File name: Pandora114s1_BuenosAires_20190227_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T054253.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190227_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190227T094446.0Z 6997.406088 229 1 32.00 2 89.75 100.01 19.47 43.80 0.00 1 0.00 1 0 29 3.658e-01 2.626e-01 2.827e-01 2.303e-01 6.023719e+03 1.594519e+04 1.792564e+02 -6.000000e+00 2.044516e+04 288.59 -2.00 20.00 -2.00 505.31 0.00e+00 1.464228e-02 6.613082e-03 7.253262e-04 -6.000000e+00 1.028542e-02 288.59 -2.00 20.00 -2.00 500.20 0.00e+00 1.806895e+00 4.622140e+00 1.277544e-01 -6.000000e+00 7.166146e+00 228.91 -2.00 3.16 -2.00 501.84 0.00e+00 19.946 0.074 489.00 513.00 1 1.0486e+01 3.5885e-01 3.6588e-02 -6.0000e+00 5.4984e-01 1.1050e-01 8.7792e-02 2.1787e-03 -6.0000e+00 1.4361e-01 1.9974e-06 2.3041e-02 2.0552e-02 3.0318e-04 -6.0000e+00 3.6020e-02 -4.4787e-02 -9.2299e-05 12 8 8 10 0 0 99.90 21.45 35.41 -0.04479 0.11503 8 2 1 4 0 4000.000 25.58 19.99 21.45 900000 9327 -37134 -6258 18451 130096 2935 -7731 10290 -20494 14049 10598 36736 3099 19164 14158 -12865 30213 31711 61605 1815 40219 3740 12362 38623 -30050 13951 -28345 -8552 22436 -25076 55521 8783 8962 7085 37307 29126 -13630 16825 -23803 46413 1083 84260 -10125 -7096 12500 -6906 33013 -41972 85803 40860 78110 50257 -9050 43720 -7500 -13981 -9856 40438 24923 -19654 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15320 -17230 24699 31776 -10477 24124 5635 10684 -49058 34680 9967 20860 32821 -3329 32221 -39604 1593 -27141 34231 31649 -66108 37618 -11635 27463 -20972 21323 -5965 31168 34354 -21550 -17802 13756 13185 24978 -21926 2078 -8621 21405 28969 16983 -18529 30565 18670 5235 19206 761 31199 -16433 31610 -16777 -19193 27110 1614 27725 14417 34250 -14344 23017 13537 -25657 -6406 -39507 37728 179 17468 16330 -31069 26464 -15012 30098 -18180 17456 157 10994 -8232 -9542 33507 -26477 22879 11995 -9762 25923 -33967 34640 SO 20190227T094846.0Z 6997.408866 233 1 32.00 2 88.94 99.45 18.92 41.55 0.00 1 0.00 1 0 29 2.052e-01 1.710e-01 2.029e-01 1.880e-01 1.795752e+04 1.395353e+04 1.961238e+03 -6.000000e+00 1.147191e+04 288.59 -2.00 20.00 -2.00 505.36 0.00e+00 -2.288044e-03 5.099669e-03 1.552960e-04 -6.000000e+00 5.765788e-03 288.59 -2.00 20.00 -2.00 500.30 0.00e+00 8.529992e-01 3.647026e+00 1.732317e-01 -6.000000e+00 3.994377e+00 228.91 -2.00 3.16 -2.00 501.92 0.00e+00 18.368 0.058 489.00 513.00 1 1.0847e+01 2.7964e-01 3.0014e-02 -6.0000e+00 3.0697e-01 5.3216e-02 7.0981e-02 1.8978e-03 -6.0000e+00 7.9319e-02 2.5086e-06 1.8337e-02 1.5908e-02 2.4763e-04 -6.0000e+00 2.0149e-02 -3.4130e-02 1.5791e-04 12 8 8 10 0 0 -189.07 21.45 5.17 -0.03413 0.09307 8 2 1 4 0 4000.000 25.58 20.00 21.45 27970 6304 30549 1668 5469 7597 45093 -18835 11865 13485 15046 -13469 11336 10546 4992 3464 9709 -11395 -5884 -9079 13608 13786 -2898 18429 -4391 15916 -11442 -5356 -4366 55597 18592 61225 2759 10005 10100 -18127 -17706 -21612 -5841 -16005 -3546 2650 12209 18586 3071 4534 -23473 26767 100 -12140 10042 -22789 -2192 -2093 9151 23850 -12470 -19926 3946 12588 7345 10186 9416 -3366 21446 16234 24831 -6589 1586 10933 -425 16634 -37123 -24013 -17602 19129 6003 17880 -11949 -15257 7439 3592 13977 2824 61517 -9623 28244 28647 888 32843 5137 51306 15763 -3664 25818 -99 37804 5025 -14826 974 -8456 13021 2776 -19244 -20956 76497 -13420 -1862 18715 -24702 6825 -19711 -6612 10281 660 11373 581 -6261 1906 12653 5421 -3849 29731 -11412 2082 -2477 -14792 -326 -5805 12143 14651 4185 13719 38389 -21040 -21383 -26 3011 -8351 40223 45422 4828 716 20976 45422 -24321 50918 32806 -19041 24458 5127 19420 12170 -3454 19887 5727 22525 1691 5473 7602 31467 -25047 11561 12783 13867 -16316 10597 9859 4929 3512 9460 -14103 -7050 -11356 13617 13795 -3434 17714 -5319 15717 -14764 -6418 -5058 34405 16401 35469 2746 9590 9929 -23835 -23065 -28949 -6604 -19865 -3878 2735 11553 16673 3246 4735 -32307 22039 106 -14173 9132 -28005 -2155 -2057 8210 19051 -14711 -25711 4025 11757 7221 9764 9141 -3723 18448 14563 20140 -7207 1579 9807 -423 13900 -53376 -30690 -21415 16220 5754 14942 -13216 -17249 6674 3355 11852 2706 33263 -10761 21867 22179 905 24216 4987 31524 13947 -3962 20622 -99 25087 4446 -15487 850 -7502 9921 2239 -20175 -23661 36662 -15307 -1909 15524 -31304 6291 -23844 -7084 9357 662 10220 583 -6780 1932 11662 5371 -4124 22264 -12621 1991 -2483 -16871 -323 -6085 10632 12491 3953 11696 25209 -24725 -25127 -24 2844 -9044 27341 29828 4839 758 18366 31398 -33903 33437 25700 -24789 20288 5080 16557 11217 -3780 SO 20190227T095247.0Z 6997.411655 237 1 32.00 2 88.12 98.88 18.39 39.17 0.00 1 0.00 1 0 43 1.698e-01 1.542e-01 1.391e-01 1.321e-01 1.724357e+03 8.039987e+03 3.622742e+02 -6.000000e+00 9.491691e+03 288.59 -2.00 20.00 -2.00 505.36 0.00e+00 2.085070e-03 3.716382e-03 1.086421e-04 -6.000000e+00 4.772400e-03 288.59 -2.00 20.00 -2.00 500.37 0.00e+00 2.967231e-01 2.544272e+00 9.823227e-02 -6.000000e+00 3.309452e+00 228.91 -2.00 3.16 -2.00 502.04 0.00e+00 16.280 0.040 489.00 513.00 1 1.0798e+01 1.9755e-01 2.5129e-02 -6.0000e+00 2.5428e-01 8.2422e-02 4.8739e-02 1.8465e-03 -6.0000e+00 6.5806e-02 3.6104e-06 2.7853e-02 1.2892e-02 8.5703e-05 -6.0000e+00 1.6663e-02 -6.7894e-02 2.6054e-04 12 9 8 11 8 0 64.83 21.45 6.68 -0.06789 0.12530 8 2 1 4 0 4000.000 25.58 20.00 21.45 -17981 11626 3101 -20868 858 -14064 -7189 -4953 19116 26099 -1619 15753 -10783 6882 -38515 3680 -10854 10270 -7657 -10189 25369 -14342 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