File name: Pandora114s1_BuenosAires_20180919_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T043814.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180919_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180919T095302.0Z 6836.411829 354 1 32.01 2 89.75 88.10 120.17 208.99 0.00 1 0.00 1 0 15 1.313e-01 1.206e-01 1.213e-01 1.157e-01 -1.026891e+04 6.681225e+03 8.352577e+02 -6.000000e+00 7.170195e+03 282.69 -2.00 20.00 -2.00 505.19 0.00e+00 4.501092e-03 3.172859e-03 1.579285e-04 -6.000000e+00 3.634855e-03 282.69 -2.00 20.00 -2.00 499.80 0.00e+00 7.939635e+00 2.373473e+00 7.183065e-02 -6.000000e+00 2.574955e+00 227.98 -2.00 3.16 -2.00 501.46 0.00e+00 20.103 0.076 489.00 513.00 1 9.3105e+00 1.8274e-01 3.1607e-02 -6.0000e+00 1.9715e-01 3.3581e-02 4.6653e-02 2.4763e-03 -6.0000e+00 5.1562e-02 5.2463e-06 2.9898e-03 1.0555e-02 7.8390e-05 -6.0000e+00 1.2913e-02 1.9161e-01 -1.1609e-03 12 8 8 10 0 0 48.57 21.25 2.88 0.19161 0.21235 8 2 1 4 0 4000.000 25.39 19.99 21.25 -11497 7563 -6461 12488 12548 -3652 -16045 -10341 -6632 -3472 14971 1985 18 17330 -3324 19616 -4786 -2311 21677 29603 -1204 -9987 11301 579 -7144 8353 6474 -2968 -12938 4889 3701 6193 -12323 4356 -2539 -1659 20252 -8458 3545 -23080 4295 22100 8320 12564 -2309 -566 -4080 -2006 17130 0 9666 -6985 30598 -22582 -1251 13891 5598 12362 6662 -4029 2455 14454 -725 -7953 2861 5947 -5005 6090 -7174 -4496 -7424 5828 8096 1549 8952 10175 -2539 8177 12388 10391 -9973 -3855 4546 -20102 -6687 1304 -10494 45030 -15899 -16531 12119 11111 -10733 -256 18790 5264 4437 32089 3107 -3689 -19375 -16427 -1195 17707 5266 18474 10749 -7073 10148 5044 1395 1027 4983 -9041 9762 -3282 7826 -7492 -14857 24046 -10267 23956 -8474 -3600 24560 5606 20810 -8397 16257 -7234 -5616 22390 21450 3205 1560 8534 -11870 -21063 5172 -19848 11075 14713 7368 11437 -10563 5220 -8180 39737 6620 3578 22153 8512 -30216 -13133 7352 -7484 12342 12706 -4438 -22357 -13655 -8381 -4190 14796 2202 20 16145 -3544 17956 -5320 -2568 19340 24620 -1366 -12383 11364 652 -8750 8779 6902 -3434 -16141 4953 3722 6087 -14908 4611 -2956 -1932 18834 -10360 3806 -32108 4547 19717 8619 12634 -2724 -659 -4905 -2335 16189 0 9354 -7763 22903 -28684 -1306 12813 5757 12057 6901 -4630 2635 13770 -806 -9501 3050 6070 -5601 5985 -7920 -4759 -7971 5420 7346 1511 8190 9231 -2430 6897 9835 8323 -9756 -3552 3867 -21943 -6399 1155 -10488 25854 -16792 -17576 9707 9057 -11031 -241 14917 4851 4152 22745 2907 -3609 -21561 -17350 -1076 13304 4554 14142 8838 -6819 8056 4147 1187 888 4239 -9100 8372 -3280 7100 -7966 -16955 18408 -10916 17830 -8649 -3496 18105 5046 16226 -8809 13367 -7094 -5433 17457 16876 2823 1374 7319 -11640 -22764 4382 -22112 9236 11975 6489 9690 -11205 4771 -8623 25979 5962 3247 16256 7041 -36889 SO 20180919T095707.0Z 6836.414664 358 1 32.01 2 88.90 87.52 120.55 208.02 0.00 1 0.00 1 0 15 1.625e-01 1.490e-01 1.732e-01 1.640e-01 -1.248876e+04 9.239946e+03 1.885389e+03 -6.000000e+00 8.876219e+03 282.69 -2.00 20.00 -2.00 505.16 0.00e+00 2.828707e-04 4.504965e-03 3.102050e-04 -6.000000e+00 4.497239e-03 282.69 -2.00 20.00 -2.00 500.00 0.00e+00 4.400942e+00 3.331612e+00 1.618668e-01 -6.000000e+00 3.177048e+00 227.98 -2.00 3.16 -2.00 501.68 0.00e+00 18.412 0.058 489.00 513.00 1 1.0228e+01 2.5864e-01 3.0596e-02 -6.0000e+00 2.4340e-01 7.8246e-02 6.5763e-02 1.9132e-03 -6.0000e+00 6.3396e-02 3.6631e-06 1.0220e-02 1.5701e-02 3.3619e-04 -6.0000e+00 1.5960e-02 1.6204e-01 -7.5790e-04 12 8 8 10 0 0 -79.13 21.25 -8.84 0.16204 0.23292 8 2 1 4 0 4000.000 25.39 20.00 21.25 -13024 26928 24507 -7900 4272 18197 13167 296 26318 4918 6790 -4927 -11765 653 4347 11656 9630 -33563 -63 14972 -5193 -371 934 17091 7470 -7348 -24050 9229 15432 5002 -20610 14151 27315 -18605 7433 -3493 17064 3840 20577 15354 -16924 -11016 6299 -8137 29838 29659 32669 10396 13926 -3858 -5810 -10176 12218 18430 25112 -4534 -2640 4163 890 7948 -9235 16165 -1091 12581 -15371 -11450 2863 1311 12708 -5592 -3482 -1541 3696 -16643 -2862 14033 -354 -6434 5908 -7898 13441 -21492 -17056 -3352 -12909 10552 -17362 -11231 27879 -4130 -15835 -7068 -19124 -6445 8394 -11054 5691 -971 -2825 24024 -9637 9643 -5828 -8942 24846 13566 2884 -2665 14778 27324 11809 37091 12321 14937 1770 29995 7995 12002 30443 -2306 42 7519 -418 -22429 9355 18286 -11173 4705 -3610 -12203 12589 22331 -22357 5599 -2825 5569 24428 47557 25526 566 8302 -24456 17005 23418 30712 14291 -23597 -23598 6224 11237 -11911 56851 5061 -15102 21640 20820 -9523 4659 17549 13454 343 23265 5307 7094 -5713 -14452 705 4541 11509 9950 -51067 -75 15298 -6498 -443 1104 17267 7764 -8819 -33758 9098 13890 4877 -25839 12737 22244 -24719 7726 -4043 15907 4033 18080 14149 -21580 -13338 6479 -9765 24618 24471 25904 10137 12833 -4133 -6163 -11012 10473 15008 19642 -4907 -2857 4238 935 7750 -10687 14550 -1169 11728 -18776 -13250 2822 1292 11030 -5752 -3470 -1503 3445 -19260 -2913 12029 -345 -6550 5254 -8040 11090 -25331 -18161 -3341 -13357 9271 -19010 -11620 20911 -4024 -17497 -7242 -22476 -6798 7757 -12547 5488 -995 -2895 18341 -10068 8234 -5854 -9431 18969 11583 2694 -2570 11727 18939 9609 23846 10396 12604 1742 22598 7549 10851 22630 -2340 41 6722 -403 -27037 8270 14879 -12234 4396 -3662 -13484 10876 17497 -27175 5062 -2725 4867 17668 27708 18975 551 7589 -31200 14349 18585 22830 12633 -28780 -28558 5815 9708 -11937 30268 4306 SO 20180919T100108.0Z 6836.417454 362 1 32.01 2 88.08 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