File name: Pandora114s1_BuenosAires_20190113_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T052515.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190113_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190113T090053.0Z 6952.375613 352 1 32.00 2 89.77 116.24 145.94 187.48 0.00 1 0.00 1 0 22 5.825e-01 3.152e-01 4.422e-01 3.176e-01 8.862494e+02 2.042153e+04 6.006835e+02 -6.000000e+00 3.252656e+04 288.37 -2.00 20.00 -2.00 505.25 0.00e+00 5.061357e-03 8.805339e-03 1.298624e-04 -6.000000e+00 1.635895e-02 288.37 -2.00 20.00 -2.00 499.78 0.00e+00 7.393699e-01 6.257994e+00 1.834756e-01 -6.000000e+00 1.140038e+01 229.95 -2.00 3.16 -2.00 501.47 0.00e+00 19.981 0.075 489.00 513.00 1 1.1029e+01 4.8472e-01 3.3382e-02 -6.0000e+00 8.7492e-01 1.7776e-01 1.1944e-01 2.9557e-03 -6.0000e+00 2.2801e-01 1.3819e-06 5.2754e-02 3.0775e-02 2.3295e-04 -6.0000e+00 5.7313e-02 1.9223e-01 -6.8408e-04 12 9 8 11 8 0 95.46 22.85 24.48 0.19223 0.55815 8 2 1 4 0 4000.000 26.73 19.99 22.85 544 27455 -37677 97391 11495 134924 86271 -3750 36916 -15104 13046 -1348 34346 19096 30655 18810 236 11380 43437 -3050 -843 -13243 3265 44150 30089 -24947 72416 -2704 396334 -18911 -734 43295 14023 67902 -45405 11106 -30102 16758 38819 -22440 33849 53747 -12029 -26353 76120 8958 -18569 25447 -4179 -7730 -7784 32892 2634 80494 6963 13254 43248 19222 95412 22110 -23876 19773 -18253 107670 57039 -21477 19274 13558 -23377 82125 59882 8618 -20666 -31608 91190 20142 59669 23639 26308 -28835 12963 54118 164655 16977 -8808 -7222 14348 26164 -10352 3848 99071 56315 10439 127683 15996 137907 9037 49375 -9232 4905 -36718 3273 18839 29453 -12733 10633 3030 23151 59959 28689 -10749 76777 -60690 26810 83283 96920 -14774 47465 -21966 14026 2536 86305 86768 156650 13821 125896 46880 32581 -2711 82006 41433 -996 5643 -30408 -8123 3280 -23174 29320 -16078 -12299 -12086 47958 36869 19670 -6723 27184 -15791 57885 6724 -9124 17538 1988 33368 900000 665 26248 -70366 47637 13289 44997 46034 -4836 31189 -21156 13633 -1618 29017 19105 27944 19656 300 12903 35733 -4000 -1087 -19433 4065 36320 28097 -36755 41861 -3030 123366 -25508 -852 33242 14549 40862 -83856 11523 -46848 16344 30610 -33062 28798 37921 -16474 -41560 42649 9666 -25817 22178 -4770 -8983 -9045 25937 2897 41759 7658 13752 33206 18747 43558 21106 -36167 19285 -25756 42451 36692 -29860 17598 12942 -32017 39196 36036 8763 -28303 -47881 39738 17555 34669 19622 21291 -40688 12105 33690 51252 15501 -10419 -8393 13398 21717 -11681 4072 41117 36226 10614 39743 14003 42926 8087 30737 -9518 4390 -50717 3120 15760 22346 -14614 9515 2888 18015 32660 21767 -12337 37341 -118067 21906 38885 39595 -18394 31395 -28631 12551 2516 36938 37136 48760 12368 39187 30097 24086 -2848 36693 27406 -988 5160 -39634 -8534 3126 -29303 22246 -19392 -14356 -14108 30789 26538 16838 -7455 21154 -18432 31531 6017 -9585 14330 1933 24019 900000 SO 20190113T090502.1Z 6952.378496 356 1 32.12 2 89.00 115.66 146.05 185.71 0.00 1 0.00 1 0 50 4.751e-01 2.785e-01 3.210e-01 2.329e-01 2.273535e+04 1.953900e+04 1.690172e+03 -6.000000e+00 2.652540e+04 288.37 -2.00 20.00 -2.00 505.26 0.00e+00 8.693707e-03 6.536808e-03 8.295788e-04 -6.000000e+00 1.333960e-02 288.37 -2.00 20.00 -2.00 500.46 0.00e+00 2.582812e-01 4.631070e+00 3.680816e-01 -6.000000e+00 9.282968e+00 229.95 -2.00 3.16 -2.00 502.00 0.00e+00 18.526 0.060 489.00 513.00 1 1.0873e+01 3.5378e-01 4.3082e-02 -6.0000e+00 7.1285e-01 1.4067e-02 8.9718e-02 4.5440e-03 -6.0000e+00 1.8498e-01 1.9183e-06 -3.0050e-02 1.9377e-02 4.4419e-04 -6.0000e+00 4.6647e-02 9.2034e-02 -8.3092e-04 12 9 8 11 8 0 39.85 22.85 4.83 0.09203 -0.11641 8 2 1 4 0 4000.000 26.83 20.00 22.85 21170 -29105 41488 5939 9132 37381 -15148 1649 3614 23284 -27682 7071 19033 30989 2344 -22788 17491 9979 5670 16234 32183 -6560 28643 -9766 -4064 8445 -16971 95070 -1180 17058 32379 -23109 92469 15917 -3226 -11885 -10973 82711 26307 -14041 26858 17274 -25069 -614 9643 52782 13354 -24020 5696 5834 7968 -15086 71268 19517 -33467 101884 -22349 -15278 -20016 47928 14315 32976 48604 -8278 37741 -2010 -8678 85122 5115 -6417 15017 32001 17329 24544 -431 29512 40106 -27945 28804 7412 56707 -17897 77861 10960 -16442 -4874 44624 31409 10534 -29398 -18898 37955 78382 -4369 84350 -26304 19351 -41445 23875 45991 -33007 47931 35993 75960 -1002 36419 57385 -4048 38776 -7696 56661 -9232 10805 63826 -2683 36576 -22409 141404 3130 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-9084 41280 -72789 29308 -7094 52649 40857 34030 41015 -29405 36668 -25993 41242 -28191 26180 -28941 20387 39197 14593 41790 -28712 32168 42492 36443 -20930 -16855 SO 20190113T090906.1Z 6952.381320 360 1 32.12 2 88.25 115.09 146.13 183.97 0.00 1 0.00 1 0 36 2.581e-01 1.930e-01 2.146e-01 1.888e-01 4.518436e+04 1.758888e+04 9.526580e+02 -6.000000e+00 1.441346e+04 288.37 -2.00 20.00 -2.00 505.33 0.00e+00 -1.087786e-03 5.142046e-03 1.928527e-04 -6.000000e+00 7.248800e-03 288.37 -2.00 20.00 -2.00 500.28 0.00e+00 -7.606901e+00 3.788298e+00 3.041512e-01 -6.000000e+00 5.046055e+00 229.95 -2.00 3.16 -2.00 501.90 0.00e+00 16.614 0.043 489.00 513.00 1 1.1675e+01 2.8684e-01 3.4387e-02 -6.0000e+00 3.8746e-01 1.8698e-01 7.4492e-02 5.5193e-03 -6.0000e+00 1.0059e-01 2.4446e-06 -2.6606e-02 1.2506e-02 3.8755e-05 -6.0000e+00 2.5339e-02 9.6900e-02 -8.9398e-04 12 9 8 11 8 0 -149.01 22.85 10.01 0.09690 -0.08765 8 2 1 4 0 4000.000 26.83 20.00 22.85 2931 -3121 35156 -13731 -4857 36995 -34967 26704 -9938 32707 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