File name: Pandora114s1_BuenosAires_20190608_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T064636.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190608_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190608T110154.1Z 7098.459654 496 1 32.18 2 89.75 61.68 143.36 109.61 0.00 1 0.00 1 0 36 8.948e-02 8.464e-02 9.144e-02 8.928e-02 8.951190e+03 6.286125e+03 5.666344e+02 -6.000000e+00 4.899624e+03 283.47 -2.00 20.00 -2.00 505.29 0.00e+00 2.342533e-03 2.410474e-03 1.996602e-04 -6.000000e+00 2.481749e-03 283.47 -2.00 20.00 -2.00 500.10 0.00e+00 1.075920e+00 1.786211e+00 4.759344e-02 -6.000000e+00 1.736332e+00 224.26 -2.00 3.16 -2.00 501.73 0.00e+00 20.124 0.076 489.00 513.00 1 9.7362e+00 1.3629e-01 3.1439e-02 -6.0000e+00 1.3324e-01 1.1271e-01 3.5116e-02 2.0093e-03 -6.0000e+00 3.4464e-02 5.7131e-06 -7.3509e-03 8.3332e-03 8.3613e-05 -6.0000e+00 8.7837e-03 9.8738e-02 -6.5849e-04 12 9 8 11 8 0 99.17 20.69 -1.84 0.09874 0.04775 8 2 1 4 0 4000.000 24.96 20.00 20.69 -5245 2565 2345 15721 -3172 1098 8530 -4049 338 -3778 7878 1637 7287 -8860 2410 -1691 -3570 -4761 -674 6182 -965 -2757 -2683 -393 5563 -9156 6321 -109 -13200 6317 -8244 6459 -2261 -5542 16142 4625 5544 -1140 4395 -6929 6341 -3340 6038 312 -12592 -427 4584 20011 8297 11567 15158 -2725 -8189 -2591 -326 -10693 2124 -12451 1475 -422 4512 1042 -4083 -2044 7645 343 614 11882 9030 -1676 6969 -15043 11176 -18501 -2572 -4553 4915 -4993 -4931 19968 -815 335 13023 -10102 752 17731 6911 -1100 3369 2694 -7763 4981 2860 4416 -1172 -5840 17114 -8083 -3791 22058 24900 -20156 1047 3016 -13141 23997 1796 15338 -3598 1301 5427 -14934 4159 -3600 5250 -11383 -904 -11270 18574 8345 9713 -8036 12204 7404 -11739 9947 2140 3334 -7681 22512 -14938 6258 9791 -11145 -6065 3012 6633 8768 -4752 997 5366 -364 -12777 -2658 13372 -12647 5132 3173 -2854 2030 3589 1434 1493 9588 -5411 2454 2301 13957 -3510 1194 8799 -4809 387 -4488 8225 1791 7426 -10468 2516 -1707 -3687 -5057 -704 6168 -1048 -3056 -2974 -427 5713 -10952 6491 -119 -16251 6266 -9188 6068 -2309 -5950 14411 4777 5758 -1264 4565 -7965 6327 -3664 6060 335 -15576 -474 4868 18215 8424 11204 13887 -2910 -8983 -2630 -321 -11855 2132 -14894 1567 -461 4686 1119 -4622 -2278 7762 374 663 11301 8694 -1770 6669 -17731 10042 -20950 -2671 -4583 4847 -5080 -4936 16312 -758 306 10473 -10278 691 13870 6087 -1059 3114 2505 -7984 4496 2644 4059 -1154 -6070 14043 -8357 -3650 15928 17026 -21170 876 2475 -12940 16934 1651 12669 -3622 1239 4899 -16421 3799 -3604 4882 -12640 -910 -12638 15546 7806 9033 -8923 10948 6845 -12907 8706 2025 3137 -8110 17610 -15997 5751 8676 -11419 -5839 2605 5806 7483 -4404 888 4669 -341 -13749 -2614 11291 -13935 4756 3006 -2865 1923 3289 1314 1345 7948 SO 20190608T110606.0Z 7098.462570 500 1 32.01 2 88.99 61.08 142.57 108.70 0.00 1 0.00 1 0 15 7.834e-02 7.309e-02 6.878e-02 6.728e-02 7.247459e+03 4.590378e+03 4.944164e+02 -6.000000e+00 4.292066e+03 283.47 -2.00 20.00 -2.00 505.28 0.00e+00 1.766120e-03 1.808228e-03 5.216594e-05 -6.000000e+00 2.173311e-03 283.47 -2.00 20.00 -2.00 500.09 0.00e+00 1.274385e+00 1.330511e+00 4.409633e-02 -6.000000e+00 1.517875e+00 224.26 -2.00 3.16 -2.00 501.72 0.00e+00 18.632 0.061 489.00 513.00 1 9.6559e+00 1.0148e-01 2.8354e-02 -6.0000e+00 1.1652e-01 1.0177e-01 2.5913e-02 1.8839e-03 -6.0000e+00 3.0052e-02 7.6469e-06 5.6749e-03 6.2820e-03 5.4804e-05 -6.0000e+00 7.6812e-03 -7.9461e-02 5.7668e-04 12 9 8 11 8 0 98.47 20.70 5.29 -0.07946 -0.04010 8 2 1 4 0 4000.000 24.96 20.00 20.70 -9419 -3970 -3012 6637 -6747 2976 -6726 8678 3372 1489 7835 -8792 12544 -8162 3997 -7128 12116 3752 -7761 -1887 6095 -3651 1671 4093 -9481 383 -3040 -9193 32133 840 2104 10537 -3941 10551 -7203 3782 -3678 17263 4753 -6414 -445 3197 -1722 2317 12594 2271 -794 -10817 -4764 -309 2678 12778 1468 1799 7412 1365 -1554 -4954 -772 107 731 -11532 -3581 2438 -3587 -1519 -9417 15370 634 10203 7601 -202 10176 -3627 9305 -4531 3015 1604 -8333 -4798 -13305 15747 4182 22811 4767 -1388 10046 -8229 10601 268 3993 -6084 13611 4183 -8913 12085 -2599 -2202 5931 -7156 -2195 -1484 17059 32 2655 -3952 10641 -10196 -2907 -9804 1919 6387 -4485 2939 -1345 -3422 6725 -12627 6748 316 -521 6373 -6459 18895 -5361 10355 -3590 12871 -3718 9294 266 -2756 2876 -5328 -4901 -10314 12866 -2329 -4818 1913 -5826 3394 12938 -5217 -3861 9403 -6820 -4318 1944 4820 -6007 -2497 3569 752 -10162 -4133 -3207 6629 -7915 3239 -8207 9159 3749 1670 8121 -10604 12056 -9537 4105 -7648 10869 3745 -8907 -2075 6218 -4110 1786 4284 -11423 420 -3436 -10955 24869 865 2082 9499 -4159 9929 -8362 4008 -4205 15866 4891 -7305 -476 3304 -1885 2465 12239 2467 -890 -13319 -5446 -331 2721 11406 1433 1733 6812 1368 -1654 -5577 -842 115 784 -13996 -4031 2594 -4054 -1669 -11056 13855 652 9422 7119 -203 9173 -3544 8634 -4576 2822 1501 -8451 -4629 -13877 12269 3672 16739 4225 -1321 8614 -8515 9090 254 3637 -6145 11391 3897 -9553 10462 -2561 -2106 5086 -6814 -1946 -1284 12237 28 2321 -3845 9212 -10970 -2888 -10306 1780 5687 -4511 2786 -1348 -3527 6293 -14420 6399 322 -535 6043 -6843 15267 -5458 9007 -3611 11036 -3549 8276 243 -2598 2555 -5085 -4583 -10045 10502 -2097 -4523 1715 -5742 3095 10843 -5283 -3880 8318 -7118 -4390 1840 4358 -5920 -2334 3130 685 SO 20190608T111021.0Z 7098.465521 504 1 32.01 2 88.23 60.47 141.78 107.80 0.00 1 0.00 1 0 15 5.139e-02 5.015e-02 5.196e-02 5.120e-02 3.973434e+03 3.276624e+03 2.092814e+02 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