File name: Pandora114s1_BuenosAires_20180925_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T045015.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180925_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180925T094430.1Z 6842.405903 289 1 32.12 2 89.75 90.93 85.65 271.38 0.00 1 0.00 1 0 36 9.538e-02 9.560e-02 9.416e-02 9.200e-02 7.476359e+02 5.438875e+03 4.035239e+02 -6.000000e+00 5.218364e+03 282.95 -2.00 20.00 -2.00 505.31 0.00e+00 3.983484e-03 2.497275e-03 1.513109e-04 -6.000000e+00 2.641996e-03 282.95 -2.00 20.00 -2.00 500.17 0.00e+00 2.667722e+00 1.833499e+00 5.947666e-02 -6.000000e+00 1.861829e+00 228.12 -2.00 3.16 -2.00 501.81 0.00e+00 20.095 0.076 489.00 513.00 1 9.4588e+00 1.4038e-01 3.1295e-02 -6.0000e+00 1.4271e-01 9.9035e-02 3.6064e-02 1.7837e-03 -6.0000e+00 3.7061e-02 6.6605e-06 6.1621e-03 8.8231e-03 8.2097e-05 -6.0000e+00 9.3610e-03 5.3500e-02 5.1813e-05 12 8 8 10 0 0 27.25 21.83 7.75 0.05350 0.09624 8 2 1 4 0 4000.000 25.90 20.03 21.83 -19094 4261 2448 8302 3679 -4350 2590 -3797 7148 11863 380 9576 2021 -11987 -6857 8461 -413 4284 10002 23771 -11326 8165 9826 -8087 13989 -430 -3994 -23569 16163 -18162 -5000 17494 -2913 16849 11576 -2787 -1527 -7013 8618 -10806 10072 6802 6341 -1935 -9808 -5618 6869 6701 754 16972 10161 -9605 -98 -11776 17338 -5555 2803 -3996 -14092 -6754 1448 9495 -1108 10399 11502 -3849 -9791 7511 14716 14817 6999 24352 5941 -6053 10077 -5781 -14236 1493 -1763 -4809 7126 -6854 4754 -14063 6076 4183 12435 -5109 6255 2331 -10651 -9085 9707 15075 2861 13503 3671 -794 6908 -671 2448 -2215 -455 1589 893 -3220 9094 11194 -7586 -7759 -7746 6596 -1217 1834 -8431 -2590 -16278 8485 2735 15081 -731 11654 10381 7833 -4971 10797 -17271 2270 4126 -18987 -2897 -9583 -3970 8896 15433 132 -14266 3223 3467 545 15522 16423 8062 3161 3120 -5150 1363 6282 9876 5578 -7404 -3352 -11525 -22999 4199 2538 8342 3957 -5155 2886 -4500 7505 11691 414 9376 2108 -14284 -7773 8338 -455 4608 10308 21436 -13549 8050 9570 -9481 13204 -468 -4466 -31455 14089 -21728 -5200 14724 -3099 15194 11204 -3117 -1670 -8010 8341 -12668 9627 6788 6442 -2164 -11970 -6586 7062 6808 798 14897 9285 -10451 -96 -13097 14801 -6144 2915 -4492 -17536 -7796 1541 9361 -1219 10190 11063 -4258 -11301 7179 12917 12827 6480 18885 5572 -6477 9269 -6221 -16432 1445 -1738 -4857 6383 -6644 4401 -14821 5274 3725 10232 -5010 5464 2115 -11045 -9370 8425 12574 2709 11416 3372 -748 5879 -602 2083 -1960 -400 1406 821 -3139 7842 9337 -7524 -7653 -7684 5762 -1173 1747 -9028 -2642 -19174 7843 2682 13005 -730 10115 9010 6931 -5015 9371 -19955 2162 3861 -22365 -2906 -10262 -3983 7721 12351 122 -15277 2943 3224 532 13210 13976 7497 3100 3077 -5218 1294 5632 8382 4823 -7148 -3094 -11677 SO 20180925T094829.0Z 6842.408669 293 1 32.01 2 88.92 90.36 86.45 270.84 0.00 1 0.00 1 0 22 5.887e-02 5.829e-02 5.954e-02 5.860e-02 8.985211e+03 3.998229e+03 4.913993e+02 -6.000000e+00 3.220035e+03 282.95 -2.00 20.00 -2.00 505.25 0.00e+00 -1.350056e-03 1.577760e-03 1.553573e-04 -6.000000e+00 1.630293e-03 282.95 -2.00 20.00 -2.00 500.18 0.00e+00 9.564863e-01 1.155656e+00 9.898857e-02 -6.000000e+00 1.148807e+00 228.12 -2.00 3.16 -2.00 501.79 0.00e+00 18.455 0.059 489.00 513.00 1 9.4165e+00 8.7973e-02 2.9076e-02 -6.0000e+00 8.8055e-02 9.9630e-02 2.2907e-02 2.4737e-03 -6.0000e+00 2.2871e-02 1.0674e-05 -7.3468e-03 5.2873e-03 6.0351e-05 -6.0000e+00 5.7785e-03 1.3428e-01 -4.4759e-04 12 8 8 10 0 0 94.92 21.84 3.07 0.13428 0.08332 8 2 1 4 0 4000.000 25.90 19.98 21.84 -1940 -6938 -1762 -1362 1532 2559 1934 -6692 11081 1275 6632 2264 -1218 5801 6572 -7063 -4521 1707 3746 101 -3564 -5099 735 -3356 7809 -3355 12193 -16530 -1383 3752 -1793 8055 6388 2519 -2550 3238 2971 5483 8673 -2813 3509 -1959 -1212 2595 -10068 1551 -3080 1050 -878 6493 765 -9621 8387 -9598 8801 -2409 1562 1596 -2017 -1442 3343 4200 2788 5297 -4432 8449 287 -2044 -1987 1716 3729 10760 697 3670 -3535 4551 -4739 -11198 3430 -5153 -3805 -9575 -5347 -7726 8386 -6404 10345 9293 12699 -3041 -4229 7833 -50 7077 7816 -1528 5493 -1769 -5489 -9129 5467 881 1009 -435 1901 260 2850 -2808 -6982 -8942 -4545 -5216 7716 2026 4241 930 2970 -2886 -1995 -3947 1803 7181 9167 -3449 1236 13512 6705 7444 1778 3931 325 -7607 11418 -5440 304 7939 -594 -11745 -6660 11710 -3448 -8960 -1786 -9433 -1218 3136 3755 4958 -3892 7451 -3972 5037 2648 -1966 -7572 -1887 -1497 1678 2646 2044 -7764 10735 1348 6551 2306 -1269 5576 6241 -7735 -4916 1791 3944 112 -4108 -5974 813 -3881 8104 -3893 12045 -21519 -1515 3792 -1874 7618 6262 2653 -2910 3533 3242 5773 8734 -3145 3668 -2167 -1341 2792 -12413 1710 -3550 1150 -965 6489 788 -10684 7611 -10363 8020 -2528 1621 1686 -2225 -1579 3482 4070 2752 5115 -4710 7825 284 -2040 -1954 1607 3387 9038 648 3346 -3515 4215 -4797 -11899 3091 -4994 -3620 -9659 -5202 -7765 7255 -6506 8987 8206 10849 -3035 -4266 7029 -49 6529 7183 -1525 4989 -1677 -5241 -8815 4475 746 859 -385 1720 250 2752 -2893 -7444 -9598 -4633 -5374 7063 1986 4095 931 2922 -3025 -1968 -4001 1724 6831 8392 -3309 1119 10820 5777 6388 1616 3493 299 -7556 9335 -5202 271 6464 -525 -11746 -6457 9653 -3367 -9384 -1762 -10135 -1214 3009 3591 4673 -3971 6671 -3905 4459 2398 SO 20180925T095235.0Z 6842.411516 297 1 32.01 2 88.08 89.78 87.28 270.28 0.00 1 0.00 1 0 15 3.192e-02 3.172e-02 3.169e-02 3.147e-02 3.604497e+03 1.950535e+03 1.130306e+02 -6.000000e+00 1.746080e+03 282.95 -2.00 20.00 -2.00 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