File name: Pandora114s1_BuenosAires_20181028_L2Fit_fwvt1c13d20161216p1-8.txt File generation date: 20241126T051349.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v4d20170314.txt Instrument calibration file used: Pandora114s1_CF_v13d20161216.txt Level 1 file used: Pandora114s1_BuenosAires_20181028_L1_smca1c13d20161216p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20181028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1651 1803 Nominal wavelengths inside fitting window [nm]: 492.0946 492.2131 492.3316 492.4501 492.5685 492.6870 492.8054 492.9238 493.0422 493.1606 493.2789 493.3972 493.5156 493.6338 493.7521 493.8704 493.9886 494.1069 494.2251 494.3433 494.4614 494.5796 494.6978 494.8159 494.9340 495.0521 495.1701 495.2882 495.4062 495.5243 495.6423 495.7602 495.8782 495.9962 496.1141 496.2320 496.3499 496.4678 496.5857 496.7035 496.8213 496.9392 497.0569 497.1747 497.2925 497.4102 497.5280 497.6457 497.7634 497.8810 497.9987 498.1163 498.2339 498.3515 498.4691 498.5867 498.7043 498.8218 498.9393 499.0568 499.1743 499.2918 499.4092 499.5266 499.6440 499.7614 499.8788 499.9962 500.1135 500.2308 500.3481 500.4654 500.5827 500.7000 500.8172 500.9344 501.0516 501.1688 501.2860 501.4031 501.5203 501.6374 501.7545 501.8715 501.9886 502.1057 502.2227 502.3397 502.4567 502.5737 502.6906 502.8076 502.9245 503.0414 503.1583 503.2751 503.3920 503.5088 503.6256 503.7424 503.8592 503.9760 504.0927 504.2095 504.3262 504.4429 504.5595 504.6762 504.7928 504.9095 505.0261 505.1427 505.2592 505.3758 505.4923 505.6088 505.7253 505.8418 505.9583 506.0747 506.1912 506.3076 506.4240 506.5403 506.6567 506.7730 506.8894 507.0057 507.1220 507.2382 507.3545 507.4707 507.5869 507.7031 507.8193 507.9355 508.0516 508.1678 508.2839 508.4000 508.5161 508.6321 508.7482 508.8642 508.9802 509.0962 509.2121 509.3281 509.4440 509.5599 509.6758 509.7917 509.9076 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181028T090203.0Z 6875.376424 268 1 32.01 2 89.76 105.86 63.63 325.31 0.00 1 0.00 1 0 64 1.234e-01 1.124e-01 1.109e-01 1.065e-01 3.673932e+03 6.765130e+03 3.060218e+02 -6.000000e+00 6.786226e+03 284.46 -2.00 20.00 -2.00 505.14 0.00e+00 7.016849e-03 2.921678e-03 2.770825e-04 -6.000000e+00 3.435606e-03 284.46 -2.00 20.00 -2.00 499.87 0.00e+00 9.767860e-01 2.131595e+00 8.961802e-02 -6.000000e+00 2.430549e+00 228.76 -2.00 3.16 -2.00 501.48 0.00e+00 20.067 0.076 489.00 513.00 1 9.7052e+00 1.6419e-01 3.2171e-02 -6.0000e+00 1.8605e-01 1.5662e-01 4.1835e-02 2.2772e-03 -6.0000e+00 4.8903e-02 5.6141e-06 3.6583e-02 1.0052e-02 1.0770e-04 -6.0000e+00 1.2159e-02 8.8784e-02 -8.4850e-04 12 9 8 11 8 0 96.36 21.65 11.22 0.08878 0.34254 8 2 1 4 0 4000.000 25.79 19.99 21.65 -2659 29348 -4597 10823 -8843 4012 1620 -1067 12813 -7777 8759 -6928 11832 -8488 -14132 3186 -7640 -7011 4034 13105 17707 7233 -2538 11221 19980 2729 17203 -6668 -4970 -6607 10894 -1117 -4974 10004 -1237 4334 -18466 -10857 9876 -1072 3461 11176 -4856 10914 -5262 -8668 -14364 24106 5962 15047 -20724 -4645 6803 -11659 -2446 29032 15924 -171 7528 1124 -3935 14844 -3515 7178 5157 -6663 -4564 6013 4705 -5216 3790 -6478 -10951 17563 -4579 1949 -21574 3522 -7535 5504 -2191 -8466 -2705 652 -878 1 13038 -6058 16997 15535 -9802 -7572 -256 9989 13612 -7085 2770 -12563 665 -14046 -6951 31254 697 -10000 44266 -5640 -10538 14797 22729 -2673 -277 1783 -20465 -6170 30449 -17943 21595 8407 2593 1404 -2251 -482 2716 7118 2774 21730 16277 -5657 11546 10707 9694 -1239 -2300 6001 -179 15317 448 24401 12744 13957 -11642 -15302 -3561 -25064 10699 -5079 18865 17756 16874 3796 21787 -12929 -14699 -2933 24281 -5482 11294 -11403 4575 1884 -1256 12893 -9449 8879 -8107 11377 -9996 -16615 3443 -8769 -8096 4181 12398 16014 7296 -2842 11006 17931 2886 15438 -7375 -5256 -7033 9852 -1174 -5605 9882 -1368 4493 -23765 -12840 9482 -1156 3612 10963 -5675 11009 -6259 -10612 -18386 20627 5972 13399 -25806 -4879 6437 -13626 -2689 23832 15066 -190 7750 1236 -4571 14354 -4083 7440 5381 -7695 -5080 5940 4648 -5624 3717 -7075 -12646 15395 -5002 1966 -25327 3382 -7519 5131 -2072 -8559 -2593 608 -836 1 10799 -6045 13413 12462 -10228 -7852 -251 8860 11541 -7254 2511 -12946 586 -14016 -6392 19772 613 -10109 26560 -5591 -10858 11677 16454 -2511 -258 1663 -24292 -6438 22241 -21415 17464 7786 2537 1373 -2246 -466 2515 6314 2588 16865 13376 -5792 9940 9288 8472 -1196 -2205 5205 -163 11988 412 17983 10722 11742 -12005 -16437 -3410 -29847 8932 -4957 14359 13406 12533 3146 14978 -12698 -14977 SO 20181028T090603.0Z 6875.379201 272 1 32.00 2 88.96 105.30 64.09 324.44 0.00 1 0.00 1 0 22 7.757e-02 7.493e-02 7.440e-02 7.263e-02 7.227627e+03 5.039626e+03 3.414212e+01 -6.000000e+00 4.268731e+03 284.47 -2.00 20.00 -2.00 505.24 0.00e+00 3.256381e-03 1.983361e-03 1.961476e-04 -6.000000e+00 2.156641e-03 284.47 -2.00 20.00 -2.00 499.92 0.00e+00 5.863915e-01 1.486337e+00 1.287362e-01 -6.000000e+00 1.514226e+00 228.76 -2.00 3.16 -2.00 501.57 0.00e+00 18.511 0.059 489.00 513.00 1 9.6208e+00 1.1380e-01 2.9840e-02 -6.0000e+00 1.1612e-01 1.4661e-01 2.9340e-02 2.4979e-03 -6.0000e+00 3.0152e-02 8.3389e-06 -8.9465e-03 6.8042e-03 7.5582e-05 -6.0000e+00 7.6142e-03 4.2000e-02 1.1242e-04 12 8 8 10 0 0 -784.78 21.65 0.74 0.04200 -0.02006 8 2 1 4 0 4000.000 25.79 20.01 21.65 766 -8077 -11388 -4380 -2268 11366 -4606 -1901 -1429 5668 -8150 3325 -441 8351 -3787 -4510 4 -463 -5132 1270 6508 -8853 10327 6009 -2637 -285 -5212 7266 9491 8488 -7101 -9938 -9745 10735 8465 5882 905 4782 4924 -4422 -3843 -6350 6064 7326 16792 2139 -2450 -3613 9088 -5336 7959 -5969 3892 8146 -608 5507 -818 -7243 -2200 9537 10800 8988 -3087 15163 594 -201 7493 -1965 1951 -2983 3230 -11736 -8547 8167 -5696 5412 -10140 -13743 10293 12643 -4701 1412 4256 16687 3581 -3627 436 -1554 -9673 -10933 6290 1597 -5319 6822 -8243 6831 7541 -932 -2282 -8699 11338 -2412 425 12218 1950 -4400 6393 2586 -2032 -2852 -3546 10934 12888 -2330 12008 -9423 2960 11777 6118 9594 -4742 25270 670 -7388 6989 -1771 -3967 1097 1228 7530 -18785 -5212 -8277 580 -1646 12410 10685 -5015 -7539 -9592 2481 927 9142 635 617 5189 -11264 430 -1949 -20353 784 14007 11449 775 -9118 -13724 -5077 -2641 11790 -5692 -2301 -1715 6254 -10153 3635 -494 8450 -4008 -4815 4 -493 -5846 1374 6702 -10630 10243 6246 -3004 -318 -6085 7414 9279 8137 -7752 -11084 -11008 10190 8477 6141 992 4993 5071 -4953 -4267 -7263 6188 7475 15779 2345 -2814 -4167 9101 -6052 7705 -6459 3732 7423 -611 5358 -873 -8422 -2454 9460 10559 8958 -3487 14321 648 -219 7468 -2117 1991 -3157 3174 -13257 -9330 7597 -5779 5291 -10828 -14981 8656 10920 -4497 1269 3731 12993 3203 -3518 409 -1493 -10071 -11480 5541 1478 -5325 6131 -8692 6170 6643 -871 -2101 -8322 8677 -2082 356 9242 1692 -4229 5660 2394 -1953 -2728 -3392 9098 10666 -2280 10311 -10105 2818 10323 5716 8708 -4958 19339 643 -7560 6126 -1694 -3901 1030 1153 6634 -20217 -4889 -7972 537 -1531 9884 8605 -4753 -7008 -9278 2296 831 7618 580 566 4563 -11698 396 -1820 -22416 683 10500 8774 SO 20181028T091006.0Z 6875.382014 276 1 32.00 2 88.16 104.73 64.57 323.57 0.00 1 0.00 1 0 22 5.608e-02 5.494e-02 5.919e-02 5.794e-02 9.437345e+03 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