File name: Pandora114s1_BuenosAires_20190220_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T054203.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190220_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190220T093823.0Z 6990.401655 216 1 32.00 2 89.75 103.17 81.96 289.48 0.00 1 0.00 1 0 29 1.592e-01 1.452e-01 1.224e-01 1.155e-01 -8.433935e+03 6.604034e+03 9.947327e+01 -6.000000e+00 8.908066e+03 288.77 -2.00 20.00 -2.00 505.23 0.00e+00 -1.406312e-03 3.161774e-03 2.027495e-04 -6.000000e+00 4.474541e-03 288.77 -2.00 20.00 -2.00 499.86 0.00e+00 3.592196e+00 2.314264e+00 1.338243e-01 -6.000000e+00 3.096916e+00 229.29 -2.00 3.16 -2.00 501.55 0.00e+00 19.944 0.074 489.00 513.00 1 9.9740e+00 1.7729e-01 3.2349e-02 -6.0000e+00 2.3806e-01 1.1619e-01 4.6651e-02 2.6148e-03 -6.0000e+00 6.1429e-02 4.1252e-06 -2.0461e-02 1.0666e-02 8.1290e-05 -6.0000e+00 1.5631e-02 -1.7135e-03 4.9293e-05 12 8 8 10 0 0 70.12 23.41 17.59 -0.00171 -0.14364 8 2 1 4 0 4000.000 27.26 20.00 23.41 4428 12050 2571 -11968 16933 605 -4013 6558 -3223 -11560 -22355 22015 377 18411 2105 7977 2295 888 5095 4086 22697 2502 15167 3546 -9274 4627 -9937 12680 -17687 31513 -14448 9209 24225 -9825 -28396 -10761 13914 6729 31924 12311 -9669 17020 3571 13613 -13865 -13562 6169 -13151 -3036 4675 24476 10346 4327 -142 5646 -7077 11907 13026 -2885 14622 3252 11363 21997 4841 14559 -16987 -3905 7444 -3118 16610 -28018 24097 -16386 10894 -1344 -306 -16679 -3571 4944 -16497 36924 5497 29153 -5412 3256 13477 -17836 12425 -4461 34099 -11250 42743 469 9177 32301 14399 937 -1846 3291 15225 7304 -1041 -27546 -1432 913 53427 -9428 5368 -2681 -22287 17671 -22518 15256 -19934 39761 -2027 34208 5949 6082 29981 -5352 39758 -16119 8238 2407 5755 15920 -12912 783 -2809 13475 576 4285 -5263 -21819 17853 4193 -3720 9134 7248 12634 -19939 6089 9593 18453 -22711 -8695 9292 1712 9115 -4495 11927 -3124 21800 4370 10822 2559 -14138 15482 671 -4774 7164 -3937 -15432 -33100 20662 433 17429 2316 8197 2488 984 5524 4596 21670 2955 15830 3882 -11556 5031 -12532 12736 -23907 25701 -18221 8902 19757 -11277 -40099 -13165 13659 7165 26277 12179 -11756 15681 3749 12953 -17485 -17206 6475 -16784 -3485 4907 20701 9844 4248 -142 5202 -7375 10430 11607 -3094 13361 3339 10726 18605 4862 13303 -21294 -4276 7195 -3297 14174 -36815 18561 -18685 9378 -1309 -298 -19397 -3668 4630 -18812 24259 4898 20474 -5394 3000 11297 -19320 10696 -4296 23948 -11708 27759 439 7927 23904 12131 915 -1869 3169 12934 6619 -1002 -33738 -1328 828 29125 -9878 4940 -2676 -26665 13887 -25985 11989 -22439 25053 -1980 23734 5559 5727 22287 -5646 26458 -18487 7290 2233 5133 12849 -13986 743 -2765 11257 546 3913 -5291 -25796 14030 3710 -3503 7501 6106 10286 -23009 5517 8490 15024 -26331 -8806 8420 1585 7835 -4373 9616 -2852 15252 SO 20190220T094231.0Z 6990.404525 220 1 32.00 2 88.93 102.58 82.72 288.86 0.00 1 0.00 1 0 29 1.006e-01 9.301e-02 8.657e-02 8.372e-02 1.615503e+04 6.454533e+03 8.276649e+02 -6.000000e+00 5.634484e+03 288.77 -2.00 20.00 -2.00 505.19 0.00e+00 -3.022159e-03 2.307559e-03 2.409238e-04 -6.000000e+00 2.838504e-03 288.77 -2.00 20.00 -2.00 499.82 0.00e+00 -9.173453e-01 1.679195e+00 9.454247e-02 -6.000000e+00 1.986502e+00 229.29 -2.00 3.16 -2.00 501.48 0.00e+00 18.331 0.058 489.00 513.00 1 1.0194e+01 1.2832e-01 2.9090e-02 -6.0000e+00 1.5219e-01 1.4813e-01 3.2962e-02 2.5086e-03 -6.0000e+00 4.0136e-02 5.7804e-06 2.7273e-02 7.2020e-03 9.0271e-05 -6.0000e+00 9.9324e-03 -5.7442e-01 2.8168e-03 12 9 8 11 256 0 -115.88 23.41 7.78 -0.57442 -0.38524 8 2 1 4 0 4000.000 27.26 20.00 23.41 900000 900000 2934 -2676 -5077 -5263 634 -4101 6754 -614 -4863 4465 -8034 13911 -505 9 -2939 10732 63 -3822 -167 495 17490 -5533 16097 5914 -6099 1605 -2048 -13585 -926 6014 -642 15003 -7737 -435 17854 7124 -7395 -3967 2698 -12376 869 2171 -14640 -4612 6291 7671 -3412 6488 6148 20861 18239 3199 -162 1203 7610 -8795 -18073 17525 5204 -630 1266 2192 1735 2707 9691 3088 -8704 3181 -5928 -418 6252 -834 24469 -6384 4819 8066 -13472 11792 -7377 51 11201 -3054 -5011 5246 2737 -12146 -8122 13905 918 11147 -3113 14477 -17243 4443 -5696 -9634 18756 9016 -578 -12711 -7111 2901 14209 2109 -4157 6192 -6225 -4408 6730 6693 16847 -14400 -2795 3722 15461 16346 17987 11015 -2227 -2145 -10954 8950 -8973 3108 -7261 4824 9503 791 10168 -7297 36824 -9678 -11348 18051 5125 -22409 -12441 2133 -16 3685 -265 -15841 20353 -8286 6849 -5333 21373 -3913 11716 1111 19410 -9050 900000 900000 2992 -2980 -5951 -6323 732 -5024 7442 -724 -5899 4868 -9794 13453 -559 9 -3151 10273 69 -4432 -188 556 16551 -6598 15497 6308 -7306 1764 -2297 -16646 -973 5823 -671 13787 -9226 -492 16896 7443 -8818 -4514 2848 -15165 937 2327 -18739 -5373 6573 7847 -3845 6495 6019 17117 14966 3010 -159 1191 7284 -10152 -23133 15722 5267 -676 1336 2302 1832 2813 9277 3108 -9713 3115 -6290 -417 5814 -839 19408 -6548 4423 7073 -14370 9615 -7225 46 9133 -2897 -4908 4708 2555 -13267 -8538 11694 876 9603 -3113 12250 -20072 4102 -5637 -9536 13466 6935 -480 -11798 -6272 2380 10930 1936 -4242 5811 -6608 -4543 6143 6110 13996 -16468 -2853 3550 13083 13748 15036 9999 -2319 -2211 -12078 7894 -9296 2837 -7373 4354 8187 742 8656 -6938 23794 -9249 -10845 13515 4363 -23902 -12249 1854 -15 3255 -247 -17433 15718 -8559 6082 -5328 16196 -3759 9444 981 14240 -8911 SO 20190220T094633.0Z 6990.407326 224 1 32.00 2 88.11 102.01 83.48 288.27 0.00 1 0.00 1 0 22 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