File name: Pandora114s1_BuenosAires_20190925_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T072836.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20190925_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20190925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190925T094504.0Z 7207.406296 331 1 32.01 2 89.70 90.78 70.15 47.01 0.00 1 0.00 1 0 53 9.749e-02 9.258e-02 9.690e-02 9.444e-02 -6.958391e+03 5.423543e+03 1.527335e+02 -6.000000e+00 5.333473e+03 282.95 -2.00 20.00 -2.00 505.24 0.00e+00 4.394501e-03 2.593280e-03 2.605804e-04 -6.000000e+00 2.702641e-03 282.95 -2.00 20.00 -2.00 500.08 0.00e+00 3.827690e+00 1.928213e+00 1.071740e-01 -6.000000e+00 1.913110e+00 228.12 -2.00 3.16 -2.00 501.72 0.00e+00 20.027 0.075 489.00 513.00 1 9.6280e+00 1.4777e-01 3.2316e-02 -6.0000e+00 1.4651e-01 9.3297e-02 3.8693e-02 2.4290e-03 -6.0000e+00 3.8286e-02 5.2679e-06 -2.3667e-02 8.7787e-03 1.0162e-04 -6.0000e+00 9.5916e-03 9.0936e-02 -1.5954e-04 12 8 8 10 0 0 11.14 21.53 4.55 0.09094 -0.07323 8 2 1 4 0 4000.000 25.68 19.97 21.53 -13014 -13339 14931 -11457 5267 2413 5310 2292 -9439 6207 19503 7920 9545 -4759 -14287 11349 789 -4182 12340 -8136 4295 6062 -9015 13150 -2083 19472 -2069 5880 -13726 9695 -13041 -2056 -1603 -763 -11075 -3979 2138 4851 4054 10808 -10874 18659 3457 5594 -1826 -4845 -3319 6523 -7175 7175 14851 1217 -2155 2645 -4871 10331 -14378 9645 3947 7591 -8088 10038 5660 1834 22644 -2326 -4064 -5907 -847 -9236 6496 13915 -5935 61 -11949 -10878 6359 4573 9279 -5846 18117 16656 -9880 9673 6078 3874 -6813 2302 -7096 10134 2878 -9089 5405 71 4786 -59 12056 -8993 14084 8667 -15809 6947 -2531 18350 29793 -18658 -319 5076 7644 7149 7958 1490 -2674 6027 -548 8944 1874 2930 -6770 -9663 -4753 -1912 -13578 -8144 703 -7643 3402 3593 6008 -7732 3269 31009 -8619 21297 -131 198 -4032 2969 -2444 -18131 14209 9528 6581 -934 2852 -11291 17 1875 -6043 14072 -9320 15767 -6754 900000 -14801 -15083 12933 -13333 5363 2600 5688 2576 -12045 6771 18441 8274 9656 -5476 -16664 10881 784 -4413 11271 -9339 4426 6173 -10681 12497 -2314 17544 -2324 6096 -17196 9453 -15533 -2132 -1632 -777 -12850 -4444 2296 5090 4253 10472 -12952 16466 3563 5696 -2028 -5621 -3830 6843 -8590 7350 13840 1269 -2261 2579 -5050 9245 -16859 9166 4068 7636 -9534 9850 5798 1958 19704 -2599 -4590 -6708 -899 -10488 6214 12194 -6263 61 -12513 -11391 6043 4154 7945 -5716 14646 12720 -9831 7947 5205 3407 -6701 2078 -7061 8502 2597 -9255 4785 67 4375 -58 10602 -9833 12223 7873 -18019 6149 -2401 13908 20168 -20834 -303 4610 6723 6204 6722 1327 -2491 5230 -520 7917 1822 2865 -7364 -10846 -5060 -1958 -15397 -8622 675 -7959 3189 3388 5561 -7747 3121 22426 -8729 17004 -121 180 -3754 2697 -2196 -19253 11838 8490 5769 -890 2624 -11989 16 1766 -6186 11724 -9643 12363 -6473 900000 SO 20190925T094924.0Z 7207.409306 335 1 32.01 2 88.81 90.17 69.51 46.20 0.00 1 0.00 1 0 15 6.297e-02 6.130e-02 5.657e-02 5.570e-02 3.060049e+03 3.443686e+03 1.151764e+02 -6.000000e+00 3.443947e+03 282.95 -2.00 20.00 -2.00 505.21 0.00e+00 9.790724e-04 1.493789e-03 4.776365e-05 -6.000000e+00 1.744211e-03 282.95 -2.00 20.00 -2.00 500.08 0.00e+00 1.085994e+00 1.099271e+00 4.607470e-02 -6.000000e+00 1.230305e+00 228.12 -2.00 3.16 -2.00 501.71 0.00e+00 18.163 0.056 489.00 513.00 1 9.5822e+00 8.3716e-02 2.7499e-02 -6.0000e+00 9.4318e-02 1.1117e-01 2.1838e-02 1.6999e-03 -6.0000e+00 2.4469e-02 9.1212e-06 -3.5018e-03 5.2247e-03 1.5701e-05 -6.0000e+00 6.1826e-03 6.6972e-02 -5.8757e-04 12 8 8 10 0 0 -27.48 21.53 8.36 0.06697 0.04268 8 2 1 4 0 4000.000 25.68 19.98 21.53 518 75 -3931 -4211 627 -3429 7031 4614 453 -3837 -2471 3870 -12106 5840 7 7622 -2170 -4261 5169 -2786 -566 9753 2820 -1679 -10554 10371 -2698 7166 -2979 4624 -3468 -5787 3779 -1223 7711 -2979 9180 -2481 4740 -3491 -2498 7563 -5644 9931 -6420 7142 965 -6695 8835 -1565 3835 -205 9540 -1284 -4057 555 -8930 3799 -4735 5035 -5357 1999 3161 1213 6355 1036 1880 -4852 3735 1948 -8464 2475 -7865 -4147 -6986 11497 4087 -3989 -3501 -8035 18388 7033 -7232 10142 -4161 1741 6498 16162 -3295 2076 -3963 3067 -5810 12163 5623 -2450 -1001 -5035 8081 -588 -9603 7780 -2016 7822 -3438 2945 -30 -3403 -6194 -14783 8846 6598 -6654 -5911 9746 7390 -3671 7828 -5714 7833 1210 4104 8082 -1935 12845 -7128 8796 -2756 -2080 6037 -87 -990 1327 10116 4487 -10545 -1154 -3191 -9026 -6609 4151 -5074 6886 -167 -8203 4302 446 3488 -9366 7242 3554 6957 4451 -6293 517 75 -4216 -4369 639 -3732 7039 4804 495 -4357 -2735 3958 -14322 5697 7 7186 -2267 -4622 5231 -3124 -628 9799 3039 -1894 -13062 10457 -3103 7434 -3384 4764 -3763 -6278 3715 -1287 7663 -3394 9391 -2845 5004 -3952 -2773 7572 -6472 9833 -7571 7435 1075 -8043 9005 -1744 3964 -215 8821 -1294 -4180 553 -10078 3887 -5378 5224 -5777 1999 3129 1230 6138 1054 1880 -5116 3557 1861 -8867 2298 -8025 -4076 -7129 9888 3822 -4030 -3465 -8171 14182 6049 -7182 8515 -4061 1616 5810 13238 -3295 1969 -3990 2878 -5988 10584 5297 -2525 -1014 -5241 7225 -560 -9767 6505 -1830 6433 -3227 2684 -29 -3495 -6553 -16851 7849 5944 -6880 -6153 8814 6935 -3656 7427 -5873 7070 1170 3836 7164 -1865 10521 -7074 7459 -2638 -1984 5313 -81 -932 1219 8480 3935 -10567 -1038 -2911 -8784 -6390 3680 -5019 6126 -161 -8616 4007 434 3305 -10078 6536 3265 6034 3889 -6104 SO 20190925T095343.0Z 7207.412303 339 1 32.01 2 87.92 89.56 68.89 45.38 0.00 1 0.00 1 0 22 2.191e-02 2.187e-02 2.016e-02 2.005e-02 8.660307e+03 1.385751e+03 6.819530e+02 -6.000000e+00 1.198755e+03 282.95 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