File name: Pandora114s1_BuenosAires_20181027_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T051438.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181027_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181027 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181027T090307.0Z 6874.377164 269 1 32.00 2 89.76 105.45 69.20 312.08 0.00 1 0.00 1 0 15 9.553e-02 9.233e-02 1.112e-01 1.081e-01 3.463657e+03 6.819629e+03 6.263220e+02 -6.000000e+00 5.258495e+03 284.41 -2.00 20.00 -2.00 505.18 0.00e+00 -6.792711e-04 2.907376e-03 6.930102e-05 -6.000000e+00 2.661638e-03 284.41 -2.00 20.00 -2.00 499.92 0.00e+00 -1.057601e-02 2.184197e+00 5.676818e-02 -6.000000e+00 1.881937e+00 228.75 -2.00 3.16 -2.00 501.56 0.00e+00 20.069 0.076 489.00 513.00 1 9.9120e+00 1.6653e-01 3.0962e-02 -6.0000e+00 1.4404e-01 1.7406e-01 4.4334e-02 1.7285e-03 -6.0000e+00 3.7886e-02 5.5330e-06 -1.0089e-03 1.0167e-02 8.5826e-05 -6.0000e+00 9.4227e-03 -4.4988e-02 8.6764e-04 12 8 8 10 0 0 -110.54 21.41 15.88 -0.04499 -0.05199 8 2 1 4 0 4000.000 25.58 19.99 21.41 848 -11488 3246 9621 2593 10747 -2967 7021 -4882 19599 539 -203 17827 -14490 -15810 1969 -4560 -3292 7825 14233 2554 -1296 -7272 16981 10598 8880 1328 2961 5077 -3277 4401 5908 -8296 7547 -8853 5995 -4477 -7593 -5779 3915 4512 2277 -18590 2851 -9511 5723 8547 22388 -5975 2163 668 -4781 -10331 -2349 15372 -1222 11255 -11664 3193 -6911 13746 -9185 -15294 5665 5109 8214 -3184 758 4539 -969 6113 -2406 -4620 12355 -6702 379 -2157 -12013 -6246 -9045 -7082 531 22716 11544 5566 23975 10488 17272 10074 -5724 -5428 -4634 11556 11083 7449 12294 4985 -5225 -14296 -2235 13593 -5371 13527 -11204 5283 -16195 1229 -905 -10870 -1550 -10938 2833 5655 -1510 -670 -4778 4307 9053 13140 -8806 2384 -12263 4601 -920 18885 4197 -4628 13717 -2807 4666 -7454 1157 -10052 -759 7484 17484 15892 -2503 -16997 11184 4236 21892 208 16312 -17092 7187 7884 -6594 3954 3048 6208 -7034 900000 859 -13560 3414 9755 2884 11222 -3592 7704 -5984 18537 608 -227 16456 -18311 -20217 2131 -5383 -3935 8526 14647 2760 -1456 -8680 15950 10628 9030 1444 3116 5092 -3472 4258 5675 -9433 7569 -10691 6266 -5153 -8902 -6570 4009 4588 2380 -24157 3020 -11486 5941 8571 19290 -6709 2184 665 -4896 -11017 -2323 13027 -1260 10492 -13839 3270 -7809 12620 -10639 -18901 5681 5124 7889 -3373 760 4328 -965 5612 -2395 -4731 10820 -7194 380 -2193 -13235 -6396 -9454 -7252 506 17486 10027 4864 18794 8888 13723 8604 -5723 -5426 -4633 9946 9686 6757 10501 4489 -5085 -14860 -2012 10260 -4872 10299 -11275 4687 -18335 1180 -881 -11515 -1477 -11442 2607 5130 -1490 -661 -4935 4077 8212 11483 -9562 2289 -13396 4173 -871 14629 3779 -4565 11261 -2714 4170 -7502 1065 -10250 -693 6193 12965 11995 -2303 -18455 9330 3842 16814 199 13392 -18532 6519 6681 -6410 3400 2583 4990 -6399 900000 SO 20181027T090707.1Z 6874.379943 273 1 32.12 2 88.96 104.89 69.80 311.34 0.00 1 0.00 1 0 29 7.708e-02 7.501e-02 7.615e-02 7.406e-02 6.800707e+02 4.379112e+03 1.705300e+02 -6.000000e+00 4.240069e+03 284.41 -2.00 20.00 -2.00 505.16 0.00e+00 -5.550312e-04 2.010988e-03 7.273223e-05 -6.000000e+00 2.143408e-03 284.41 -2.00 20.00 -2.00 499.87 0.00e+00 3.990998e+00 1.504968e+00 3.096941e-02 -6.000000e+00 1.509200e+00 228.75 -2.00 3.16 -2.00 501.50 0.00e+00 18.510 0.059 489.00 513.00 1 9.4568e+00 1.1504e-01 2.7950e-02 -6.0000e+00 1.1567e-01 7.9690e-02 3.0375e-02 1.6334e-03 -6.0000e+00 3.0153e-02 8.1578e-06 -1.9323e-02 6.9184e-03 4.1210e-05 -6.0000e+00 7.5802e-03 9.5376e-02 -4.2208e-04 12 8 8 10 0 0 82.99 21.41 0.95 0.09538 -0.03866 8 2 1 4 0 4000.000 25.68 20.00 21.41 -3667 12874 -11101 7104 5123 -5262 14343 3788 6788 6504 -2270 -1933 12452 8653 -11921 17805 -7945 2851 -3079 -1565 1454 8583 655 -2173 4172 636 5008 -12251 -1839 -1447 71 8818 -5068 6497 -11603 5174 -4619 -6538 8225 11667 -8441 -9277 16928 5869 -2445 3662 2303 10679 -4977 -2867 -10887 4879 -2820 -3698 -2525 218 1038 -10391 -8225 -1266 3954 378 -4499 6220 -1443 -3071 5547 -6493 -2445 -249 17233 2025 14404 2967 11770 -5536 -7414 2913 -760 -14625 -1024 -1038 13136 1132 3913 -3319 554 5959 20373 -5677 -11107 14721 -1426 -2361 -7920 -1671 962 -6252 1276 -8095 -4360 -3141 987 3719 4579 -928 2872 5639 -12904 6714 2615 817 14079 -15988 14806 -10015 4225 11967 -7390 10852 707 8284 -11769 -4146 -234 8823 9692 8194 -5075 -5896 7533 -514 7432 8745 15338 11541 -3227 -2788 452 -2970 746 -2025 -1471 -11651 1545 4498 -11681 255 7202 5374 5900 6057 7411 -3841 11481 -12893 7109 5392 -6302 14428 4301 7532 7217 -2538 -2275 12526 8333 -13961 15424 -8959 2939 -3457 -1773 1618 8930 738 -2524 4563 723 5453 -15771 -2109 -1618 76 8450 -5568 6477 -14319 5559 -5543 -7973 8558 11575 -10131 -11179 15729 6135 -2804 3987 2552 10853 -5853 -3247 -13066 4864 -2948 -3812 -2554 217 1055 -12170 -9593 -1385 4095 404 -5052 6291 -1578 -3404 5583 -7259 -2580 -253 14511 1960 12199 2638 10309 -5476 -7535 2656 -707 -15328 -924 -933 10250 1001 3391 -3117 505 5191 15436 -5589 -11539 11821 -1353 -2281 -8193 -1638 917 -6326 1175 -8006 -4055 -2821 838 3071 3823 -846 2606 5066 -13934 5879 2349 741 11242 -17481 12091 -10633 3930 10370 -7812 9601 693 7480 -12815 -4120 -221 7565 8267 7138 -4768 -5590 6240 -461 6156 7133 11593 8920 -2853 -2441 386 -2676 662 -1885 -1382 -12239 1432 4072 -12520 244 6427 4842 5190 5199 6171 SO 20181027T091112.0Z 6874.382778 277 1 32.01 2 88.15 104.31 70.43 310.58 0.00 1 0.00 1 0 22 8.380e-02 8.003e-02 7.001e-02 6.796e-02 4.102556e+03 4.488363e+03 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