File name: Pandora114s1_BuenosAires_20190117_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T052613.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190117_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190117T090444.0Z 6956.378287 299 1 32.00 2 89.77 115.32 133.50 261.10 0.00 1 0.00 1 0 15 1.217e-01 1.103e-01 1.057e-01 1.014e-01 6.638712e+03 7.249901e+03 4.118607e+01 -6.000000e+00 6.807578e+03 288.52 -2.00 20.00 -2.00 505.25 0.00e+00 -1.566967e-04 2.813739e-03 1.053172e-04 -6.000000e+00 3.424578e-03 288.52 -2.00 20.00 -2.00 499.88 0.00e+00 1.337522e+00 2.057102e+00 1.557972e-01 -6.000000e+00 2.390542e+00 229.95 -2.00 3.16 -2.00 501.56 0.00e+00 19.968 0.075 489.00 513.00 1 9.9770e+00 1.5829e-01 3.2755e-02 -6.0000e+00 1.8339e-01 1.2945e-01 3.9724e-02 2.9352e-03 -6.0000e+00 4.7922e-02 4.6828e-06 1.5988e-02 9.6042e-03 3.0639e-05 -6.0000e+00 1.2003e-02 -6.1147e-02 6.7820e-04 12 8 8 10 0 0 -444.76 22.15 5.40 -0.06115 0.04975 8 2 1 4 0 4000.000 26.21 20.00 22.15 -1714 6998 8786 -19 8182 -11341 4471 -3394 -3075 -3907 -14492 13837 17147 -14511 -16155 4668 12524 -9495 11287 -3095 10720 -10190 14395 4317 -2076 -5806 -14208 14230 25860 2592 -5569 -5154 -4718 6665 14733 -6620 -9134 3025 5680 9007 -1220 19601 6026 11707 4637 -5383 344 7777 -8801 110 15304 -801 5503 10547 -3590 -3720 -5073 20871 22469 664 9068 -20388 4459 5107 8430 -659 6166 13129 -9432 8454 -924 -21147 -5191 14990 -2050 20984 9701 -14391 -6129 1153 16890 -15301 8631 14892 -8976 8726 -10884 -13045 7967 22340 -16053 -3995 -8916 -696 -7789 -16383 17549 8558 -3371 1501 596 12063 2016 14863 8296 -9581 8207 7578 -2463 3142 9595 -6706 26957 5404 6761 -63 -2729 2337 -15670 30887 15678 14700 10710 -9608 29260 -14010 18473 -10579 9488 19064 2138 -14239 -13489 25150 -8658 -1453 52695 -5172 1554 -6818 -11203 2088 16711 962 -3396 -7711 -10601 2306 -6716 10633 500 -4588 2852 900000 -1765 6809 8674 -21 8542 -14660 4986 -4098 -3669 -4634 -18836 13365 15832 -18241 -20653 4907 12453 -12071 11864 -3529 11421 -12496 14824 4608 -2367 -6850 -18083 13394 21085 2595 -5980 -5569 -5223 6804 14161 -7898 -11080 3209 5798 8837 -1327 17411 6192 11485 4918 -6316 379 7836 -10268 114 13290 -796 5071 9299 -3736 -3995 -5649 18124 19213 704 8837 -26759 4582 5214 8270 -699 6009 11749 -10442 7733 -918 -25653 -5402 12918 -2120 17248 8810 -16313 -6297 1093 13660 -16070 7667 12537 -9092 7483 -11431 -14025 6932 16799 -17758 -3947 -9364 -679 -8132 -18327 13632 7073 -3058 1269 500 8996 1692 11361 7063 -10062 7293 6735 -2388 2851 8169 -6793 19768 4971 6176 -62 -2764 2266 -18308 22650 13251 12332 9185 -9972 20548 -15236 14580 -11176 8196 14927 1980 -15486 -14418 17974 -8555 -1328 28163 -5014 1439 -6991 -12184 2012 14020 950 -3524 -7893 -11161 2118 -6639 8645 442 -4240 2469 900000 SO 20190117T090843.1Z 6956.381054 303 1 32.12 2 89.02 114.76 134.27 260.44 0.00 1 0.00 1 0 22 8.106e-02 7.721e-02 7.410e-02 7.187e-02 3.006862e+03 4.701254e+03 4.156402e+02 -6.000000e+00 4.528821e+03 288.52 -2.00 20.00 -2.00 505.19 0.00e+00 2.555196e-03 1.971581e-03 6.804637e-05 -6.000000e+00 2.276875e-03 288.52 -2.00 20.00 -2.00 499.68 0.00e+00 2.694541e+00 1.463128e+00 4.627275e-02 -6.000000e+00 1.582508e+00 229.95 -2.00 3.16 -2.00 501.34 0.00e+00 18.566 0.060 489.00 513.00 1 9.6960e+00 1.1201e-01 2.8082e-02 -6.0000e+00 1.2155e-01 1.2294e-01 2.9011e-02 1.5924e-03 -6.0000e+00 3.1501e-02 6.6972e-06 7.5717e-03 6.7204e-03 5.5294e-05 -6.0000e+00 7.9584e-03 2.9096e-02 -3.7943e-04 12 8 8 10 0 0 91.87 22.15 8.62 0.02910 0.08162 8 2 1 4 0 4000.000 26.21 19.99 22.15 2789 -9998 5994 6342 -5177 2145 -4070 -1516 6548 2473 36 -6528 1842 1472 6184 -6877 5329 10321 16666 -9957 -713 -5500 15980 -4787 -679 6002 -4956 -10722 -2660 4049 -12345 17678 -2328 3546 -8295 10685 8690 -807 6545 4519 4850 -7267 8049 -2559 685 -1362 -3994 -1801 -12447 1699 -6274 6397 -5805 5338 1944 -837 -2294 19560 9252 8403 -10498 3903 -2305 988 3130 -3120 3337 13051 17634 -13356 -17441 7423 5839 -6004 4366 -3379 7477 4702 -3880 -7348 14303 2885 -7817 -6393 306 3515 9355 851 21437 -4448 10381 -437 -2030 2527 -1817 9419 17940 3622 302 -752 -8910 8363 3543 250 -6910 2858 -12373 6154 10948 -572 -13374 -7127 2603 -10762 11463 882 -2419 -8708 2339 -3071 1626 2421 -1939 6972 4416 12583 3902 -10140 10697 -1522 15355 13103 -5108 2964 -7007 6863 -15302 -5882 -7721 -7020 -1067 -8024 -8231 -9241 4452 -2760 17417 1782 9682 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2 14.55 19.24 135.95 99.60 0.00 1 0.00 1 0 15 3.170e-03 3.162e-03 3.554e-05 3.544e-05 1.639685e+03 2.093798e+00 1.175538e+02 -6.000000e+00 1.771785e+02 288.53 -2.00 20.00 -2.00 505.23 0.00e+00 4.442889e-04 9.731600e-07 3.385411e-05 -6.000000e+00 8.903478e-05 288.53 -2.00 20.00 -2.00 500.33 0.00e+00 -1.214125e-01 6.894562e-04 1.223456e-02 -6.000000e+00 6.179530e-02 229.95 -2.00 3.16 -2.00 501.94 0.00e+00 1.033 0.000 489.00 513.00 1 8.7251e-01 5.2922e-05 1.9575e-03 -6.0000e+00 4.7481e-03 -1.7334e-04 1.3699e-05 2.8326e-04 -6.0000e+00 1.2276e-03 7.0799e-01 5.7114e-04 3.3972e-06 1.7417e-05 -6.0000e+00 3.1128e-04 -1.0422e-02 -4.4425e-06 10 0 0 10 0 0 99.95 23.79 3.00 -0.01042 -0.00646 8188 1606 1 4 0 3.914 27.56 20.00 23.79 -438 -215 -29 97 279 435 643 694 709 797 665 458 436 402 244 -37 -250 -228 -68 101 185 208 186 127 91 117 72 -23 -147 -251 -508 -695 -551 -210 20 46 0 -38 -75 -190 -204 -168 -201 -153 -28 156 246 264 284 153 -125 -419 -643 -711 -679 -406 -133 -13 6 19 36 36 78 78 98 91 60 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