File name: Pandora114s1_BuenosAires_20180913_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T042909.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180913_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180913T100133.0Z 6830.417743 420 1 32.01 2 89.75 85.29 118.82 126.55 0.00 1 0.00 1 0 36 1.780e-01 1.543e-01 1.571e-01 1.471e-01 1.505865e+04 1.081445e+04 1.023388e+03 -6.000000e+00 9.716909e+03 282.49 -2.00 20.00 -2.00 505.33 0.00e+00 4.196261e-03 4.019145e-03 3.928200e-05 -6.000000e+00 4.927518e-03 282.49 -2.00 20.00 -2.00 500.15 0.00e+00 -4.588691e-02 2.899244e+00 1.918119e-02 -6.000000e+00 3.491480e+00 227.80 -2.00 3.16 -2.00 501.79 0.00e+00 20.112 0.076 489.00 513.00 1 1.0089e+01 2.2221e-01 3.0931e-02 -6.0000e+00 2.6734e-01 1.2622e-01 5.6085e-02 1.9371e-03 -6.0000e+00 6.9875e-02 4.0932e-06 1.8924e-02 1.3473e-02 1.0853e-04 -6.0000e+00 1.7506e-02 4.1362e-02 -2.2132e-04 12 8 8 10 0 0 -377.58 21.31 2.25 0.04136 0.17262 8 2 1 4 0 4000.000 25.47 19.99 21.31 27176 -4424 36391 -7069 -21202 17768 -19400 17626 -7839 -6025 9808 -10685 -11796 -10583 30870 -205 11207 -3157 3394 6475 -18286 35820 -8855 4995 -4631 14779 967 6347 26679 -6476 25587 -2771 15656 32562 1078 -2757 -10492 1416 1647 -11423 14336 -13456 3265 -13803 7185 6275 29427 13763 9752 -8493 -12834 22520 395 5068 -14408 -10638 15037 -9588 22188 -18770 11044 -15663 18082 11875 12989 39005 -5753 2720 -10870 58982 24040 -376 31224 -10544 14668 -15192 -6881 19424 4028 386 -9105 29998 1210 -7233 -1602 3025 -2448 9866 3076 -1282 19860 941 21014 5445 15428 30465 -6400 20914 -16092 -4473 -2563 -14314 15488 -7279 62079 567 14801 -8034 -1775 7752 683 -1571 -17089 12204 -12020 42625 7548 -12929 20134 -34620 26900 10777 -7178 -10145 12594 -7755 -9753 40771 -5136 35248 12757 19831 10771 -24533 24067 993 18012 30779 45 -9857 -23081 8762 -25973 17191 1164 -5738 12809 8716 -11661 -6996 9589 24095 20835 20718 -4785 26993 -8301 -29268 16841 -26781 16706 -9448 -7014 9598 -12659 -13975 -12320 23852 -219 10968 -3643 3706 6870 -24866 28414 -11037 5455 -5582 14616 1013 6164 21987 -6787 20824 -2851 13849 25047 1151 -3049 -12408 1470 1695 -13400 13095 -16432 3422 -17386 7392 6517 24050 12969 9376 -9554 -14685 17756 388 4825 -17179 -12581 14025 -11523 19414 -24725 10832 -20180 16690 11646 12489 28503 -6472 2772 -12542 33460 19185 -383 23417 -12166 13257 -18405 -7542 16061 3834 378 -9805 21921 1187 -7790 -1648 2996 -2566 9107 3016 -1306 16422 950 17578 5340 13499 22262 -6115 15685 -15956 -3870 -2149 -13548 11169 -6890 30777 537 12275 -8328 -1712 6779 646 -1543 -19872 10671 -13436 27664 7008 -14918 16878 -50243 20853 9617 -7506 -10791 10672 -8109 -10462 26461 -5278 24147 10925 15731 9224 -29412 17573 913 14126 21641 44 -10751 -29128 8135 -34416 14877 1185 -6259 11547 8093 -13034 -7315 8384 18244 16528 SO 20180913T100533.0Z 6830.420521 424 1 32.00 2 88.93 84.72 118.18 125.76 0.00 1 0.00 1 0 15 9.197e-02 8.710e-02 7.997e-02 7.813e-02 1.674015e+04 5.890972e+03 9.888340e+02 -6.000000e+00 5.023086e+03 282.49 -2.00 20.00 -2.00 505.33 0.00e+00 3.352686e-03 2.128390e-03 1.742422e-04 -6.000000e+00 2.546005e-03 282.49 -2.00 20.00 -2.00 500.29 0.00e+00 -6.495626e-01 1.567125e+00 1.282418e-01 -6.000000e+00 1.800217e+00 227.80 -2.00 3.16 -2.00 501.89 0.00e+00 18.470 0.059 489.00 513.00 1 9.7402e+00 1.1987e-01 3.0027e-02 -6.0000e+00 1.3791e-01 1.0753e-01 3.0479e-02 3.2124e-03 -6.0000e+00 3.5928e-02 7.9487e-06 -2.1126e-03 6.8842e-03 1.1418e-04 -6.0000e+00 9.0444e-03 -1.2000e-02 2.7938e-04 12 9 8 11 8 0 -249.15 21.31 -0.79 -0.01200 -0.02665 8 2 1 4 0 4000.000 25.47 20.00 21.31 10679 4604 -2511 -11211 5825 1161 -14419 6775 -4520 8716 3907 -5145 521 -6659 -1690 -7312 10095 135 9679 3017 -5819 10119 3050 28383 -8092 951 -1307 -6063 8671 -4525 17954 -10912 -1744 -1426 -6846 -8097 2349 -4763 -4016 8718 11394 642 7884 1764 3080 -4915 3940 -1056 3277 3322 -673 4350 -6747 11468 -7006 -2047 2954 12206 8844 -5836 18004 3710 13457 -9676 -9733 587 -2633 4961 -1331 17123 -2585 -13513 146 3648 7116 -11936 8666 -1610 2551 692 28 5734 -17628 6807 -4990 9558 -1386 -6762 -1384 -10493 14940 -3386 17302 6362 2568 2546 -4095 286 -5312 12790 -1187 7166 2743 -14423 13156 -5708 26753 -2767 7366 3845 -15171 13366 -6883 22957 -11151 -3447 -9921 4060 10417 -12050 15676 -765 5773 3043 20146 11425 -18067 8324 -5599 6577 885 5181 5113 9524 -11349 -12749 14280 8654 1151 4987 -5026 2445 -2378 4611 -8664 12484 -2414 -5123 -3568 -8813 6626 -12466 20921 9229 4332 -2623 -13185 5926 1264 -18613 7115 -5291 8820 4082 -5798 547 -7430 -1784 -7652 9663 137 9092 3065 -6476 9609 3114 22605 -9337 1005 -1408 -6779 8190 -4735 14666 -11866 -1763 -1485 -7760 -9425 2458 -5301 -4388 8323 10587 669 7728 1865 3255 -5670 4164 -1164 3413 3392 -698 4175 -7096 10012 -7475 -2143 3031 11653 8805 -6734 16361 3902 12916 -11757 -11826 638 -2917 5015 -1413 14949 -2718 -15730 148 3613 6903 -13254 8317 -1580 2357 642 26 5022 -19575 5962 -4967 8326 -1360 -7023 -1358 -11199 12299 -3354 14078 5846 2458 2401 -3998 257 -4881 9550 -1000 5488 2206 -14151 10264 -5655 19847 -2794 6699 3588 -17063 11387 -7280 18240 -12542 -3597 -11064 3964 9672 -14188 14031 -799 5527 2928 16103 9953 -21273 7569 -5868 6107 868 4860 4772 8387 -11400 -12865 11687 7580 1107 4702 -5003 2291 -2368 4320 -9328 10910 -2447 -5308 -3600 -9211 5820 -13084 15738 SO 20180913T100937.0Z 6830.423345 428 1 32.01 2 88.09 84.15 117.51 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