.00 513.00 1 9.3137e+00 1.0424e-01 3.1194e-02 -6.0000e+00 1.0446e-01 1.0749e-01 2.7200e-02 1.8756e-03 -6.0000e+00 2.7087e-02 9.1173e-06 -1.4626e-02 6.5122e-03 3.7644e-05 -6.0000e+00 6.8585e-03 2.6680e-02 2.9874e-04 12 8 8 10 0 0 95.09 21.38 9.90 0.02668 -0.07477 8 2 1 4 0 4000.000 25.47 20.00 21.38 2508 -8762 3779 -4172 8830 5865 1852 -2645 8868 -5864 -6461 4266 -9193 18272 -8218 1104 -2109 7060 3683 -998 9739 1929 2891 2738 648 -8613 2347 5007 5088 11257 -1214 4097 -10111 -1376 -597 -577 14275 -5081 -7860 -2149 18449 -6689 -2751 -2514 -5779 4867 9877 5268 -7914 -7413 -2468 1752 -748 3622 -2252 -10475 -2405 5228 1548 -7338 2349 9522 -8713 5341 244 6184 154 -560 7447 -7489 -2660 4095 -3967 6848 2098 -8659 4946 -2529 -6080 17036 -1138 6455 5967 10254 6215 -11976 -2176 12023 -2456 9869 -7107 6826 -9113 10909 4209 -861 -1597 -22393 5627 6076 3832 2565 10772 -8000 2948 11184 -1863 1582 5699 -10002 4639 -5699 -1181 -3003 9733 -7063 -1279 893 -1375 -888 185 2051 -4480 7156 -969 1535 756 -500 -13456 -8150 13469 10003 7930 789 12207 14228 7921 3524 -312 2284 -3025 -2317 -791 -8650 9928 -516 -2810 3292 984 -6580 -830 6806 -5562 2356 -9370 3677 -4542 8677 6074 2034 -3071 9185 -6977 -7626 4459 -10849 16195 -8793 1077 -2152 6729 3726 -1076 9502 2038 3028 2881 700 -10223 2491 5133 5124 10375 -1233 3905 -11228 -1441 -642 -633 13542 -5802 -9117 -2328 16174 -7548 -3006 -2770 -6651 5076 9813 5447 -9215 -8432 -2608 1725 -736 3371 -2237 -11585 -2530 5218 1621 -8412 2440 9204 -10145 5427 261 6200 162 -584 7065 -8148 -2727 3884 -4066 6342 1937 -9015 4503 -2452 -5996 13140 -1045 5496 5131 8514 5422 -12669 -2110 10186 -2412 8569 -7309 6128 -9679 9610 4009 -864 -1595 -26994 5004 5250 3311 2206 8491 -7722 2635 9569 -1869 1547 5308 -10750 4263 -5814 -1165 -3063 8861 -7681 -1321 907 -1438 -928 191 2058 -4721 6606 -960 1482 740 -497 -14359 -8245 11638 8413 6795 720 9782 11694 6877 3020 -282 2057 -2928 -2261 -768 -9162 8782 -510 -2853 3147 956 -6787 -790 5886 -5406 SO 20180905T101644.0Z 6822.428287 381 1 32.01 2 88.93 81.05 60.79 26.09 0.00 1 0.00 1 0 22 4.336e-02 4.247e-02 4.153e-02 4.104e-02 2.411637e+03 2.504074e+03 9.955766e+01 -6.000000e+00 2.366438e+03 282.36 -2.00 20.00 -2.00 505.24 0.00e+00 2.615961e-04 1.113344e-03 5.821289e-05 -6.000000e+00 1.199227e-03 282.36 -2.00 20.00 -2.00 500.18 0.00e+00 2.567585e+00 8.078925e-01 7.599443e-02 -6.000000e+00 8.454248e-01 227.43 -2.00 3.16 -2.00 501.80 0.00e+00 18.487 0.059 489.00 513.00 1 8.9038e+00 6.1999e-02 2.8438e-02 -6.0000e+00 6.4799e-02 7.5406e-02 1.5885e-02 1.9048e-03 -6.0000e+00 1.6818e-02 1.5590e-05 2.0112e-03 3.8316e-03 3.0550e-05 -6.0000e+00 4.2547e-03 7.9740e-02 -7.4971e-05 12 8 8 10 0 0 -231.11 21.38 6.50 0.07974 0.09369 8 2 1 4 0 4000.000 25.47 19.99 21.38 8462 5811 3680 2656 -3751 -1609 -4380 3141 3872 -321 -1460 2420 -835 -1847 -1516 -764 -4959 349 -5038 -306 -6214 968 3724 3686 3241 105 6557 -114 -298 -6744 -2179 1410 -2610 -740 -40 5719 2434 -1222 -2597 1432 -2195 410 -1234 1076 6590 -2029 5357 5304 -75 -1787 -3405 -810 -50 -4023 6728 -4899 2192 4889 7363 -302 -2096 1918 545 2068 -4139 4044 -4869 7303 -5285 -4483 8842 816 -518 -2901 1455 -8650 5325 -4559 -4039 -1335 -10254 7172 -5824 -1081 2603 -4065 -6884 1818 5345 -3695 3673 -10 -783 125 -5523 434 -5386 -1568 1114 -6798 5838 9776 3776 -10360 239 -130 8954 2228 531 -826 -1551 6559 7336 -8290 3576 3035 4891 -3167 -339 -3608 7079 -103 166 3335 3579 4959 3100 1737 7041 -3148 -2695 2255 4416 -718 3602 -1012 2189 1336 -3824 -7981 4828 -965 -4430 7372 8534 -6005 4254 -3189 2674 -4145 1451 -1330 -3482 7806 5678 3544 2657 -4094 -1752 -4958 3302 4009 -342 -1551 2440 -860 -1907 -1562 -791 -5479 375 -5824 -340 -7334 1064 3995 3974 3521 118 6824 -125 -318 -7470 -2280 1437 -2850 -820 -45 6090 2657 -1367 -2912 1532 -2438 447 -1381 1189 6947 -2334 5690 5562 -82 -1927 -3626 -819 -49 -4165 6406 -5400 2304 5061 6980 -309 -2176 1920 555 2075 -4392 3904 -5057 6611 -5355 -4453 7604 757 -490 -2844 1383 -9114 4821 -4471 -3880 -1239 -10391 6131 -5711 -1019 2389 -4027 -7062 1715 4865 -3679 3408 -10 -776 124 -5819 426 -5512 -1510 1020 -6581 4889 7817 3248 -10577 228 -127 8105 2140 511 -797 -1509 5954 6715 -8475 3284 2822 4491 -3171 -331 -3637 6350 -98 155 2983 3193 4389 2810 1600 6148 -3039 -2590 2060 3919 -661 3128 -913 1917 1198 -3692 -8197 4433 -950 -4550 6769 7796 -6381 4087 -3283 2557 -4150 1346 -1259 -3395 SO 20180905T102047.0Z 6822.431100 385 1 32.01 2 88.11 80.47 60.44 25.11 0.00 1 0.00 1 0 22 6.798e-03 6.703e-03 2.377e-03 2.371e-03 8.126253e+03 1.546365e+02 5.575920e+02 -6.000000e+00 3.710270e+02 282.36 -2.00 20.00 -2.00 505.40 0.00e+00 2.544437e-03 6.509838e-05 1.458657e-04 -6.000000e+00 1.880826e-04 282.36 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