File name: Pandora114s1_BuenosAires_20190517_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T062304.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190517_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20190517T122043.7Z 7076.514395 108 1 33.45 2 73.38 51.31 124.63 224.63 0.00 1 0.00 1 0 17 2.824e-02 5.013e-03 7.315e-03 8.812e-04 3.540534e-01 4.364231e-04 3.776326e-03 -6.000000e+00 1.567254e-02 224.66 -2.00 3.16 -2.00 319.14 0.00e+00 7.132867e-04 1.062686e-04 1.814172e-04 -6.000000e+00 7.065547e-04 284.57 -2.00 20.00 -2.00 318.38 0.00e+00 3.440 0.000 302.00 328.00 3 6.5402e-01 1.2138e-03 3.7776e-02 -6.0000e+00 3.8652e-02 4.8524e-02 1.4109e-03 1.6459e-02 -6.0000e+00 4.2088e-02 -1.1362e-02 1.0105e-03 8.1375e-03 -6.0000e+00 2.5152e-02 -7.5045e-03 5.3285e-04 2.4302e-03 -6.0000e+00 1.0825e-02 6.0308e-03 -5.4020e-05 2.5412e-05 2.5784e-05 -6.0000e+00 7.3450e-04 5.6535e-03 -1.4840e-04 10 0 0 10 0 0 79.79 21.80 0.42 0.00565 0.00525 268 53 1 5 0 124.324 25.90 20.01 21.80 -8807 -4167 -13321 -8068 -14356 -7062 -10214 -6279 -4987 -10306 -3292 -9768 -435 -3778 -909 -692 -1372 580 -1464 1590 -2122 1661 -349 -33 -53 -1990 -1014 -2917 -838 -699 -236 1900 140 -934 -3345 -1762 -2892 88 164 -709 -436 -876 -201 -274 701 125 6 -236 -953 673 481 1210 1309 896 690 1136 1002 -175 500 -55 786 1554 1866 2009 -22 414 -192 -363 1224 1033 581 327 155 330 202 -422 -276 -929 -589 -541 -1060 -980 -2056 -1560 -952 -835 -34 148 441 150 666 556 -334 241 232 -58 174 812 -23 -312 47 -670 -344 330 -102 -1224 -567 -669 -490 372 344 329 95 287 -121 111 535 211 235 -84 -385 -265 110 47 260 707 -160 622 762 59 194 -198 -379 -186 386 -96 -224 303 167 -118 6 -93 -526 -97 -326 -159 -559 -294 -506 -231 -382 -260 -225 -508 -152 -521 -25 -267 -73 -61 -129 57 -153 168 -237 177 -39 -4 -7 -274 -137 -379 -102 -86 -32 281 23 -161 -555 -283 -515 18 41 -210 -141 -302 -71 -98 250 45 2 -84 -340 241 184 502 583 386 311 524 475 -84 233 -28 405 778 1028 1203 -14 247 -107 -196 689 665 418 249 119 246 141 -268 -174 -553 -360 -339 -765 -794 -1835 -1462 -939 -884 -38 159 477 174 725 558 -309 210 209 -58 195 929 -30 -412 59 -783 -399 372 -123 -1473 -713 -882 -678 548 547 553 162 468 -185 156 717 288 338 -130 -630 -436 176 74 388 1005 -218 878 1103 86 308 -333 -660 -332 720 -177 -433 600 337 -239 13 -176 -959 -187 SU 20190517T122717.9Z 7076.518957 111 1 33.82 2 72.33 50.11 125.50 223.07 0.00 1 0.00 1 0 17 2.165e-02 4.965e-03 4.664e-03 6.662e-04 3.355863e-01 3.296578e-04 3.609629e-03 -6.000000e+00 1.201918e-02 224.66 -2.00 3.16 -2.00 318.89 0.00e+00 7.461891e-04 7.409936e-05 1.884566e-04 -6.000000e+00 5.417582e-04 284.57 -2.00 20.00 -2.00 318.12 0.00e+00 3.249 0.000 302.00 328.00 3 3.3315e-01 9.0555e-04 3.5714e-02 -6.0000e+00 2.9642e-02 4.7326e-02 1.0451e-03 1.5629e-02 -6.0000e+00 3.2275e-02 -1.0875e-02 7.2555e-04 7.7053e-03 -6.0000e+00 1.9288e-02 -7.1181e-03 3.8237e-04 2.2969e-03 -6.0000e+00 8.3030e-03 1.0236e-02 5.0047e-05 1.9109e-05 2.4096e-05 -6.0000e+00 5.6317e-04 4.7656e-03 -1.3958e-04 10 0 0 10 0 0 3.35 21.82 0.44 0.00477 0.00514 426 84 1 5 0 77.892 25.90 20.00 21.82 -1891 -8388 -3475 -9811 -9198 -8851 -7919 -2307 -6337 -4870 -7125 -3122 -4574 -748 -335 -1252 412 -522 974 -504 162 566 -216 353 -1068 458 -1834 -1514 -1652 -751 611 777 1471 -2544 -2084 -2668 -2188 57 -132 -57 -1226 -110 -394 -235 195 -216 -24 -334 -478 267 1036 818 1001 1419 439 1320 451 420 76 419 1115 1246 1943 1521 443 168 -41 -265 1283 1166 383 471 -76 368 -25 -446 -274 -1109 -326 -899 -884 -1079 -2103 -1549 -924 -666 -243 135 263 325 494 430 -172 25 634 47 210 684 78 -242 -80 -586 -489 504 -186 -1104 -529 -801 -353 306 432 300 206 303 -104 191 461 273 298 -4 -469 -308 87 45 317 636 -36 629 893 75 81 -127 -372 -108 243 -46 -219 198 218 -228 53 -108 -400 -96 -81 -413 -163 -448 -378 -360 -353 -112 -353 -275 -412 -187 -325 -61 -31 -131 45 -60 116 -63 21 71 -28 49 -162 71 -286 -222 -231 -105 92 131 271 -499 -382 -482 -431 13 -37 -19 -444 -42 -154 -93 77 -86 -9 -130 -185 105 428 369 439 656 213 653 230 215 38 207 559 671 1144 976 296 106 -24 -151 759 787 290 376 -62 287 -19 -299 -164 -693 -207 -588 -662 -908 -1944 -1501 -942 -728 -259 149 294 356 558 446 -164 22 584 48 240 797 101 -325 -103 -696 -579 577 -228 -1354 -678 -1078 -496 458 696 471 325 497 -159 269 620 374 429 -6 -772 -511 140 71 476 909 -50 818 1185 109 128 -213 -644 -191 414 -83 -421 388 437 -460 105 -204 -724 -170 SU 20190517T123231.7Z 7076.522589 114 1 33.40 2 71.51 49.14 126.19 221.80 0.00 1 0.00 1 0 17 2.115e-02 5.082e-03 1.117e-02 1.697e-03 3.206499e-01 8.328368e-04 3.407112e-03 -6.000000e+00 1.174388e-02 224.66 -2.00 3.16 -2.00 318.81 0.00e+00 8.726963e-04 1.829062e-04 1.944264e-04 -6.000000e+00 5.293463e-04 284.57 -2.00 20.00 -2.00 318.02 0.00e+00 3.113 0.000 302.00 328.00 3 2.2391e+00 2.2800e-03 3.4156e-02 -6.0000e+00 2.8963e-02 4.2670e-02 2.6270e-03 1.4809e-02 -6.0000e+00 3.1536e-02 -5.0826e-03 1.8116e-03 7.3370e-03 -6.0000e+00 1.8846e-02 -9.0340e-03 9.5490e-04 2.2400e-03 -6.0000e+00 8.1129e-03 1.7694e-03 6.6045e-05 4.8772e-05 2.2232e-05 -6.0000e+00 5.5027e-04 4.6353e-03 -1.4252e-04 11 1 0 11 8 0 70.79 21.85 0.48 0.00464 0.00513 74 15 1 5 0 451.112 25.90 20.00 21.85 -4308 -8126 -2189 -9666 -6098 -8028 -4735 1919 -7294 -5084 -10508 -1919 -4016 2893 2743 334 327 -519 1499 -1123 -217 -1470 -1783 833 -474 1319 -873 -551 -180 135 281 -305 1839 -2446 -1854 -1521 -1105 -61 591 -60 -1000 -1004 -1519 -295 518 69 -996 -313 -489 -372 1173 637 883 845 945 915 321 242 -309 649 1078 1499 2052 1511 262 -13 -244 -781 1783 990 479 436 60 437 202 -170 23 -1212 -197 -978 -747 -940 -1676 -1491 -1141 -918 -250 125 -36 461 326 623 -189 288 519 -58 540 593 121 -302 -203 -668 -322 486 -320 -1085 -724 -829 -268 288 603 211 263 127 111 115 452 380 120 91 -423 -285 -1 46 363 553 -4 731 874 -2 169 -249 -328 69 11 15 -439 216 194 -90 63 -146 -395 -82 -206 -434 -110 -478 -263 -351 -221 96 -442 -310 -673 -121 -303 240 264 36 37 -63 186 -149 -29 -197 -247 120 -74 210 -140 -83 -26 19 44 -53 345 -489 -345 -277 -220 -14 167 -20 -366 -387 -607 -118 206 28 -400 -123 -191 -147 484 287 424 430 498 496 179 135 -170 348 590 878 1195 959 173 -8 -155 -481 1129 653 353 340 47 333 145 -122 15 -740 -121 -684 -542 -764 -1491 -1395 -1127 -972 -280 146 -43 533 356 624 -174 248 459 -56 588 721 162 -386 -272 -826 -363 531 -376 -1388 -969 -1163 -392 410 922 341 427 197 160 167 626 533 179 133 -657 -446 -2 68 563 817 -6 978 1194 -3 274 -393 -531 114 19 28 -854 428 393 -184 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