File name: Pandora114s1_BuenosAires_20190121_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T054124.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190121_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190121T090839.0Z 6960.381007 206 1 32.01 2 89.77 114.27 89.42 295.79 0.00 1 0.00 1 0 15 1.236e-01 1.127e-01 1.178e-01 1.133e-01 4.080309e+03 7.594026e+03 1.798411e+02 -6.000000e+00 6.911115e+03 288.58 -2.00 20.00 -2.00 505.28 0.00e+00 3.173159e-03 3.131715e-03 1.336450e-04 -6.000000e+00 3.471407e-03 288.58 -2.00 20.00 -2.00 500.06 0.00e+00 2.163652e+00 2.284925e+00 4.865530e-02 -6.000000e+00 2.403721e+00 229.91 -2.00 3.16 -2.00 501.70 0.00e+00 19.971 0.075 489.00 513.00 1 9.9836e+00 1.7594e-01 3.0888e-02 -6.0000e+00 1.8472e-01 1.1385e-01 4.4507e-02 1.8811e-03 -6.0000e+00 4.7734e-02 4.1901e-06 1.9377e-03 1.0907e-02 4.3968e-05 -6.0000e+00 1.2118e-02 7.4983e-03 8.7471e-04 12 8 8 10 0 0 90.85 22.43 4.01 0.00750 0.02094 8 2 1 4 0 4000.000 26.41 19.99 22.43 585 -12386 3899 5149 9701 4020 -8477 21 11393 -5263 -14510 18331 12832 11162 -3456 -877 -12884 3694 -3670 -10158 9643 -271 -1953 8403 -6819 13166 10125 -2959 44684 -876 3926 -302 4026 -1204 2212 11875 -2421 -9424 5060 3895 -16071 -10326 4888 -5941 -11768 16243 3197 12054 747 8541 -6560 -4843 7601 -11536 23814 36568 12962 3616 -14384 -10360 12416 6776 112 20401 -5217 -7828 4214 -5828 -23924 -1436 -4002 11810 8213 8600 17150 -10549 -3027 7992 22275 -5824 7144 -8555 -14136 19124 -8588 24482 -5268 7494 -11668 10216 1732 7253 -1898 13061 162 12045 1380 -20164 262 -1318 28990 7737 16335 -494 -16056 -1945 -11020 -5812 18151 14632 -3361 -18078 5073 -773 4740 11646 -4499 10557 4272 11571 10468 -2942 16273 -15350 1077 42261 -4899 9363 -2553 -22435 1581 20781 -12005 4864 5731 -1259 8593 -5134 -7241 9167 19639 1849 24802 -21604 -3421 12832 4545 15960 -13980 10232 -6521 1626 -5269 900000 584 -14536 4019 5390 9923 4431 -10687 24 11654 -6260 -18640 16716 12210 10710 -3836 -960 -16243 4042 -4395 -12179 10170 -316 -2168 9062 -8024 12667 9967 -3263 29763 -895 3777 -306 4022 -1310 2373 11601 -2705 -11159 5131 3978 -20101 -12304 5064 -6948 -14718 15387 3431 11686 796 8218 -7137 -5054 6919 -12806 19034 26522 12183 3773 -17991 -12421 11854 6871 122 18118 -5947 -9037 4241 -6384 -30985 -1466 -4147 10401 7537 7956 14723 -11945 -3136 7275 17310 -5948 6398 -8990 -15797 15427 -8640 19025 -5191 6499 -12224 8577 1587 6341 -1844 11056 156 10196 1273 -22524 233 -1162 18505 6066 11900 -438 -17267 -1862 -11622 -5767 13979 11573 -3194 -20195 4575 -751 4407 10181 -4651 9449 4090 10277 9297 -2939 13210 -16934 1009 26390 -4928 8186 -2515 -26929 1492 16148 -12827 4320 4971 -1161 7214 -5022 -7386 8078 15807 1796 19273 -25253 -3561 11396 4383 13620 -14881 8874 -6174 1413 -4955 900000 SO 20190121T091239.0Z 6960.383785 210 1 32.01 2 89.02 113.71 90.13 295.24 0.00 1 0.00 1 0 29 7.807e-02 7.422e-02 7.937e-02 7.722e-02 2.410556e+03 5.031781e+03 1.033302e+02 -6.000000e+00 4.363113e+03 288.58 -2.00 20.00 -2.00 505.24 0.00e+00 -5.191892e-04 2.122839e-03 5.024774e-05 -6.000000e+00 2.193237e-03 288.58 -2.00 20.00 -2.00 499.83 0.00e+00 3.600315e+00 1.562854e+00 3.950106e-02 -6.000000e+00 1.523795e+00 229.91 -2.00 3.16 -2.00 501.50 0.00e+00 18.552 0.060 489.00 513.00 1 9.7491e+00 1.2012e-01 2.8029e-02 -6.0000e+00 1.1705e-01 7.8748e-02 3.0635e-02 1.6871e-03 -6.0000e+00 3.0325e-02 6.2233e-06 6.3010e-03 7.2687e-03 1.8719e-05 -6.0000e+00 7.6656e-03 2.6993e-02 -3.5089e-04 12 8 8 10 0 0 90.27 22.43 3.18 0.02699 0.07070 8 2 1 4 0 4000.000 26.41 20.00 22.43 3163 -6893 -1858 -3027 3746 4577 10054 -6674 -2044 9170 -2300 -5492 8782 -946 9512 3759 6008 865 -3425 -11286 -1182 -2307 11399 246 203 -1306 -2849 4505 -16651 7068 -1111 -8426 832 -5303 6397 -3706 15038 3041 -1405 1471 13602 -6549 -3852 2039 7322 9028 6704 -9023 2792 419 3692 -236 11815 -10245 -2741 1469 -9320 11439 5906 10567 -6955 9508 5650 -7962 1554 -6858 -837 -5792 8970 13709 -2482 -4635 -4697 -770 -8837 1116 -6926 -9503 7245 1748 17077 -8548 983 8286 24478 14085 -3878 7171 -14107 -1456 3042 -6220 11012 3044 -5174 -4487 -8701 -2009 15919 8156 -11558 4457 6011 -2419 -2658 8101 4508 3929 -11164 8134 14911 -4151 4525 -656 -5947 -5323 1591 177 -4447 4627 -4557 12467 2064 5674 -2487 1400 -7314 11539 647 -13301 12191 12705 -6807 5975 -604 3613 -977 -2826 -2834 11560 -5688 -14119 17732 1872 2033 1290 -5794 -3315 -4633 -4249 -9510 6060 17905 11150 3061 -7492 -1979 -3372 4011 4975 10546 -8373 -2454 9769 -2711 -6592 9022 -1059 9516 3718 5883 913 -3872 -14068 -1342 -2655 11448 276 230 -1503 -3321 4843 -21766 7099 -1177 -9483 861 -5995 6651 -4358 14724 3330 -1589 1596 12974 -7635 -4394 2212 7612 9295 7072 -11065 3002 452 3764 -243 10495 -11169 -2781 1460 -10630 10854 5992 10239 -8003 9261 5732 -9282 1647 -7857 -892 -6372 8375 12039 -2531 -4772 -4812 -761 -8989 1040 -7013 -9757 6170 1547 12847 -8291 870 6860 17372 11196 -3725 6209 -15151 -1378 2749 -6181 9274 2809 -5239 -4522 -9057 -1920 12427 6715 -11320 3648 4806 -2129 -2414 6861 4074 3606 -11832 7004 11852 -3987 4025 -624 -6050 -5440 1528 174 -4586 4379 -4722 10794 1954 5101 -2401 1298 -7440 9773 612 -13623 10267 10640 -6517 5002 -533 3008 -844 -2492 -2537 9163 -5471 -15027 13898 1734 1892 1218 -5908 -3307 -4663 -4201 -9698 5181 13475 9036 SO 20190121T091642.0Z 6960.386597 214 1 32.00 2 88.25 113.14 90.85 294.68 0.00 1 0.00 1 0 22 5.451e-02 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