File name: Pandora114s1_BuenosAires_20190819_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T070800.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190819_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190819 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190819T103508.0Z 7170.441065 251 1 32.01 2 89.72 74.21 63.85 288.86 0.00 1 0.00 1 0 15 1.190e-01 1.088e-01 1.043e-01 1.009e-01 -2.979130e+03 5.810913e+03 2.506946e+01 -6.000000e+00 6.486604e+03 282.07 -2.00 20.00 -2.00 505.32 0.00e+00 3.836672e-03 2.776372e-03 1.717627e-04 -6.000000e+00 3.289570e-03 282.07 -2.00 20.00 -2.00 500.12 0.00e+00 3.889879e+00 2.011877e+00 5.984273e-02 -6.000000e+00 2.319625e+00 226.65 -2.00 3.16 -2.00 501.79 0.00e+00 20.099 0.076 489.00 513.00 1 9.6577e+00 1.5532e-01 3.1428e-02 -6.0000e+00 1.7784e-01 7.2209e-02 3.9220e-02 1.9247e-03 -6.0000e+00 4.6058e-02 4.9887e-06 1.0980e-02 9.5972e-03 5.1506e-05 -6.0000e+00 1.1683e-02 3.4234e-02 -2.9068e-04 12 9 8 11 4 0 -399.63 19.96 7.75 0.03423 0.11040 8 2 1 4 0 4000.000 24.35 20.01 19.96 3216 25503 -314 -13476 15623 -8104 5893 -8210 13746 -5148 -3072 -4534 -7715 4205 -1766 -718 -9233 -3806 8182 -1493 8446 -9799 20875 297 5972 15774 -7246 7020 46828 10979 -13903 -819 -8531 -6503 -5193 4163 9833 -18417 -3667 -5112 8019 163 3774 17282 4470 15054 -241 -14836 -3673 -2102 -969 -5623 31841 -3414 12530 6692 -5112 23276 -7592 19453 -4974 19352 -911 -5340 16920 -4111 20475 -4914 1699 -5961 -14372 16629 -13936 1796 994 3852 -12736 -1459 8481 132 12028 -1635 -3838 -1296 16825 -763 -15025 3507 -5666 19123 -490 10542 595 -1626 5761 -6704 23005 3235 9078 -11884 -1175 15939 -12254 7130 5243 3529 3881 1866 13800 3515 13234 -15861 27405 3753 -14092 3680 -14457 12214 -10774 27112 -15115 -4710 11462 -178 8288 -20402 18369 6078 19849 20706 -17233 1359 -5496 -325 5226 9899 -9946 -843 -8462 -812 435 -9936 16531 15509 13146 -250 -8738 16546 -13305 18628 -4422 -4465 6271 -3906 3023 19645 -324 -16380 14574 -9794 6288 -10153 13600 -6076 -3496 -5159 -8941 4279 -1897 -767 -10896 -4357 8500 -1615 8300 -11569 19473 319 6106 14670 -8459 7038 30887 10065 -15956 -821 -9397 -7249 -5891 4366 9729 -23930 -4063 -5698 7827 174 3908 15845 4717 14397 -269 -18983 -4143 -2287 -1016 -6008 22892 -3467 10991 6400 -5665 19805 -8863 17322 -5643 17232 -998 -6129 15512 -4609 17692 -5380 1715 -6408 -16589 13930 -15810 1753 990 3760 -14616 -1473 7608 127 10234 -1496 -3607 -1194 13872 -708 -16165 3145 -5571 14663 -458 8866 559 -1588 5308 -7047 17923 3040 7915 -12493 -1082 12123 -12275 5952 4571 3208 3552 1730 11179 3108 10556 -17066 19488 3457 -15860 3527 -16806 10951 -12192 20956 -17665 -4893 9993 -173 7380 -24348 14993 5637 16079 16645 -20247 1328 -5743 -320 4782 8508 -10333 -803 -8843 -803 433 -10466 14310 13618 11869 -244 -9357 13770 -14790 14744 -4297 -4261 5365 -3750 SO 20190819T103922.0Z 7170.444005 255 1 32.01 2 88.89 73.61 64.67 288.16 0.00 1 0.00 1 0 15 7.000e-02 6.699e-02 6.106e-02 6.015e-02 2.810800e+03 3.681697e+03 1.765700e+02 -6.000000e+00 3.814201e+03 282.07 -2.00 20.00 -2.00 505.31 0.00e+00 1.375673e-03 1.626327e-03 7.268844e-05 -6.000000e+00 1.934700e-03 282.07 -2.00 20.00 -2.00 500.27 0.00e+00 2.730390e+00 1.173353e+00 3.369327e-02 -6.000000e+00 1.364813e+00 226.65 -2.00 3.16 -2.00 501.90 0.00e+00 18.387 0.058 489.00 513.00 1 9.4811e+00 8.9892e-02 2.7848e-02 -6.0000e+00 1.0463e-01 5.1028e-02 2.2998e-02 1.6549e-03 -6.0000e+00 2.7116e-02 8.5818e-06 6.5769e-03 5.7049e-03 2.6985e-05 -6.0000e+00 6.8709e-03 3.5085e-02 -3.3836e-04 12 9 8 11 4 0 79.65 19.96 -1.12 0.03508 0.08070 8 2 1 4 0 4000.000 24.35 20.00 19.96 3675 -1141 -6926 17670 -5338 -4859 -759 5282 -5793 -6663 -3018 -5148 16614 -4949 14329 6064 3236 3168 -2997 9103 -4484 358 2747 -4801 -367 13058 941 -6804 -7097 -4117 -2730 1663 -8916 7321 -10827 12373 -2994 8736 -6673 6909 2937 -4177 5487 -7718 2956 -1893 -1340 3086 4780 8785 -3160 7645 3929 6876 -2263 -556 3282 -10486 17476 185 7147 -1110 -3218 1861 -9211 6598 2299 -63 -2342 16403 1690 -7711 1025 -11807 3271 -7921 -3804 646 2756 17474 -6513 427 -8059 9109 4379 -1074 1033 -3693 3445 4993 2100 3596 -6466 7435 -5638 8159 -4873 19163 -2701 -8083 1310 -3416 -1246 -3639 8967 12217 7358 -2581 -6927 12282 -3492 -1037 -5287 -1378 10679 3291 -287 -4187 10014 -6069 13584 -3084 -3892 3390 -14294 -6210 -7278 4544 -1851 58 2573 -721 14032 343 -5786 -700 10021 -2698 -11325 8791 1275 5091 153 6331 -2217 -5198 5998 -8545 -970 -3162 1586 339 -714 11228 3390 -1124 -7467 15405 -6025 -5587 -854 5651 -6467 -7439 -3203 -5504 15115 -5155 12223 5625 3129 3139 -3240 8874 -5041 384 2883 -5455 -401 12525 1017 -7890 -8118 -4451 -2834 1634 -9849 7080 -12982 12014 -3401 8757 -7712 6898 3037 -4647 5586 -9072 3160 -2143 -1512 3312 4979 8633 -3416 7213 3753 6298 -2286 -566 3315 -12449 15869 200 7192 -1213 -3380 1866 -10320 6692 2254 -63 -2330 14250 1576 -7815 948 -12488 3014 -8261 -3813 612 2508 13523 -6361 389 -8019 7687 3905 -1021 971 -3661 3186 4545 1965 3327 -6672 6768 -5922 7487 -5046 15325 -2627 -8102 1169 -3135 -1112 -3367 7534 10310 6698 -2616 -7275 10501 -3461 -1005 -5416 -1382 9642 3238 -295 -4506 9411 -6732 12365 -3285 -4116 3285 -15419 -6182 -7371 4114 -1791 55 2383 -691 11584 322 -5700 -646 8238 -2527 -11745 7623 1216 4750 152 5951 -2284 -5554 5763 -9514 -996 -3268 1529 324 -686 9658 SO 20190819T104334.0Z 7170.446921 259 1 32.02 2 88.06 73.01 65.48 287.47 0.00 1 0.00 1 0 15 2.710e-02 2.683e-02 2.673e-02 2.661e-02 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