File name: Pandora114s1_BuenosAires_20190506_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T062556.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190506_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190506 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190506T103913.0Z 7065.443901 464 1 32.01 2 89.74 69.61 106.50 79.38 0.00 1 0.00 1 0 22 8.496e-02 8.062e-02 8.123e-02 7.944e-02 1.240139e+04 5.927942e+03 1.004738e+03 -6.000000e+00 4.687987e+03 285.29 -2.00 20.00 -2.00 505.34 0.00e+00 2.698556e-03 2.149607e-03 1.633674e-04 -6.000000e+00 2.367502e-03 285.29 -2.00 20.00 -2.00 500.21 0.00e+00 1.987156e+00 1.577962e+00 5.151407e-02 -6.000000e+00 1.645546e+00 225.18 -2.00 3.16 -2.00 501.81 0.00e+00 20.052 0.075 489.00 513.00 1 9.5627e+00 1.2014e-01 3.1254e-02 -6.0000e+00 1.2641e-01 7.2534e-02 3.0503e-02 2.3003e-03 -6.0000e+00 3.2572e-02 6.3707e-06 4.0242e-03 7.1634e-03 1.0318e-04 -6.0000e+00 8.3304e-03 -8.9019e-02 6.6743e-04 12 8 8 10 0 0 98.19 21.26 9.74 -0.08902 -0.06111 8 2 1 4 0 4000.000 25.39 20.00 21.26 -15069 1355 5172 -3047 5670 17 -2148 -5009 10256 8750 4040 3656 5036 2260 -7748 40 6240 11944 5591 -5626 14416 5399 -3300 12374 4063 -5987 -7460 3647 -3439 734 -9326 -345 -1731 -2735 6145 -3078 11613 1134 -7040 992 3654 -2876 -14019 -162 -282 13731 1369 -10801 -5072 6149 12352 -47 173 -3499 1523 -15151 -8938 4893 3013 4149 -2269 -309 -3594 -10658 -7585 2906 -4092 1470 4002 8052 11335 -515 -4372 11742 -5900 23823 -1401 16845 -1212 13297 21250 -8947 2091 -15193 6819 14252 7188 2826 -1382 5462 -1894 -14269 3050 -2851 10535 -5619 -1484 4961 -3782 7709 8026 -4258 3739 5605 -2104 3676 -9902 15139 -9970 -6281 -4046 -5584 8690 -1304 16340 -1599 -15606 -7627 14960 8081 -1286 16950 -16038 -1396 -4732 -3002 16951 3839 12830 -3043 -669 -5486 -3838 3630 -9179 2480 18740 12395 -2750 -5405 151 -678 661 -645 7769 -7727 7122 -6745 -3578 -1952 -7959 10929 3353 28820 -16680 1296 4919 -3255 5709 19 -2438 -5907 10383 8907 4247 3803 5099 2326 -8749 42 6213 11494 5486 -6280 13248 5438 -3632 11692 4197 -6870 -8675 3768 -3750 747 -10216 -342 -1762 -2896 6157 -3451 11274 1213 -8077 1041 3718 -3136 -17249 -176 -310 13259 1499 -13289 -5819 6193 11415 -47 171 -3561 1487 -17935 -10255 5004 3176 4329 -2521 -337 -4067 -13003 -8979 3078 -4589 1534 4010 7650 10298 -521 -4585 10547 -6402 19418 -1377 14517 -1150 11460 16769 -8928 1873 -16268 5908 11585 6332 2614 -1332 4891 -1816 -15488 2805 -2817 9178 -5716 -1416 4298 -3461 6116 6211 -3668 2966 4446 -1874 3238 -10362 12526 -10578 -6359 -3978 -5598 7655 -1289 13679 -1611 -18154 -8241 13034 7630 -1339 14603 -18891 -1393 -4814 -2995 13943 3624 11115 -3095 -665 -5378 -3692 3209 -9082 2293 14685 10437 -2583 -5323 143 -659 642 -642 7154 -8353 6656 -7231 -3688 -1949 -8276 9262 3057 20595 SO 20190506T104328.0Z 7065.446852 468 1 32.01 2 88.92 69.00 105.68 78.83 0.00 1 0.00 1 0 15 6.657e-02 6.566e-02 5.478e-02 5.395e-02 3.315259e+03 3.372182e+03 2.112500e+02 -6.000000e+00 3.671648e+03 285.29 -2.00 20.00 -2.00 505.30 0.00e+00 -9.697894e-04 1.476274e-03 1.488253e-04 -6.000000e+00 1.854808e-03 285.29 -2.00 20.00 -2.00 500.21 0.00e+00 2.610285e+00 1.046646e+00 3.635676e-02 -6.000000e+00 1.291727e+00 225.18 -2.00 3.16 -2.00 501.85 0.00e+00 18.417 0.058 489.00 513.00 1 9.4172e+00 8.0244e-02 2.8011e-02 -6.0000e+00 9.9184e-02 6.0461e-02 2.0515e-02 1.6502e-03 -6.0000e+00 2.5637e-02 9.5481e-06 -2.3202e-05 5.0707e-03 5.6354e-05 -6.0000e+00 6.5340e-03 6.1222e-02 -4.1567e-04 12 9 8 11 8 0 75.23 21.26 2.93 0.06122 0.06106 8 2 1 4 0 4000.000 25.39 19.98 21.26 1856 -8109 -3433 -9009 6892 -9711 5566 -5058 522 6466 -10380 14279 903 -3315 3171 -471 -6455 -3586 10915 -1937 970 2563 4684 670 -12350 9390 -10735 -2180 7242 7965 -7581 3921 9253 -4170 10777 -3230 4797 1929 14475 1484 -11624 7612 -1306 8956 -3744 3100 6324 -6406 3658 -4819 1916 -5877 -565 876 -155 10044 -4011 9628 3001 -3221 76 5266 9361 525 12817 -4534 796 4351 -8785 -1669 -441 4540 3952 15225 -2617 -11260 5282 162 10093 -9053 3266 820 3762 3758 -9867 -8819 -3767 -875 4817 6379 -3399 8019 9066 -9308 14790 8116 5825 -4458 1335 7727 -1999 472 -10034 3955 -2390 2612 9617 -6717 654 -4887 8233 -4576 -2751 -320 1436 11954 -4164 1452 -531 10429 -5960 -6366 2273 -2572 10294 1479 2282 -487 -2502 4202 -3198 10027 -9504 4510 -12494 -2035 6439 -8835 14668 -2406 3749 582 -5777 -4813 -2908 9609 -3924 -6184 -1163 -2057 5123 8491 -1694 -4124 1774 -8669 -3605 -9657 6952 -11060 5554 -5689 558 6475 -12150 12889 920 -3483 3097 -477 -7009 -3869 10468 -2158 1060 2765 4955 739 -15590 9568 -13361 -2475 7380 7864 -8500 3857 8678 -4587 10564 -3736 5159 2122 13882 1601 -14180 7649 -1441 9000 -4316 3366 6667 -7634 3895 -5488 1993 -6423 -570 856 -153 9137 -4328 9301 3143 -3600 77 5048 8634 531 11481 -4811 792 4114 -9322 -1628 -420 4067 3540 12229 -2543 -12097 4836 155 8574 -9157 2893 743 3320 3342 -10143 -9066 -3724 -848 4427 5777 -3393 7157 8061 -10061 12711 7485 5449 -4539 1253 6641 -1850 418 -9784 3386 -2244 2426 8615 -7193 649 -5056 7375 -4644 -2764 -319 1424 10787 -4184 1387 -520 9214 -6211 -6615 2136 -2497 8679 1358 2087 -460 -2421 3804 -3114 8547 -9846 4040 -13099 -1893 5448 -8714 11591 -2305 3453 564 -6039 -5031 -3003 8819 -4150 -6715 -1198 -2112 4798 7529 -1645 -4119 SO 20190506T104739.0Z 7065.449757 472 1 32.01 2 88.12 68.40 104.88 78.29 0.00 1 0.00 1 0 15 4.545e-02 4.512e-02 3.669e-02 3.639e-02 6.919789e+03 2.402341e+03 5.048078e+02 -6.000000e+00 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