File name: Pandora114s1_BuenosAires_20190810_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T071036.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190810_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190810 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190810T104507.0Z 7161.447998 363 1 32.01 2 89.73 70.78 122.76 200.49 0.00 1 0.00 1 0 15 6.620e-02 6.546e-02 8.181e-02 8.028e-02 3.962461e+03 5.105920e+03 3.593268e+01 -6.000000e+00 3.606385e+03 282.06 -2.00 20.00 -2.00 505.21 0.00e+00 2.854481e-03 2.169764e-03 1.674667e-04 -6.000000e+00 1.831173e-03 282.06 -2.00 20.00 -2.00 500.01 0.00e+00 2.261487e+00 1.601618e+00 9.032275e-02 -6.000000e+00 1.298028e+00 226.23 -2.00 3.16 -2.00 501.64 0.00e+00 20.117 0.076 489.00 513.00 1 9.5437e+00 1.2248e-01 3.1836e-02 -6.0000e+00 9.9355e-02 1.0776e-01 3.1843e-02 2.2010e-03 -6.0000e+00 2.6024e-02 6.3745e-06 4.1049e-03 7.5954e-03 6.6129e-05 -6.0000e+00 6.5126e-03 1.1117e-01 -1.1086e-03 12 8 8 10 0 0 58.56 20.07 5.23 0.11117 0.13965 8 2 1 4 0 4000.000 24.46 19.99 20.07 900000 -6276 -2503 -9703 5501 3193 1654 12354 -1499 7842 837 13038 3943 -2504 -3025 -3423 -1743 -2933 4584 7183 5085 9414 2378 -4045 10201 -7068 -6955 -3393 4489 3151 -5254 -6332 -2794 7729 -1747 -2288 1592 1628 -12527 5812 -2841 -1448 14192 -7581 1553 -9096 -6387 3527 1109 16053 5819 9555 917 -6079 -240 10259 -1703 6165 -11037 7396 -3004 -6824 4266 -1119 3949 5145 -7245 -7421 1438 5170 -5721 3207 9549 3983 3817 7260 -6352 -624 4466 -5701 -6881 11885 -5766 10630 -12481 -3916 -3055 -5367 2035 -10028 9318 -14996 6358 -2486 8907 7017 -1153 6649 -9357 -1841 -9443 -19 14232 -3143 3992 5129 -2779 1069 -28 5144 -417 740 -2071 -10217 -262 11230 -394 1760 7518 -2323 3304 -659 11976 -1701 420 7795 3296 2929 -2713 15089 1935 -12936 2302 -6007 9323 -9334 4706 4838 4026 40 -3916 6910 -6583 10197 1539 -1324 -6784 -2365 3655 1591 -8859 4405 4435 6051 900000 -6702 -2645 -11398 5720 3482 1869 12707 -1778 8419 887 12898 4211 -2627 -3157 -3574 -1801 -3123 4641 7234 5281 9383 2545 -4625 10167 -8417 -8282 -3880 4687 3256 -5733 -6842 -2917 7420 -1906 -2581 1745 1777 -15574 5946 -3144 -1580 13327 -8948 1695 -11166 -7673 3830 1222 14990 5891 9073 924 -6442 -240 9364 -1804 6210 -13432 7526 -3388 -7983 4476 -1167 4185 5371 -7945 -8029 1401 4780 -5824 2949 8171 3605 3491 6498 -6561 -604 4041 -5607 -6768 9644 -5586 8782 -13075 -3794 -2960 -5358 1891 -10505 8019 -16447 5659 -2446 7929 6419 -1139 5984 -9664 -1720 -9289 -16 10639 -2798 3376 4439 -2692 1015 -27 4629 -391 684 -1986 -10803 -255 9886 -393 1731 7025 -2411 3250 -671 10601 -1699 405 6938 3080 2603 -2562 11943 1746 -13532 2067 -5839 7681 -9117 3942 4031 3410 36 -3734 6013 -6643 8779 1453 -1293 -7034 -2353 3418 1502 -9103 3874 3838 5153 SO 20190810T104910.0Z 7161.450810 367 1 32.01 2 88.95 70.20 123.02 199.46 0.00 1 0.00 1 0 15 5.199e-02 5.088e-02 5.123e-02 5.064e-02 5.561330e+03 3.304983e+03 3.677441e+02 -6.000000e+00 2.832868e+03 282.06 -2.00 20.00 -2.00 505.25 0.00e+00 2.594379e-03 1.366702e-03 1.096089e-04 -6.000000e+00 1.437089e-03 282.06 -2.00 20.00 -2.00 500.15 0.00e+00 1.181856e+00 1.002577e+00 4.639671e-02 -6.000000e+00 1.012920e+00 226.23 -2.00 3.16 -2.00 501.77 0.00e+00 18.540 0.060 489.00 513.00 1 9.3733e+00 7.6661e-02 2.8325e-02 -6.0000e+00 7.7659e-02 1.0161e-01 1.9606e-02 1.8272e-03 -6.0000e+00 2.0115e-02 1.0285e-05 2.2124e-03 4.7593e-03 5.6487e-05 -6.0000e+00 5.1028e-03 8.2722e-03 -1.4897e-04 12 8 8 10 0 0 -28.44 20.08 2.54 0.00827 0.02362 8 2 1 4 0 4000.000 24.46 20.00 20.08 4255 -1397 -7502 -8199 698 1437 201 1054 -2684 -3466 -4945 1231 452 1462 -5894 -1686 2178 -1036 3695 1161 2568 858 938 2747 -3361 10501 -4642 6605 -5531 1026 1658 2678 -1088 -811 5459 1327 -2436 1106 -1247 702 -5337 3032 4750 5925 -811 843 375 -845 3482 -635 -1972 6248 -352 41 -3674 5781 12021 1670 -1422 5741 -4987 1178 -4702 3859 3739 -2399 -8642 10462 -592 -10001 -910 -2358 4269 -5768 748 -1472 3154 -4119 -2819 1036 9188 -2849 5522 -2357 -6075 6679 3188 6222 1410 1903 2918 -4700 2654 2303 2985 -3416 9799 -1143 -2717 -3366 2729 3589 4352 -4449 2744 -6338 -10504 -3987 15406 -6105 -994 -3601 -5879 -1174 4503 8274 2859 11253 4407 12958 14180 -2968 7584 -6503 1586 -14174 -9797 4869 -1173 -2307 -2118 858 3605 -5433 3444 195 6566 -5298 7796 1409 1093 2321 434 -10219 6476 513 -5128 179 -5508 7253 4127 1341 -9173 -1787 4028 -1417 -8325 -9477 759 1484 215 1126 -2984 -3855 -5499 1267 462 1461 -6280 -1718 2155 -1080 3766 1237 2720 926 1012 2918 -3815 10426 -5361 6776 -6315 1069 1668 2623 -1112 -848 5546 1440 -2766 1204 -1374 750 -6022 3150 4889 6098 -905 934 420 -954 3722 -696 -2140 6079 -357 41 -3793 5548 11179 1769 -1577 5947 -5385 1196 -5076 3844 3736 -2538 -9625 9478 -590 -10798 -887 -2305 3881 -5816 715 -1457 2994 -4166 -2764 961 7782 -2713 4848 -2252 -6069 5927 2957 5637 1343 1801 2725 -4739 2503 2208 2880 -3529 8786 -1120 -2638 -3206 2388 3051 3632 -4086 2410 -6331 -11308 -4083 12953 -6289 -963 -3575 -6038 -1169 4303 7701 2830 10299 4348 11819 12803 -2973 6732 -6532 1449 -15107 -10042 4336 -1114 -2216 -2028 796 3252 -5331 3047 175 5484 -4981 6510 1280 1015 2162 417 -11011 5938 501 -5331 176 -5726 6544 3760 1229 -9241 -1681 SO 20190810T105310.0Z 7161.453588 371 1 32.01 2 88.17 69.63 123.27 198.43 0.00 1 0.00 1 0 15 4.138e-02 4.050e-02 3.460e-02 3.427e-02 5.408921e+03 2.217144e+03 3.171815e+02 -6.000000e+00 2.254362e+03 282.06 -2.00 20.00 -2.00 505.26 0.00e+00 1.444588e-03 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