File name: Pandora114s1_BuenosAires_20190405_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T060403.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190405_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190405 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190405T101456.1Z 7034.427038 430 1 32.20 2 89.72 82.46 90.25 87.45 0.00 1 0.00 1 0 22 1.367e-01 1.311e-01 1.239e-01 1.193e-01 -3.064996e+03 6.820127e+03 7.290502e+02 -6.000000e+00 7.594849e+03 287.20 -2.00 20.00 -2.00 505.31 0.00e+00 1.252096e-04 3.320137e-03 1.362810e-04 -6.000000e+00 3.826961e-03 287.20 -2.00 20.00 -2.00 500.36 0.00e+00 4.435942e-01 2.313036e+00 8.509353e-02 -6.000000e+00 2.656188e+00 226.82 -2.00 3.16 -2.00 502.01 0.00e+00 19.969 0.075 489.00 513.00 1 1.0180e+01 1.7840e-01 3.1205e-02 -6.0000e+00 2.0405e-01 1.2095e-01 4.5113e-02 1.8282e-03 -6.0000e+00 5.2758e-02 4.1045e-06 7.9628e-04 1.1831e-02 1.2944e-04 -6.0000e+00 1.3416e-02 -2.9753e-02 9.4849e-05 12 8 8 10 0 0 87.74 21.33 0.11 -0.02975 -0.02423 8 2 1 4 0 4000.000 25.47 20.00 21.33 -16701 4902 -11514 -1129 -615 1787 2219 -24241 -1366 9844 522 -3978 -2315 14035 5989 -4062 737 -1988 2163 -16138 17733 -12334 7958 15603 -11034 -10018 374 5827 4489 22844 12529 -17823 4994 -8192 26139 14217 10152 13742 15157 20184 12290 -17242 -7393 12792 1217 8351 22319 -696 -11443 4092 21685 -19991 6293 19363 18344 18347 -9285 10546 13860 1391 -7436 5810 2211 -8145 6046 -4711 7154 26222 7471 22459 -7415 -836 3459 -9421 29489 1658 20613 -14396 -25679 2578 -6899 2588 13651 26291 20148 -9574 12000 -7672 -22935 7820 15802 632 -5832 14198 21935 -6612 -15438 18210 -8967 9174 -203 -843 -3707 -949 31039 24094 -2243 7369 4065 1620 -12611 -3909 34697 19774 9789 -4068 -19843 -2145 -5131 -4438 14067 2200 23331 10792 -2315 -5244 -14096 2940 82 11597 -5201 40538 18813 13104 -14691 9937 10124 1384 -7479 7414 5524 -354 -35883 18653 5296 -6265 8661 1637 -8211 -2885 19886 -8420 4965 -13037 -18696 4464 -12697 -1160 -648 1881 2373 -34225 -1540 9869 567 -4454 -2514 12781 5854 -4377 763 -2159 2313 -21166 16741 -15765 8311 15121 -13078 -11795 397 5816 4480 18525 10942 -20707 4634 -8879 20789 13081 9815 12751 13709 17155 11212 -21108 -8243 11770 1272 8205 19143 -749 -13562 4084 17754 -24161 5692 15098 14446 14735 -10135 9703 12537 1431 -8350 5709 2258 -9272 5988 -5180 6917 20650 6990 17863 -7863 -821 3237 -10063 21614 1629 16877 -16613 -32637 2433 -7101 2422 11496 19680 16181 -10451 10667 -8375 -27495 7378 13800 646 -6011 12953 18814 -7154 -18282 15309 -9767 8181 -194 -795 -3550 -888 21555 18493 -2296 6895 3893 1563 -13828 -3915 23842 16044 8945 -4341 -25094 -2289 -5664 -4866 12751 2219 18760 9703 -2352 -5481 -16178 2858 82 10343 -5475 26966 15540 11399 -16646 8644 8659 1285 -7654 6666 5168 -357 -52199 15817 5149 -6870 8230 1675 -9244 -3037 16281 -8925 4537 -13454 SO 20190405T101859.0Z 7034.429850 434 1 32.01 2 88.90 81.89 89.45 86.89 0.00 1 0.00 1 0 29 6.028e-02 5.807e-02 5.933e-02 5.860e-02 6.941433e+03 3.983682e+03 7.419905e+02 -6.000000e+00 3.350150e+03 287.20 -2.00 20.00 -2.00 505.35 0.00e+00 6.241491e-04 1.609586e-03 9.157781e-05 -6.000000e+00 1.687082e-03 287.20 -2.00 20.00 -2.00 500.47 0.00e+00 2.128351e+00 1.148326e+00 1.662453e-02 -6.000000e+00 1.168184e+00 226.82 -2.00 3.16 -2.00 502.06 0.00e+00 18.320 0.058 489.00 513.00 1 9.5406e+00 8.7951e-02 2.7608e-02 -6.0000e+00 8.9787e-02 3.1614e-02 2.2347e-02 1.6415e-03 -6.0000e+00 2.3134e-02 8.6291e-06 -8.6462e-03 5.4423e-03 1.0201e-04 -6.0000e+00 5.9127e-03 1.1799e-02 5.7035e-05 12 9 8 11 8 0 97.52 21.33 5.52 0.01180 -0.04817 8 2 1 4 0 4000.000 25.47 20.00 21.33 92 -2047 2202 12899 814 -902 -1721 678 684 3126 11340 2222 6176 1730 -414 -5808 -2888 -7022 8355 -7242 2358 -5419 68 -2892 1159 -462 6356 -3780 -8834 7208 -5424 3431 -4049 -1337 537 2493 -2463 -6346 1332 1274 9580 3175 6299 -6082 2850 2906 -1051 10189 -930 3708 1321 -4540 -263 6068 -3958 -138 -2099 4229 -7369 -6304 950 -2376 9654 445 1523 -7834 -1545 -6375 3533 -10995 644 689 16092 3892 -12264 1293 20034 -382 -1218 1563 4337 -6905 -8946 9169 -1638 8078 -1340 28 5127 -10988 -7451 8143 10653 5732 -4310 6154 4313 -2431 -3207 -1384 7557 12692 -2707 8225 -11544 -1669 -11285 9645 -8507 12149 5416 752 -1124 3604 3992 -582 -893 -3734 -7917 6155 -2483 2416 -7667 -5129 3757 811 1794 -3114 857 8797 -1990 7270 3963 -2334 -2736 -2137 -338 -4051 237 2290 12777 2800 -1085 -3784 5700 -2494 -1210 4418 1654 7875 -7610 -7180 -1753 13514 86 -1949 2061 11221 825 -955 -1879 735 747 3322 10983 2171 6133 1657 -401 -5917 -2876 -7423 7776 -8071 2420 -6040 72 -3157 1221 -498 6403 -4199 -10218 6957 -5775 3272 -4156 -1362 555 2607 -2745 -7340 1414 1337 9173 3235 6248 -6895 2991 3083 -1167 10107 -1023 3835 1371 -4869 -263 5578 -4003 -136 -2179 4244 -8467 -7219 1011 -2612 9429 449 1525 -8607 -1581 -6753 3336 -11844 611 646 13683 3508 -13123 1226 15898 -370 -1172 1437 3830 -6794 -8994 7737 -1553 7020 -1294 27 4713 -11876 -7759 7251 9295 5310 -4472 5790 4104 -2426 -3144 -1297 6323 9889 -2430 6645 -11648 -1588 -12319 8762 -9316 10732 5056 732 -1122 3481 3899 -602 -933 -4036 -8983 6122 -2551 2507 -8188 -5252 3466 765 1680 -3084 819 7789 -1964 6535 3683 -2303 -2681 -2051 -315 -3915 222 2144 11011 2716 -1111 -4028 5567 -2663 -1284 4450 1710 7585 -8410 -7740 -1766 11692 SO 20190405T102306.0Z 7034.432708 438 1 32.01 2 88.06 81.30 88.63 86.31 0.00 1 0.00 1 0 22 1.629e-02 1.632e-02 1.430e-02 1.425e-02 7.744485e+03 9.614045e+02 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