File name: Pandora114s1_BuenosAires_20181003_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T044950.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181003_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181003 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181003T093317.0Z 6850.398113 336 1 32.00 2 89.75 94.70 58.54 19.93 0.00 1 0.00 1 0 22 1.504e-01 1.300e-01 1.276e-01 1.221e-01 1.107135e+04 8.507950e+03 1.046019e+03 -6.000000e+00 8.236985e+03 283.29 -2.00 20.00 -2.00 505.29 0.00e+00 -1.345024e-05 3.315873e-03 8.407401e-05 -6.000000e+00 4.171083e-03 283.29 -2.00 20.00 -2.00 500.28 0.00e+00 -3.155538e+00 2.419568e+00 2.808517e-02 -6.000000e+00 2.948603e+00 228.30 -2.00 3.16 -2.00 501.89 0.00e+00 20.086 0.076 489.00 513.00 1 1.0218e+01 1.8427e-01 3.0861e-02 -6.0000e+00 2.2586e-01 1.9151e-01 4.8477e-02 1.8482e-03 -6.0000e+00 5.8975e-02 4.9399e-06 -8.0421e-03 1.1127e-02 1.5068e-04 -6.0000e+00 1.4793e-02 6.0991e-02 -2.9451e-04 12 8 8 10 0 0 93.57 21.07 9.30 0.06099 0.00521 8 2 1 4 0 4000.000 25.28 20.00 21.07 -9936 14689 -13111 1738 -13696 -8720 7515 4465 19772 6754 -1061 -1050 -14185 18719 -3915 13921 -9675 19113 239 -316 20188 11477 5762 -18588 12825 2569 8563 74634 -8336 20090 -15954 10429 -16272 6282 -7366 13452 -6222 1006 29579 -3571 3509 -7031 -8487 -4565 -16941 11440 -18332 5493 -1086 10730 30276 -20540 -1844 -3129 36840 -1605 3997 949 -10098 1028 -10584 22194 3044 17738 -5760 9025 12150 -12124 15486 -5364 10690 8069 -11830 13938 -10328 6408 -2634 185 -10526 27822 -6104 14969 21249 8129 25214 -14002 -5635 17218 24110 16520 -12510 28862 21781 28838 -4597 -3538 5108 -13386 3034 -6223 16295 14741 -1314 -10904 4993 22624 -6469 8212 13091 -11834 6797 -21265 -8758 -8262 -2522 19276 8480 -10702 -16946 4930 -20410 25353 -3110 -3863 994 -5719 -336 5506 8829 -9563 9959 23165 -12871 -6902 496 10756 -5871 34565 -4198 -3064 1672 688 31104 -5478 27460 -8022 17732 3458 -9656 -4924 -11353 16323 -4106 -10701 12555 -15242 1798 -16976 -10509 7837 4847 18421 7101 -1188 -1158 -17581 16480 -4283 12732 -11329 17154 266 -360 18809 11674 6206 -23875 12936 2685 8403 40191 -9444 16669 -18456 9152 -18824 5964 -8286 12556 -7098 1059 23126 -3846 3499 -7797 -9615 -5026 -21354 10952 -23693 5566 -1161 10016 22705 -24907 -1810 -3071 24394 -1601 3890 977 -11762 1074 -12413 18768 3133 15850 -6525 8784 11341 -14219 13590 -5735 9637 7403 -13213 12121 -11618 6186 -2795 189 -11757 20864 -6379 12659 16952 7458 19713 -15394 -5774 15109 19812 14629 -13847 22565 18419 23007 -4847 -3678 4775 -14617 2723 -5957 12187 11025 -1150 -10684 4332 17259 -6871 7677 11652 -13365 6304 -26083 -9563 -9084 -2641 16291 7991 -12246 -20785 4904 -26256 20479 -3279 -4016 966 -5903 -329 5106 7924 -10299 8789 17846 -14150 -7072 463 8930 -5708 22491 -4081 -3002 1588 668 22565 -5777 20949 -8760 14986 3362 -9992 -4783 -11508 13063 -3758 SO 20181003T093717.0Z 6850.400891 340 1 32.01 2 88.92 94.13 58.27 18.91 0.00 1 0.00 1 0 22 7.496e-02 7.297e-02 7.397e-02 7.275e-02 6.117740e+03 4.937075e+03 1.696539e+02 -6.000000e+00 4.106185e+03 283.29 -2.00 20.00 -2.00 505.29 0.00e+00 -8.462557e-04 1.989129e-03 1.041302e-04 -6.000000e+00 2.078180e-03 283.29 -2.00 20.00 -2.00 500.38 0.00e+00 9.124966e-01 1.444259e+00 1.718061e-01 -6.000000e+00 1.464972e+00 228.30 -2.00 3.16 -2.00 501.97 0.00e+00 18.445 0.059 489.00 513.00 1 9.6477e+00 1.1045e-01 3.0630e-02 -6.0000e+00 1.1228e-01 7.7728e-02 2.8082e-02 2.9955e-03 -6.0000e+00 2.9201e-02 8.4798e-06 1.7342e-03 6.7806e-03 5.3440e-05 -6.0000e+00 7.3623e-03 6.0512e-02 -7.4347e-05 12 8 8 10 0 0 95.81 21.07 5.71 0.06051 0.07254 8 2 1 4 0 4000.000 25.28 19.98 21.07 7384 -14513 10809 2105 1567 259 2023 10207 8606 -1322 -2219 5207 -3730 -10454 -3227 -5849 -2242 2326 -4174 7244 -3410 6681 1352 9733 1188 3305 -3118 -10408 2937 1093 -5093 1231 -430 -2437 2272 8533 -5849 7240 11479 6766 564 -717 -9169 -7248 -424 10930 2966 -443 -7339 3350 -8140 4840 11788 -15633 8749 -2435 5840 2540 2400 -2273 4952 -4636 -1548 883 55 10383 -7316 3438 8171 149 -3220 3093 160 -5063 12015 9957 -5758 -5734 8294 -3102 -8382 1012 5857 -9750 2497 6695 5626 20907 -5042 -4257 1425 5481 -15450 -5393 -16516 -13892 -12504 8294 23219 -2584 5931 1545 1782 2967 16245 4590 -79 4780 6445 -804 -129 5903 -3652 1097 19991 1541 -10482 -10612 -6293 -3987 1266 1067 9505 10065 1965 -4752 12060 -3993 10306 -1971 4689 4086 -1590 7774 4803 18058 3649 5104 -7997 -1698 3514 -6628 5370 -1673 2789 -13316 5241 6133 -787 -11273 9611 -6245 -142 6544 -16486 9856 2155 1652 282 2195 10242 8724 -1461 -2442 5252 -4066 -12088 -3237 -6090 -2302 2344 -4584 7164 -3761 6670 1427 9486 1265 3441 -3439 -12173 2932 1080 -5278 1206 -439 -2630 2398 8519 -6702 7194 10806 6626 587 -761 -10680 -8373 -462 10653 3116 -476 -8304 3329 -8823 4487 10032 -17541 7862 -2524 5719 2609 2476 -2453 4968 -5136 -1670 932 58 9823 -8139 3383 7575 148 -3277 2941 157 -5320 10796 9184 -5774 -5648 6987 -2904 -8256 911 5064 -9952 2281 5939 5091 16308 -5102 -4269 1353 5032 -17697 -5648 -19360 -15665 -13598 7135 16765 -2361 4891 1322 1541 2618 13105 4317 -80 4559 5975 -792 -126 5472 -3776 1095 16662 1552 -11961 -12204 -6984 -4337 1298 1079 8685 9017 1900 -4935 10643 -4147 9279 -1885 4452 3668 -1500 6999 4388 14326 3350 4686 -8051 -1638 3273 -6923 5024 -1691 2714 -15306 5013 5788 -785 -12247 8306 -6261 -135 SO 20181003T094114.0Z 6850.403634 344 1 32.01 2 88.11 93.58 58.02 17.89 0.00 1 0.00 1 0 29 6.971e-03 6.885e-03 2.317e-03 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