File name: Pandora114s1_BuenosAires_20180930_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T044927.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20180930_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20180930 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180930T093726.0Z 6847.400995 289 1 32.00 2 89.75 93.29 58.48 332.25 0.00 1 0.00 1 0 47 9.293e-01 5.353e-01 7.122e-01 4.942e-01 -2.503813e+04 3.177789e+04 1.573062e+03 -6.000000e+00 5.291939e+04 283.16 -2.00 20.00 -2.00 505.51 0.00e+00 8.785045e-03 1.489323e-02 4.887089e-04 -6.000000e+00 2.604663e-02 283.16 -2.00 20.00 -2.00 499.88 0.00e+00 1.923007e+01 1.071555e+01 2.996802e-01 -6.000000e+00 1.890945e+01 228.23 -2.00 3.16 -2.00 501.69 0.00e+00 20.096 0.076 489.00 513.00 1 9.8279e+00 8.2543e-01 4.0767e-02 -6.0000e+00 1.4411e+00 -1.8680e-01 2.0367e-01 6.2854e-03 -6.0000e+00 3.8271e-01 9.5790e-07 5.4521e-03 4.0394e-02 1.8989e-04 -6.0000e+00 9.5507e-02 -1.9840e-01 1.8406e-03 12 9 8 11 8 0 63.00 21.83 -18.88 -0.19840 -0.16058 8 2 1 4 0 4000.000 25.90 19.97 21.83 133888 81690 -19526 173319 -25622 149065 -8333 197048 47876 33640 -53549 23495 -3318 -39399 26412 24160 56572 32793 26954 96855 -44956 39716 15931 34063 34958 -4143 93365 4081 4112 100555 30488 -22938 181681 54987 -14807 157925 170327 37947 53840 -24221 41738 -33997 13753 -43319 900000 28564 367864 19728 -4710 900000 -28618 176845 14738 115797 21188 30942 53170 -6072 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63428 63109 -15918 16690 -7118 9606 -26867 37054 61696 66886 89581 -45218 20104 51368 34428 71212 -36997 48251 32048 900000 19049 39769 -1968 805 19958 -162726 76453 28190 52306 -33594 -11897 15929 23597 5262 30186 85058 -2581 37468 22069 -32191 900000 27603 22746 -23113 128438 73633 72639 106036 59374 9614 15662 65234 413 25301 -82588 680 44449 -51129 900000 14875 -3539 40779 -8746 35234 -45708 21956 65259 104974 85943 -63135 -20581 -11789 37359 -49467 35920 -400 -42086 900000 -47568 81427 -20550 51810 20321 17178 43475 24662 900000 -4780 20920 -9485 900000 SO 20180930T094130.0Z 6847.403819 293 1 32.00 2 88.91 92.72 58.87 331.25 0.00 1 0.00 1 0 29 7.036e-01 3.967e-01 5.826e-01 3.962e-01 -2.984282e+04 2.210776e+04 2.544587e+03 -6.000000e+00 3.920925e+04 283.16 -2.00 20.00 -2.00 505.04 0.00e+00 1.426361e-02 1.153719e-02 2.728140e-04 -6.000000e+00 1.976376e-02 283.16 -2.00 20.00 -2.00 499.89 0.00e+00 6.390311e+00 8.382070e+00 6.213099e-02 -6.000000e+00 1.435221e+01 228.23 -2.00 3.16 -2.00 501.54 0.00e+00 18.422 0.059 489.00 513.00 1 1.0705e+01 6.4873e-01 2.9092e-02 -6.0000e+00 1.0949e+00 7.8189e-02 1.7117e-01 2.8329e-03 -6.0000e+00 2.8946e-01 1.3015e-06 -6.0762e-02 2.6113e-02 4.9131e-04 -6.0000e+00 7.0203e-02 2.3953e-01 -2.0672e-03 12 8 8 10 0 0 27.07 21.85 -0.43 0.23953 -0.18193 8 2 1 4 0 4000.000 25.90 20.01 21.85 52785 -28082 95902 -1266 65566 14021 -2513 20914 10540 106630 32543 7019 6190 -4308 22305 26077 36919 9321 97518 -1445 104803 -30408 26458 62175 -40494 43120 -16962 40691 38486 -47671 36265 52478 30397 -5914 -30254 -3079 10496 137413 16548 41885 56166 9662 27308 39224 1212 -44041 42457 44433 81942 -11196 -30755 21452 60820 101566 -26827 54238 60139 197910 -2606 -2200 28142 7516 138541 34572 82670 6573 44257 318650 11683 73395 -11562 50442 26387 900000 130217 -23579 136482 -18776 120589 -56627 129010 -34965 -14782 17717 89618 900000 -15616 900000 33237 -10079 16722 -30609 900000 -12894 153022 21207 4110 73591 -30982 115441 -32380 61990 93207 -12234 57423 21265 115901 -31404 61032 -6204 16405 -3193 64079 171016 -18261 186567 7602 23278 11683 9320 53680 45333 157904 19360 45728 18677 -8506 29591 14569 143095 107041 107666 21488 900000 -37613 19977 109529 -54165 154805 68859 900000 30820 -7729 7500 40775 118218 -13027 44490 1923 85968 17643 8506 8121 39503 -45147 42531 -1438 38164 13991 -3065 20869 11978 47289 30669 8560 7549 -5731 22257 24575 30700 10076 43248 -1723 43574 -49728 24935 41361 -70188 34661 -23257 33836 30865 -91260 30021 36656 25950 -7038 -44612 -3425 10319 53323 16267 32507 37779 10248 24019 30442 1379 -79755 32951 34485 44517 -15641 -52512 21643 40909 44668 -41641 36482 37339 76799 -3034 -2618 25482 8556 53761 30409 44912 7652 35493 123653 12996 43671 -15853 36538 23893 900000 50531 -33549 52962 -25259 46795 -112802 50062 -55177 -18738 16042 39413 900000 -19795 900000 25795 -11994 15141 -41572 900000 -14698 59380 18653 4086 39980 -46587 44797 -54188 42097 47472 -17803 40388 20630 44975 -48745 37006 -7222 14722 -3330 32637 66363 -20372 72398 6822 18631 11051 9494 36453 34083 61275 18312 32163 16760 -9902 23683 13780 55528 41538 41780 19804 900000 -62945 18895 42503 -107722 60073 38411 900000 23920 -8810 7458 29668 45875 -16429 31292 2052 39615 16261 8665 8272 SO 20180930T094532.0Z 6847.406620 297 1 32.00 2 88.08 92.15 59.28 330.27 0.00 1 0.00 1 0 39 3.847e-01 2.563e-01 3.719e-01 3.018e-01 2.160516e+04 2.370318e+04 1.017632e+03 -6.000000e+00 2.106795e+04 283.16 -2.00 20.00 -2.00 505.30 0.00e+00 2.424264e-03 8.130639e-03 2.393788e-04 -6.000000e+00 1.066755e-02 283.16 -2.00 20.00 -2.00 500.24 0.00e+00 -1.023797e+00 6.024079e+00 1.346810e-01 -6.000000e+00 7.531108e+00 228.23 -2.00 3.16 -2.00 501.84 0.00e+00 16.253 0.040 489.00 513.00 1 1.1420e+01 4.5539e-01 2.6979e-02 -6.0000e+00 5.7705e-01 9.1999e-02 1.1731e-01 3.2290e-03 -6.0000e+00 1.5031e-01 1.9095e-06 -1.3244e-02 2.4556e-02 1.4086e-04 -6.0000e+00 3.7835e-02 -1.4189e-02 2.9648e-04 12 8 8 10 0 0 10.61 21.85 3.48 -0.01419 -0.10605 8 2 1 4 0 4000.000 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