File name: Pandora114s1_BuenosAires_20190827_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T070731.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190827_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190827T102512.0Z 7178.434167 388 1 32.01 2 89.72 77.53 69.49 40.34 0.00 1 0.00 1 0 36 1.340e-01 1.218e-01 1.266e-01 1.214e-01 1.143405e+04 8.837116e+03 7.532877e+02 -6.000000e+00 7.315837e+03 282.20 -2.00 20.00 -2.00 505.30 0.00e+00 -1.643560e-03 3.290895e-03 1.041954e-04 -6.000000e+00 3.709249e-03 282.20 -2.00 20.00 -2.00 500.12 0.00e+00 7.671514e-01 2.469143e+00 1.858895e-02 -6.000000e+00 2.617457e+00 227.02 -2.00 3.16 -2.00 501.78 0.00e+00 20.091 0.076 489.00 513.00 1 1.0131e+01 1.8829e-01 3.0926e-02 -6.0000e+00 2.0060e-01 1.1214e-01 4.8492e-02 1.8459e-03 -6.0000e+00 5.2098e-02 4.1148e-06 -1.4348e-02 1.0718e-02 8.7357e-05 -6.0000e+00 1.3173e-02 -1.1427e-01 1.4172e-03 12 8 8 10 0 0 95.96 21.47 11.53 -0.11427 -0.21380 8 2 1 4 0 4000.000 25.58 20.00 21.47 -13048 5500 15819 -9141 -2402 4804 8519 5098 252 9183 -3615 2597 9510 -6749 -7661 -245 -11968 21989 -13246 -3517 -10622 -10324 14074 -3308 12910 11562 -7620 14042 15219 1513 14324 7381 -340 -17066 2391 8079 -34 -5470 -8660 8328 1990 -4843 32943 718 20407 -1766 5101 10906 -9305 1742 -4291 4476 -3871 28146 -12384 -18714 -10199 -3242 -10220 4625 9214 -16167 5294 -9568 24954 12066 17958 -13012 10462 2501 -5625 -3606 -6417 -13977 -3166 10523 14638 13736 9222 3172 21558 4355 6353 15304 8961 30781 11551 37519 -13406 -2735 -7505 20755 -13316 3111 5546 -8389 779 -8406 1687 -8637 -4429 36204 5051 216 -10104 2020 37148 -11988 1170 2503 12922 9161 972 18921 15271 -13791 3357 40714 -10747 7003 -10969 -15893 -29800 -3271 -7252 -10123 21279 247 -1825 494 2652 14220 -6896 17749 4777 16734 -2900 -2412 19 3815 25290 3451 18124 7577 -23625 13117 14337 -6481 -10333 22020 -19824 5512 20226 900000 -14420 5096 13582 -10413 -2634 5024 8763 5504 288 9523 -4210 2803 9459 -7803 -8857 -263 -14549 19440 -17115 -4215 -12894 -12533 14357 -3753 12497 11375 -9069 13369 14127 1572 12729 6911 -346 -20988 2504 8205 -38 -6380 -10307 8259 2084 -5418 25353 769 18134 -1976 5342 10730 -11074 1825 -4665 4333 -3962 20545 -13559 -22272 -11490 -3498 -12001 4697 8919 -20138 5334 -11235 20789 11392 15815 -15383 9629 2460 -5935 -3690 -6721 -15858 -3265 9601 12891 12097 8341 2995 16762 4008 5746 12749 8034 22468 10356 26196 -14659 -2686 -7704 17126 -14561 2916 5115 -8861 736 -8441 1481 -8159 -3921 21005 3983 182 -9770 1818 24592 -13287 1140 2383 10957 8041 933 15340 12949 -15695 3221 26953 -11991 6616 -12484 -18915 -40120 -3309 -7498 -10692 16461 237 -1792 474 2486 11847 -7079 14126 4264 13070 -2739 -2279 18 3519 19188 3312 15233 7157 -28944 11903 12903 -6760 -11140 18017 -22760 4823 15151 900000 SO 20190827T102919.0Z 7178.437026 392 1 32.01 2 88.90 76.95 68.96 39.53 0.00 1 0.00 1 0 15 8.464e-02 7.776e-02 7.727e-02 7.566e-02 5.988984e+03 5.009012e+03 3.006214e+02 -6.000000e+00 4.617027e+03 282.20 -2.00 20.00 -2.00 505.26 0.00e+00 -8.641342e-05 2.049212e-03 3.501233e-05 -6.000000e+00 2.339300e-03 282.20 -2.00 20.00 -2.00 500.15 0.00e+00 6.736925e-01 1.505580e+00 5.741703e-02 -6.000000e+00 1.643846e+00 227.02 -2.00 3.16 -2.00 501.77 0.00e+00 18.406 0.058 489.00 513.00 1 9.8886e+00 1.1494e-01 2.8086e-02 -6.0000e+00 1.2612e-01 1.1045e-01 2.9740e-02 1.9011e-03 -6.0000e+00 3.2501e-02 6.7193e-06 -8.3519e-03 7.0427e-03 2.5023e-05 -6.0000e+00 8.2928e-03 -1.9085e-02 3.3188e-04 12 9 8 11 8 0 25.92 21.47 2.54 -0.01909 -0.07702 8 2 1 4 0 4000.000 25.58 20.01 21.47 7543 1331 -4044 -2245 -6891 -2085 15806 -2693 9890 233 882 5269 -10147 5147 3089 1146 -7782 -1743 -6502 -1087 8161 -5808 11564 13239 5629 -483 -4437 1243 -9570 8935 -7849 10271 1882 4947 933 -7785 5420 -4444 11323 832 -1478 6877 -7580 -3190 -5170 13807 -3270 -3943 -1875 -11205 12961 -7894 1197 -9512 2424 -2990 -511 16923 734 4153 -7804 7291 2610 -6897 4306 -8975 308 1698 16244 11555 11499 -7283 -6137 7666 -2964 2899 8890 -2685 5601 -2270 118 -7167 7900 -4385 11081 -2001 -11916 -3249 -5105 -315 -3807 15765 -893 9720 2371 -2311 10569 -13134 4899 -11377 10240 2623 7083 -1168 -126 3905 -4909 -3624 269 -1272 -2113 3676 863 -7515 12668 -7393 6525 725 4576 -5576 -10204 13703 -846 -2646 5841 -8587 -114 -1943 29939 31902 -872 -1099 -11548 8650 -9508 7792 -573 -769 -5492 -3518 -998 -5727 22922 -1177 25147 -9004 125 -5768 2762 6836 -5782 13469 -15327 12721 6834 1291 -4242 -2390 -7922 -2342 15157 -3153 10270 265 986 5554 -12311 5290 3207 1209 -8427 -1810 -7266 -1177 8151 -6692 11207 12634 5817 -532 -5090 1340 -11357 8615 -8693 9294 1851 4819 978 -9161 5655 -5098 10974 884 -1594 6801 -8696 -3533 -5906 13176 -3719 -4504 -2077 -13407 11920 -8705 1172 -10159 2289 -3030 -521 14895 773 4251 -8991 7210 2711 -7912 4429 -10517 325 1746 14217 10456 10292 -7779 -6433 7013 -3048 2853 8308 -2626 4959 -2136 107 -6977 6629 -4188 9143 -1901 -12649 -3193 -5135 -303 -3777 12862 -865 8561 2275 -2336 9309 -14369 4360 -11603 8212 2226 5680 -1024 -112 3476 -4961 -3696 264 -1256 -2077 3391 824 -7908 11040 -7950 6140 726 4434 -6023 -11589 12197 -859 -2687 5361 -9036 -111 -1927 21650 22626 -857 -1016 -11841 7659 -9375 6755 -533 -716 -5103 -3269 -923 -5647 18276 -1135 19934 -9507 121 -5939 2603 6115 -5752 10813 -16183 10156 SO 20190827T103331.0Z 7178.439942 396 1 32.01 2 88.05 76.35 68.43 38.70 0.00 1 0.00 1 0 15 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