File name: Pandora114s1_BuenosAires_20190407_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T060402.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190407_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190407T101630.0Z 7036.428125 417 1 32.01 2 89.72 81.54 112.69 91.93 0.00 1 0.00 1 0 15 6.867e-02 6.737e-02 7.243e-02 7.114e-02 8.192438e+03 4.859392e+03 5.953841e+02 -6.000000e+00 3.813346e+03 287.10 -2.00 20.00 -2.00 505.23 0.00e+00 -7.839868e-04 1.930228e-03 6.591831e-05 -6.000000e+00 1.924894e-03 287.10 -2.00 20.00 -2.00 500.12 0.00e+00 1.488740e-01 1.405526e+00 4.635584e-02 -6.000000e+00 1.346623e+00 226.71 -2.00 3.16 -2.00 501.75 0.00e+00 19.968 0.075 489.00 513.00 1 9.6686e+00 1.0704e-01 3.0804e-02 -6.0000e+00 1.0321e-01 1.2344e-01 2.7941e-02 2.0428e-03 -6.0000e+00 2.7086e-02 7.0633e-06 3.9289e-03 6.5559e-03 5.8854e-05 -6.0000e+00 6.7647e-03 8.1847e-02 -1.1168e-03 12 8 8 10 0 0 83.04 21.18 11.52 0.08185 0.10910 8 2 1 4 0 4000.000 25.39 20.00 21.18 900000 9837 -5315 -6215 -3118 -1899 -6197 2778 4905 2911 2283 -3528 -4456 4213 -3765 228 7900 -4412 -554 5484 4658 -6271 -1266 -1581 17952 -4595 -2895 -4566 -3545 4834 1081 3322 -10425 10883 1745 -12707 5098 4133 1420 1033 6240 -2172 5085 3133 3293 15506 11765 -4790 -290 -1758 -10292 14189 -1764 1568 -5322 -3224 1412 2557 167 -9734 -7360 3016 6291 -7415 3951 -5454 4545 -2056 7718 -198 -8723 2182 -2359 -4199 821 1824 9679 1934 -2655 7786 -367 9957 3901 -1745 -3159 9915 -6976 5895 14028 8707 14604 -6480 2169 11150 7037 4017 4697 -13023 2663 -8787 6637 7749 -2312 -14178 9810 5506 6536 518 -10008 3176 5089 -10031 -13363 4120 -830 7668 13873 -6966 40 5581 -6191 -3794 -5634 -4602 -6053 4449 -6272 1084 -304 -3674 10802 6687 10349 14500 5541 1103 3535 1138 -13785 1282 1583 6111 -1251 -11282 5110 4006 -11487 603 56 4800 3592 12142 -5878 -3830 900000 8770 -5639 -6872 -3447 -2129 -7408 3085 5375 3248 2367 -3821 -4806 4113 -3938 228 7345 -4718 -584 5583 4850 -7318 -1406 -1764 16524 -5319 -3298 -5264 -4005 4922 1111 3259 -11680 10017 1817 -15772 5379 4400 1539 1109 6295 -2372 5177 3277 3475 14633 11595 -5567 -319 -1937 -12104 12731 -1804 1516 -5468 -3282 1411 2604 178 -11539 -8520 3141 6346 -8079 3857 -5847 4378 -2088 7463 -192 -9086 2016 -2262 -4099 769 1717 8521 1838 -2603 6753 -341 8289 3451 -1642 -3042 8469 -7145 5369 11860 7779 12284 -6721 2070 9816 6532 3869 4463 -14473 2461 -8846 5583 6316 -2055 -14211 7910 4823 5925 515 -11166 3087 4791 -10885 -15025 3932 -843 7219 12334 -7650 41 5473 -6880 -4118 -5800 -4606 -6033 3942 -6175 996 -285 -3557 9039 5815 8660 11598 4796 982 3031 995 -14079 1146 1442 5414 -1211 -12217 4737 3779 -12721 594 56 4489 3344 10160 -5787 -3676 SO 20190407T102033.0Z 7036.430938 421 1 32.01 2 88.90 80.96 111.89 91.35 0.00 1 0.00 1 0 15 4.128e-02 4.166e-02 3.938e-02 3.907e-02 5.634006e+03 2.568592e+03 2.972100e+02 -6.000000e+00 2.293534e+03 287.10 -2.00 20.00 -2.00 505.31 0.00e+00 1.594574e-03 1.074230e-03 9.466865e-05 -6.000000e+00 1.155664e-03 287.10 -2.00 20.00 -2.00 500.37 0.00e+00 2.252810e+00 7.614555e-01 6.470086e-02 -6.000000e+00 8.021053e-01 226.71 -2.00 3.16 -2.00 501.98 0.00e+00 18.319 0.058 489.00 513.00 1 9.1033e+00 5.8450e-02 2.8056e-02 -6.0000e+00 6.1620e-02 4.6717e-02 1.4806e-02 1.9556e-03 -6.0000e+00 1.5927e-02 1.3115e-05 -3.0137e-03 3.6610e-03 4.0193e-05 -6.0000e+00 4.0529e-03 -1.2698e-02 1.0492e-05 12 8 8 10 0 0 98.75 21.18 -0.65 -0.01270 -0.03360 8 2 1 4 0 4000.000 25.39 19.99 21.18 -1595 -971 2197 -1500 -3010 -5835 4551 1516 -4106 5060 -2835 -1362 -194 -3926 2271 52 -579 -2769 -2136 5132 2854 -4349 -9082 4364 1462 -2890 2195 4467 -11216 4469 -3593 -246 3889 2303 3652 10438 -524 4642 -3641 1518 10849 1568 -2404 996 2015 2223 -638 -4536 -1869 1025 5829 9491 2010 3980 -2121 1820 -3639 692 -315 2953 6076 -7537 4442 5916 3077 1932 -2685 2240 -3884 -2674 -6445 4776 -2880 -2793 1704 -8435 -1034 6769 -1990 -1804 2688 9661 -5743 -1955 840 -2018 -1463 -5636 1304 563 -4031 804 76 -747 4805 5521 -2602 -2757 -2052 5423 -2254 -107 1021 2476 -4194 -4852 -835 -1061 2304 3781 -644 -335 963 10187 3136 -2211 7449 3431 -1210 -1302 -7938 1332 -1280 530 6886 3268 -1173 -690 -2759 3073 6037 2319 5742 567 3504 -2832 -1809 -1765 -460 360 3465 4290 -5485 3533 -1952 -1724 -8772 548 -3262 -842 4036 -8883 1004 4236 -1545 -941 2116 -1448 -3044 -6228 4474 1560 -4498 5039 -3019 -1408 -195 -4060 2186 51 -575 -2864 -2253 5150 2966 -4875 -10691 4502 1560 -3239 2342 4643 -13490 4496 -3808 -247 3744 2299 3721 10235 -581 4871 -4109 1609 10388 1645 -2639 1068 2166 2412 -717 -5293 -2105 1105 5864 8966 1992 3791 -2140 1794 -3902 732 -321 2934 5847 -8300 4349 5736 3079 1952 -2815 2204 -3998 -2682 -6634 4345 -2806 -2721 1603 -8905 -1022 6158 -1944 -1727 2432 8118 -5637 -1858 782 -1951 -1422 -5761 1248 543 -4062 772 74 -740 4566 5247 -2666 -2779 -2004 4790 -2099 -96 889 2134 -3956 -4785 -821 -1069 2251 3603 -634 -327 936 9170 3078 -2182 6730 3247 -1208 -1312 -8584 1309 -1275 510 6128 2996 -1129 -665 -2729 2873 5481 2184 5227 541 3213 -2724 -1703 -1658 -432 341 3256 4070 -5820 3462 -2036 -1806 -9921 567 -3498 -872 3910 -9586 968 3961 SO 20190407T102437.0Z 7036.433762 425 1 32.01 2 88.07 80.38 111.09 90.78 0.00 1 0.00 1 0 22 5.976e-03 5.891e-03 2.239e-03 2.234e-03 1.119870e+04 1.529163e+02 7.436568e+02 -6.000000e+00 3.319591e+02 287.10 -2.00 20.00 -2.00 505.38 0.00e+00 2.507243e-03 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