File name: Pandora114s1_BuenosAires_20181025_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T051423.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181025_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181025T090520.0Z 6872.378704 269 1 32.01 2 89.75 104.61 82.37 288.77 0.00 1 0.00 1 0 57 1.367e-01 1.224e-01 1.166e-01 1.117e-01 1.018123e+04 7.821455e+03 3.531842e+02 -6.000000e+00 7.521530e+03 284.31 -2.00 20.00 -2.00 505.32 0.00e+00 7.739460e-04 3.041590e-03 7.819111e-05 -6.000000e+00 3.800765e-03 284.31 -2.00 20.00 -2.00 499.98 0.00e+00 1.955201e+00 2.203441e+00 2.061517e-02 -6.000000e+00 2.670649e+00 228.72 -2.00 3.16 -2.00 501.66 0.00e+00 20.066 0.076 489.00 513.00 1 9.7598e+00 1.6974e-01 3.0799e-02 -6.0000e+00 2.0479e-01 1.0978e-01 4.2498e-02 1.7543e-03 -6.0000e+00 5.3191e-02 5.3301e-06 1.8070e-02 1.0185e-02 4.8243e-05 -6.0000e+00 1.3428e-02 -2.0375e-02 4.7336e-04 12 8 8 10 0 0 95.72 21.48 7.52 -0.02037 0.10496 8 2 1 4 0 4000.000 25.58 20.00 21.48 -14774 3443 -3110 -10625 -2814 6790 -5135 -11994 171 12747 9811 3985 15784 2854 -13321 12800 4768 8250 -3845 -5542 5853 -5242 -7899 6885 13352 -1291 10547 2952 -659 3472 -10594 13396 -5387 -12065 -6551 17772 5422 14613 1387 -10980 17548 -9416 24643 253 -8847 130 945 10553 16853 -23184 -2450 -9032 21898 -4815 14780 85 12415 18233 6504 15444 282 4156 20290 5241 5522 2469 -1296 -9439 4862 -1492 -19981 24595 -16068 12939 1031 5211 -19178 13649 -4071 -9481 -645 -16792 19848 -11722 11507 -5857 2960 1201 -16248 19310 -5303 36320 20986 51672 41833 29469 8725 -10573 -13673 -14759 -14061 -429 9697 -2086 2657 -6731 -1816 -14246 -3959 -1243 13763 7033 3599 13559 5317 -2878 20019 8223 -7827 21071 -19587 23749 9322 19709 18308 -16227 125 -12672 17476 -9693 25238 2001 1271 -8120 -8837 28990 -5553 -7560 -10907 10480 12628 -14301 16836 -18136 -3162 8640 5918 360 -19272 11326 6529 20259 -2820 -17558 3526 -3502 -13209 -3300 7327 -6263 -15567 194 12558 9819 4176 14562 2990 -16561 12510 5182 8837 -4690 -6890 6498 -6517 -9453 7135 12959 -1441 10314 3037 -683 3395 -11983 12219 -6133 -15055 -7793 16471 5618 13649 1467 -13141 15879 -11268 21220 280 -10782 144 1027 10242 15004 -29946 -2503 -9689 17258 -5059 13158 90 11778 16366 6549 14201 303 4306 17916 5354 5561 2523 -1352 -10539 4648 -1503 -24059 19025 -18878 11519 1039 4982 -22952 11554 -4070 -9963 -622 -19116 15788 -12917 10161 -5810 2873 1109 -17786 15782 -5225 25444 17305 31297 27475 21290 7044 -10054 -13095 -14035 -13179 -355 7496 -1898 2400 -6815 -1752 -15399 -3819 -1165 11205 6207 3324 11409 4875 -2875 16024 7483 -8407 16866 -23182 17872 7971 15102 14279 -17984 118 -13611 13869 -10080 18475 1834 1156 -8000 -8706 19635 -5395 -7654 -11641 9177 10972 -16437 14282 -21962 -3310 8039 5628 357 -21467 9686 5806 15800 -2651 SO 20181025T090920.0Z 6872.381481 273 1 32.00 2 88.95 104.05 83.13 288.19 0.00 1 0.00 1 0 54 1.057e-01 9.798e-02 1.030e-01 9.934e-02 2.459648e+03 6.437771e+03 6.008198e+02 -6.000000e+00 5.814614e+03 284.31 -2.00 20.00 -2.00 505.30 0.00e+00 4.549536e-03 2.733963e-03 1.940359e-04 -6.000000e+00 2.939831e-03 284.31 -2.00 20.00 -2.00 499.86 0.00e+00 4.741004e+00 2.021780e+00 1.219233e-01 -6.000000e+00 2.070664e+00 228.72 -2.00 3.16 -2.00 501.53 0.00e+00 18.495 0.059 489.00 513.00 1 9.6217e+00 1.5545e-01 2.9488e-02 -6.0000e+00 1.5869e-01 6.2559e-02 3.9573e-02 2.0866e-03 -6.0000e+00 4.1374e-02 6.0281e-06 1.2196e-02 9.3352e-03 9.8241e-05 -6.0000e+00 1.0400e-02 9.6075e-02 -4.3096e-04 12 8 8 10 0 0 87.03 21.47 9.62 0.09608 0.18067 8 2 1 4 0 4000.000 25.68 20.00 21.47 -1670 10058 -8713 -2513 -952 6162 8740 -7115 3329 1707 -1643 -4823 6133 -2288 3796 2640 1160 964 -142 -11513 -3783 2263 14251 -4101 11326 -6170 -6546 1844 9855 -4233 19786 9649 -7149 1759 -1349 -3165 7757 5300 6945 14774 -13450 -16946 549 -13345 -856 -237 6050 2781 -12126 -10949 10184 16626 11336 13913 -7456 -3979 22982 5409 -12266 18347 -3227 14558 -2634 6733 -8251 13496 610 203 6574 -6296 7442 -11418 17120 -8626 -1143 3594 7379 11879 -19119 6714 8725 -12909 13913 -3961 6834 -7842 7542 -6631 19885 11780 2720 8598 -5259 14163 3083 6744 -562 4624 19067 -7858 3495 -13098 7960 -3034 3581 -8336 1373 13948 -7691 -1080 1701 -2004 7494 -2736 25089 11545 10866 -18475 -3082 -16454 -2831 6665 -9834 776 -19556 29012 14 1634 -1402 518 -4370 -15461 14794 -14 -11949 13458 -7215 13481 -3350 20492 -3715 13392 -3865 3306 43207 2540 9545 -18224 5578 -2419 -2324 14433 -5527 -1742 9654 -10424 -2902 -1106 6771 9422 -8957 3728 1912 -1874 -5602 6313 -2547 3986 2846 1212 1033 -156 -14200 -4322 2439 13692 -4765 11323 -7330 -7734 1963 9404 -4534 16569 9082 -8214 1907 -1533 -3657 7956 5505 7033 13811 -16765 -22112 609 -17239 -984 -271 6441 3015 -14956 -13008 9520 14247 10156 12283 -8374 -4443 19992 5653 -15289 16793 -3666 13893 -2993 6950 -9802 12704 641 211 6316 -6785 6908 -12749 14448 -9519 -1180 3523 6850 10333 -20944 6015 7646 -13198 10923 -3736 5823 -7779 6426 -6498 14886 9535 2417 7274 -5185 11636 2833 5910 -520 3968 13809 -7269 2829 -12435 6201 -2715 3095 -8269 1237 10950 -7396 -966 1490 -1854 6431 -2647 18628 9907 9457 -21701 -3114 -18926 -2809 5922 -10174 718 -22257 20481 13 1532 -1357 491 -4361 -16207 12065 -13 -11635 10730 -7113 10994 -3303 16213 -3575 11655 -3786 3030 28400 2371 8310 -20773 4920 -2259 -2130 11161 -5287 SO 20181025T091323.0Z 6872.384294 277 1 32.00 2 88.14 103.48 83.91 287.62 0.00 1 0.00 1 0 43 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