File name: Pandora114s1_BuenosAires_20190604_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T064603.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190604_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190604T105945.0Z 7094.458160 488 1 32.01 2 89.75 62.21 101.15 70.74 0.00 1 0.00 1 0 15 1.207e-01 1.080e-01 1.108e-01 1.070e-01 5.280325e+03 6.944424e+03 3.785580e+02 -6.000000e+00 6.613319e+03 283.67 -2.00 20.00 -2.00 505.23 0.00e+00 2.291949e-03 2.902492e-03 1.254300e-04 -6.000000e+00 3.351170e-03 283.67 -2.00 20.00 -2.00 500.06 0.00e+00 2.325695e+00 2.131413e+00 4.333337e-02 -6.000000e+00 2.348482e+00 224.33 -2.00 3.16 -2.00 501.68 0.00e+00 20.125 0.076 489.00 513.00 1 9.8314e+00 1.6352e-01 3.1177e-02 -6.0000e+00 1.8013e-01 9.1531e-02 4.1864e-02 1.9374e-03 -6.0000e+00 4.6756e-02 4.7354e-06 -1.3022e-03 1.0182e-02 6.0363e-05 -6.0000e+00 1.1847e-02 1.0100e-01 -8.9016e-04 12 9 8 11 8 0 -522.88 21.21 17.70 0.10100 0.09197 8 2 1 4 0 4000.000 25.39 20.01 21.21 -3269 1805 5117 14957 -1543 -3029 10202 2555 1136 -8699 -8766 -2746 3307 6322 6763 4079 -13360 4901 -14491 14049 7287 -404 10516 -8698 -11694 6174 27336 -10793 5560 -11150 15089 29986 -10431 -2064 12508 4191 -316 16521 -988 -1535 -6747 -3175 2541 -10115 -1005 7327 -9937 20844 2374 29849 6867 130 -4637 -2000 3144 -10281 39990 -18554 592 633 -1353 3659 5839 20125 -634 -4555 -6664 17093 -979 2963 8912 -6860 -13418 3054 -1004 -17245 -6740 -663 8383 12719 -11997 -17485 17512 16273 -2139 -12495 -1090 2505 21524 1403 -8230 960 -7341 14269 5181 12622 2806 6087 -7257 3323 -2095 -9885 -5847 -5864 -2430 23068 -16754 25474 -12386 3552 5886 1000 1676 -4275 -13750 9759 31704 -5477 5552 -5933 5424 31238 -13402 11454 -6417 29650 17106 1578 -5150 5729 8615 -4392 4931 -813 -8935 21160 -11809 15295 -4418 22934 -3725 8858 22414 -6916 -5017 -17940 16056 -5893 4515 -9272 -4575 5593 -10250 21224 -3307 1745 4908 13452 -1688 -3451 10399 2853 1294 -10888 -10841 -3148 3519 6444 6792 4188 -15327 4766 -17536 13071 7340 -441 10298 -10343 -14397 6392 22946 -13212 5717 -13259 13404 22443 -11674 -2166 11724 4397 -351 15486 -1092 -1686 -7740 -3509 2666 -12170 -1118 7585 -12303 18955 2574 24220 6869 136 -4930 -2028 3013 -11434 27694 -23751 638 686 -1495 3840 6004 18019 -701 -5225 -7738 15424 -1041 2984 8354 -7438 -15393 2969 -1025 -19678 -6984 -644 7312 10426 -12430 -19034 13436 12700 -2020 -13192 -1037 2316 16515 1315 -8473 900 -7510 11884 4791 10926 2668 5508 -7329 2942 -1910 -9529 -5330 -5345 -2183 16640 -18678 19044 -13565 3284 5249 931 1561 -4289 -15419 8768 23078 -5819 5316 -6420 5265 23354 -15468 10140 -6691 21388 14022 1521 -5336 5335 7796 -4256 4352 -758 -8934 16374 -11808 12337 -4118 17596 -3587 7654 17154 -7172 -5140 -21038 13478 -6183 4264 -9958 -4603 4971 -10502 15851 SO 20190604T110352.0Z 7094.461019 492 1 32.01 2 89.01 61.62 100.39 70.22 0.00 1 0.00 1 0 15 6.475e-02 6.557e-02 6.137e-02 6.035e-02 5.299672e+03 4.086021e+03 5.870817e+02 -6.000000e+00 3.549732e+03 283.67 -2.00 20.00 -2.00 505.34 0.00e+00 1.624147e-03 1.654431e-03 8.885401e-05 -6.000000e+00 1.796684e-03 283.67 -2.00 20.00 -2.00 500.22 0.00e+00 3.346784e+00 1.197504e+00 1.432147e-02 -6.000000e+00 1.252991e+00 224.33 -2.00 3.16 -2.00 501.84 0.00e+00 18.664 0.061 489.00 513.00 1 9.3905e+00 9.1667e-02 2.8233e-02 -6.0000e+00 9.6210e-02 4.6808e-02 2.3156e-02 1.6037e-03 -6.0000e+00 2.4787e-02 8.5854e-06 -4.8113e-03 5.6119e-03 7.2417e-05 -6.0000e+00 6.3462e-03 1.4375e-02 7.9985e-05 12 8 8 10 0 0 -89.52 21.21 5.24 0.01438 -0.01900 8 2 1 4 0 4000.000 25.39 20.00 21.21 -4733 -7727 4842 -3392 -2707 -9052 -810 -4206 6357 -3273 -1650 5852 9967 538 -2685 3489 -7600 5638 -1461 2524 -560 4538 6611 4982 10989 -954 7994 -5589 -23464 2620 1287 3512 -6452 1214 5790 934 1089 -511 9621 9682 3500 870 1508 4078 -1950 1920 -843 -3576 -5343 -4273 1054 1733 -579 -769 2843 7712 702 -1474 8395 74 -6084 13304 -4265 7549 5411 2013 -9255 -7445 14525 -15529 -1952 5185 424 1440 -1413 6632 779 3425 3602 -2174 10627 6706 1382 -5590 10348 9909 -2260 7286 239 -6307 -4748 12314 -339 -10159 184 2933 847 414 -1319 6898 15132 9762 514 806 -16814 3141 -10511 10388 528 -248 6644 -3096 2197 -6007 -786 2661 -1041 -9818 8668 3293 6264 -2386 4331 -3597 -11151 321 2003 818 17158 3343 319 -798 -1878 6018 -3993 4466 -10313 -5206 -6755 2808 779 9784 -5259 -1872 2009 -1495 14990 -3603 -7162 345 -6754 -4723 4027 5302 -4780 -8132 4625 -3641 -2975 -10865 -914 -4977 6797 -3577 -1751 6084 9814 537 -2743 3344 -8214 5448 -1556 2638 -609 4707 6728 5169 10793 -1061 8136 -6481 -32115 2697 1305 3422 -6973 1245 5869 1020 1199 -568 9563 9509 3631 927 1606 4279 -2200 2106 -954 -4147 -6239 -4854 1110 1763 -587 -767 2736 7209 725 -1599 8378 81 -7032 12646 -4845 7653 5613 2017 -10267 -7984 13120 -17515 -1899 4640 395 1332 -1359 5959 746 3166 3264 -2050 8724 5703 1242 -5416 8610 8354 -2173 6413 227 -6367 -4706 10291 -323 -10819 178 2787 814 392 -1239 5816 11471 7653 437 689 -17596 2800 -11116 9066 508 -238 5872 -3011 2048 -6176 -779 2578 -1055 -10928 8078 3264 6046 -2497 4180 -3698 -11487 312 1813 754 14339 3025 298 -753 -1791 5278 -3822 3870 -10265 -4929 -6583 2541 735 8581 -5436 -1890 1965 -1525 13043 -3787 -7778 343 -7075 -4751 3672 4798 SO 20190604T110804.0Z 7094.463935 496 1 32.01 2 88.25 61.02 99.61 69.69 0.00 1 0.00 1 0 15 5.330e-02 5.142e-02 5.324e-02 5.249e-02 4.752527e+03 3.382095e+03 1.083001e+02 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