File name: Pandora114s1_BuenosAires_20191103_L2Fit_fwvt1c14d20181227p1-8.txt File generation date: 20241126T100137.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v5d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20191103_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20191103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1803 Nominal wavelengths inside fitting window [nm]: 492.0322 492.1508 492.2693 492.3878 492.5062 492.6247 492.7431 492.8616 492.9800 493.0984 493.2167 493.3351 493.4534 493.5718 493.6901 493.8083 493.9266 494.0449 494.1631 494.2813 494.3995 494.5177 494.6359 494.7540 494.8721 494.9903 495.1083 495.2264 495.3445 495.4625 495.5806 495.6986 495.8166 495.9345 496.0525 496.1704 496.2883 496.4062 496.5241 496.6420 496.7598 496.8777 496.9955 497.1133 497.2311 497.3488 497.4666 497.5843 497.7020 497.8197 497.9374 498.0551 498.1727 498.2903 498.4079 498.5255 498.6431 498.7606 498.8782 498.9957 499.1132 499.2307 499.3481 499.4656 499.5830 499.7004 499.8178 499.9352 500.0526 500.1699 500.2872 500.4045 500.5218 500.6391 500.7563 500.8736 500.9908 501.1080 501.2252 501.3424 501.4595 501.5766 501.6937 501.8108 501.9279 502.0450 502.1620 502.2790 502.3961 502.5130 502.6300 502.7470 502.8639 502.9808 503.0977 503.2146 503.3315 503.4483 503.5652 503.6820 503.7988 503.9155 504.0323 504.1490 504.2658 504.3825 504.4992 504.6158 504.7325 504.8491 504.9657 505.0823 505.1989 505.3155 505.4320 505.5486 505.6651 505.7816 505.8980 506.0145 506.1309 506.2474 506.3638 506.4802 506.5965 506.7129 506.8292 506.9455 507.0618 507.1781 507.2944 507.4106 507.5268 507.6430 507.7592 507.8754 507.9916 508.1077 508.2238 508.3399 508.4560 508.5721 508.6881 508.8041 508.9202 509.0361 509.1521 509.2681 509.3840 509.4999 509.6159 509.7317 509.8476 509.9635 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-405: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191103T085629.0Z 7246.372558 311 1 32.02 2 89.72 108.13 124.09 183.67 0.00 1 0.00 1 0 36 8.033e-02 7.778e-02 7.609e-02 7.443e-02 2.169080e+03 4.606431e+03 2.478582e+02 -6.000000e+00 4.426552e+03 284.77 -2.00 20.00 -2.00 505.24 0.00e+00 4.154041e-03 2.025369e-03 2.404490e-04 -6.000000e+00 2.234077e-03 284.77 -2.00 20.00 -2.00 499.98 0.00e+00 4.097626e-01 1.483165e+00 6.369455e-02 -6.000000e+00 1.561127e+00 228.85 -2.00 3.16 -2.00 501.64 0.00e+00 20.002 0.075 489.00 513.00 1 9.6529e+00 1.1420e-01 3.1467e-02 -6.0000e+00 1.1987e-01 1.6415e-01 2.8879e-02 1.9927e-03 -6.0000e+00 3.0874e-02 6.5780e-06 2.5754e-02 6.9940e-03 8.7290e-05 -6.0000e+00 7.8720e-03 -2.8526e-02 3.9624e-04 12 8 8 10 0 0 95.11 21.32 4.17 -0.02853 0.15011 8 2 1 4 0 4000.000 25.47 20.00 21.32 1653 -10148 12673 -9458 5899 17226 -758 9735 -6842 16857 -4499 -11620 3760 -13375 6661 -4785 -3385 -9976 9931 -2112 -802 -2867 -7519 4892 10311 -8562 1932 -5379 -1162 3449 2847 -1955 -6798 416 -2479 5707 7478 3422 2668 9031 8723 1740 -80 -1510 8210 -6095 706 5614 5921 -1945 11390 -8816 7104 -1275 -5689 -2855 11251 11337 19108 6740 1845 3253 4456 -3000 439 2621 -12202 969 -2165 1895 2542 -4631 -1810 -6075 -5403 -9175 -2738 -12198 17704 -3555 21 -1464 -7041 -4942 2114 18890 17359 11115 -6939 -867 5162 -3235 -7051 15298 -1757 7040 8667 6344 -11163 -2038 -5170 -1091 4492 1377 8912 2038 8619 -4140 6984 -3364 -10617 21833 765 1353 -3981 5985 18917 -1434 10333 -3250 7934 -5126 -8199 -16680 4919 3501 14692 -3789 -14350 -1848 -14707 -2121 1745 1911 14525 5087 3218 385 -691 3201 -4248 8362 -580 7969 -13773 10010 -4762 7110 -10270 7519 -217 -7804 8716 338 1689 -12058 12351 -11780 6425 16967 -897 10299 -8416 16077 -5229 -14293 3919 -16451 6735 -5511 -3672 -11792 9709 -2333 -873 -3193 -8814 5092 10182 -10162 2039 -5966 -1198 3322 2756 -2026 -7639 448 -2773 5857 7457 3512 2739 8697 8486 1837 -87 -1689 8386 -7174 769 5735 5904 -2043 10195 -9477 6497 -1290 -6199 -3111 10836 10974 17102 6819 1966 3434 4660 -3371 472 2715 -14423 990 -2253 1871 2473 -4843 -1857 -6589 -5861 -10265 -2824 -12738 14467 -3356 19 -1362 -6967 -4823 1938 14730 13774 9377 -6993 -822 4637 -3201 -7364 12906 -1755 6357 7549 5525 -11301 -1840 -4739 -960 3810 1243 7681 1905 7507 -4041 6019 -3206 -10990 16627 733 1308 -4103 5622 15700 -1465 9377 -3349 7200 -5212 -8487 -18712 4463 3241 12194 -3784 -15901 -1803 -16297 -2060 1608 1726 11393 4361 2833 354 -656 2963 -4281 7474 -535 7195 -14601 8378 -4599 6012 -10094 6034 -186 -7201 6921 297 SO 20191103T090057.0Z 7246.375660 315 1 32.01 2 88.84 107.50 124.14 182.47 0.00 1 0.00 1 0 15 5.791e-02 5.548e-02 4.818e-02 4.729e-02 1.813502e+03 2.863202e+03 1.655672e+02 -6.000000e+00 3.189875e+03 284.77 -2.00 20.00 -2.00 505.16 0.00e+00 1.319630e-03 1.284588e-03 8.698472e-05 -6.000000e+00 1.611778e-03 284.77 -2.00 20.00 -2.00 499.87 0.00e+00 1.216428e+00 9.458958e-01 1.371785e-02 -6.000000e+00 1.132274e+00 228.85 -2.00 3.16 -2.00 501.52 0.00e+00 18.209 0.057 489.00 513.00 1 9.4227e+00 7.2489e-02 2.7373e-02 -6.0000e+00 8.6843e-02 1.3490e-01 1.8935e-02 1.5166e-03 -6.0000e+00 2.2542e-02 1.0546e-05 -1.8666e-03 4.5164e-03 3.6089e-05 -6.0000e+00 5.6817e-03 2.4215e-02 -3.9707e-04 12 9 8 11 8 0 -44.37 21.32 2.23 0.02421 0.01127 8 2 1 4 0 4000.000 25.47 19.99 21.32 720 -8315 8504 -2787 -2060 4832 -3914 301 898 10095 916 3650 11724 -5774 5368 -2165 8301 -3071 -376 -2551 -3999 -486 -3685 -2810 -6140 1997 4051 -31 1626 -3027 -375 -3079 6817 -7131 1374 670 8363 3491 -645 4294 -3195 2380 -1815 169 3271 -674 -2517 -492 -1676 -7192 2279 1978 -5832 1481 -5593 9178 6745 10588 -2674 -7082 2751 -5026 6736 -4009 7105 -2555 2203 -2104 -5727 12918 -7914 6467 -1073 -1788 3056 -6343 3135 -7459 8529 -1578 7750 -3658 -4479 15985 -5331 1865 3737 3925 -2924 749 5304 -5835 9010 -12005 -57 2130 -1150 11178 -5676 1234 1317 3589 -12089 5429 -484 -1666 11983 -4431 6619 1632 9062 1525 -13252 -2896 -5254 7472 621 -173 3231 477 4369 -4499 8181 -4220 8274 -6655 837 5707 -8682 5708 -3761 4068 1789 -2473 3991 -2677 3295 -11369 -1992 -4252 9095 5002 -3834 7447 -4192 16887 -7904 1930 8741 -1542 2649 -3380 3651 -4699 739 -9361 8279 -2929 -2215 4973 -4487 336 1002 10233 1005 3835 11196 -6478 5325 -2302 7978 -3360 -411 -2909 -4684 -551 -4316 -3265 -7400 2228 4432 -36 1794 -3424 -401 -3302 6594 -8066 1474 745 8736 3820 -727 4551 -3614 2537 -2025 186 3538 -767 -2932 -561 -1916 -8557 2416 2047 -6344 1465 -5894 8453 6546 10177 -2992 -7818 2750 -5417 6460 -4297 6835 -2702 2202 -2164 -6007 11079 -8254 5771 -1023 -1714 2816 -6506 2952 -7780 7463 -1500 6624 -3487 -4309 12597 -5236 1718 3410 3605 -2889 714 4825 -5934 7936 -13183 -56 2080 -1159 9845 -5805 1151 1198 3120 -12084 4546 -438 -1574 10208 -4532 6060 1550 7877 1418 -14360 -2870 -5419 6884 582 -165 2987 455 4015 -4490 7094 -4073 6949 -6443 753 4918 -8665 4934 -3569 3561 1600 -2299 3439 -2423 2767 -10974 -1760 -3907 7465 4351 -3690 6458 -4104 13447 -8104 1800 7604 -1472 2376 -3143 3107 -4331 SO 20191103T090517.0Z 7246.378669 319 1 32.01 2 87.99 106.89 124.17 181.31 0.00 1 0.00 1 0 15 3.403e-02 3.365e-02 3.445e-02 3.398e-02 2.845225e+03 2.127484e+03 2.399547e+02 -6.000000e+00 1.874933e+03 284.77 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