File name: Pandora114s1_BuenosAires_20191227_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T102026.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20191227_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20191227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20191227T110031.4Z 7300.458696 389 1 6.70 2 64.02 101.49 78.00 109.18 0.00 1 0.00 1 0 17 1.844e-02 7.927e-03 1.598e-02 5.606e-03 2.608793e-01 2.802681e-03 2.776583e-03 -6.000000e+00 1.041889e-02 229.81 -2.00 3.16 -2.00 317.17 0.00e+00 8.517203e-04 3.912354e-04 7.913493e-05 -6.000000e+00 4.673698e-04 287.52 -2.00 20.00 -2.00 316.33 0.00e+00 2.269 0.000 302.00 328.00 3 4.1346e+00 7.4079e-03 2.5587e-02 -6.0000e+00 2.5977e-02 3.5588e-02 8.3307e-03 1.2245e-02 -6.0000e+00 2.8182e-02 -7.8215e-03 4.9488e-03 5.8931e-03 -6.0000e+00 1.6804e-02 -6.9637e-03 2.4177e-03 1.7679e-03 -6.0000e+00 7.1581e-03 6.5552e-04 -1.5401e-04 1.5669e-04 1.7969e-05 -6.0000e+00 4.8065e-04 1.9031e-02 -1.3632e-04 12 9 1 12 1 1 999.00 22.62 0.45 0.01903 0.01787 2 5 1 5 0 2172.173 26.51 20.00 22.62 -6380 -3592 -6202 4075 -2866 3454 4539 -3307 5104 1148 596 -3821 812 -5542 -1681 -2618 45 3097 1250 2855 6119 444 102 -1306 3565 -1861 -1188 -2999 1780 1164 -505 4779 -2481 564 -4090 -515 -3401 -49 1325 -475 -850 -1949 -1394 123 455 -699 445 2151 -1308 233 278 339 241 750 861 1781 1133 666 410 522 1534 767 483 622 -774 -1464 -1071 414 2680 -18 950 -470 1304 -768 -984 -357 706 -354 -1817 -604 -1611 -638 -2266 -726 -1630 -685 120 544 613 903 813 861 90 -189 165 708 22 333 -58 -296 181 -508 -251 175 -114 -1857 -257 -633 67 820 379 297 -302 593 -683 -15 301 -265 741 -395 218 -380 556 -45 -535 967 -268 1105 77 -10 65 -479 24 371 606 -452 -97 736 206 80 -502 133 -813 -272 -818 -473 -823 483 -329 370 531 -477 737 175 90 -639 135 -1140 -377 -638 11 768 328 765 1600 122 29 -397 1093 -619 -383 -921 491 322 -152 1499 -905 201 -1417 -170 -1271 -19 620 -260 -469 -1134 -828 73 267 -415 256 1188 -732 129 163 214 161 523 618 1295 845 498 300 379 1132 569 392 539 -687 -1217 -809 319 2133 -15 896 -441 1210 -705 -913 -297 561 -265 -1407 -479 -1464 -637 -2314 -765 -1838 -771 143 673 764 1100 933 963 92 -195 162 755 24 412 -74 -387 240 -620 -300 207 -136 -2432 -347 -843 93 1194 558 456 -463 855 -972 -19 397 -358 987 -573 333 -557 837 -66 -755 1363 -362 1407 102 -15 93 -722 36 577 930 -745 -158 1222 350 137 -844 226 -1339 -439 SU 20191227T110734.6Z 7300.463595 392 1 11.15 2 62.60 100.63 76.67 108.32 0.00 1 0.00 1 0 17 1.521e-02 6.510e-03 9.512e-03 3.527e-03 2.486144e-01 1.763486e-03 2.660539e-03 -6.000000e+00 8.593011e-03 229.81 -2.00 3.16 -2.00 317.09 0.00e+00 2.190670e-04 2.413112e-04 1.236812e-04 -6.000000e+00 3.854798e-04 287.52 -2.00 20.00 -2.00 316.26 0.00e+00 2.161 0.000 302.00 328.00 3 4.0068e+00 4.6598e-03 2.4375e-02 -6.0000e+00 2.1425e-02 3.9264e-02 5.2434e-03 1.1617e-02 -6.0000e+00 2.3244e-02 -4.2952e-03 3.0988e-03 5.6132e-03 -6.0000e+00 1.3859e-02 -1.0294e-02 1.4986e-03 1.5473e-03 -6.0000e+00 5.9032e-03 8.4464e-04 2.8288e-04 9.9003e-05 1.6689e-05 -6.0000e+00 3.9644e-04 2.0140e-02 -1.1116e-04 12 9 1 12 9 1 98.30 22.64 0.44 0.02014 0.02227 5 5 1 5 0 1827.608 26.51 20.00 22.64 1637 -196 -1556 -7677 -5342 -4406 600 1984 -3474 -1356 -6496 274 -4327 186 -1153 973 1094 2266 2383 -1068 1802 -274 2282 1076 2357 -389 1219 -283 -380 2102 2251 3443 862 -2135 -2771 -2742 -582 -1318 614 121 -662 252 -1115 -465 -109 -24 -581 -651 -1425 -812 827 -112 1101 385 141 1419 -121 390 -1087 657 50 1506 1101 1223 358 -278 187 -404 1691 1152 275 755 87 1315 -562 761 -1016 -96 -267 -1360 -1184 -1384 -1747 -1807 -620 -974 247 540 219 526 286 34 -661 -317 -76 371 167 454 190 189 177 -943 -748 462 -219 -1021 -1089 -834 269 543 170 453 303 -54 21 81 451 139 -325 229 -114 1 -43 580 611 724 66 175 672 104 249 -193 -549 360 332 -404 -453 311 276 -158 86 -307 -224 -422 224 -29 -225 -1062 -652 -532 76 285 -572 -221 -1095 46 -863 37 -263 232 269 573 624 -300 495 -76 637 323 741 -129 387 -85 -107 574 657 1083 300 -766 -930 -909 -208 -567 286 65 -388 153 -701 -292 -68 -15 -356 -388 -836 -476 503 -74 760 259 98 994 -88 280 -775 456 36 1144 914 1082 321 -232 142 -296 1285 999 265 707 83 1286 -526 635 -772 -73 -207 -1098 -1080 -1302 -1773 -1922 -692 -1094 292 663 272 637 326 38 -674 -325 -80 393 197 552 251 256 229 -1130 -885 538 -276 -1303 -1456 -1161 362 773 258 714 474 -79 29 109 576 182 -451 320 -169 2 -63 817 879 992 86 234 852 143 366 -278 -810 537 519 -675 -748 523 473 -272 145 -500 -373 -692 SU 20191227T111329.3Z 7300.467700 395 1 22.59 2 61.40 99.91 75.55 107.61 0.00 1 0.00 1 0 17 1.094e-02 5.865e-03 4.783e-03 1.793e-03 2.383301e-01 8.929067e-04 2.548401e-03 -6.000000e+00 6.179730e-03 229.81 -2.00 3.16 -2.00 317.10 0.00e+00 3.511457e-04 1.232466e-04 8.661369e-05 -6.000000e+00 2.771965e-04 287.52 -2.00 20.00 -2.00 316.27 0.00e+00 2.079 0.000 302.00 328.00 3 3.5263e+00 2.3599e-03 2.3433e-02 -6.0000e+00 1.5408e-02 3.4109e-02 2.6575e-03 1.1151e-02 -6.0000e+00 1.6716e-02 -4.1012e-03 1.5694e-03 5.3914e-03 -6.0000e+00 9.9666e-03 -7.9273e-03 7.5922e-04 1.4982e-03 -6.0000e+00 4.2456e-03 1.5061e-03 2.3381e-04 5.0201e-05 1.6047e-05 -6.0000e+00 2.8507e-04 1.9975e-02 -9.3225e-05 12 1 1 12 1 1 99.74 22.66 0.36 0.01998 0.02173 21 10 1 5 0 1019.173 26.62 20.00 22.66 -1509 1331 -1981 -5656 -3134 -1621 948 -1702 560 -4098 -2419 -909 1218 -54 -654 -45 -138 -26 1792 1391 1350 1106 1360 506 993 134 614 605 392 1369 425 2665 318 -1036 -2367 -2100 -1029 -1231 -72 -1515 -546 -395 -945 -695 -424 -326 -1068 -678 -1376 378 146 929 1530 748 826 674 434 388 422 235 580 1288 1357 1515 174 120 -564 -800 1378 771 363 443 145 206 220 -149 -848 -830 -671 -1039 -1111 -1236 -2063 -1537 -843 -600 177 2 602 377 763 648 -444 -119 250 31 383 676 423 -364 -191 -766 -493 573 -404 -897 -699 -672 -427 407 370 481 279 232 -116 100 388 100 255 211 -298 9 282 -57 321 809 -237 410 715 47 4 -363 -485 -164 483 -191 -166 330 205 69 113 -291 -352 -333 -219 197 -297 -788 -384 -195 123 -258 90 -698 -397 -155 232 -12 -149 -11 -34 -7 470 380 371 302 380 151 313 44 194 178 119 408 136 826 109 -359 -772 -674 -360 -513 -36 -802 -310 -233 -574 -423 -257 -197 -635 -390 -777 230 85 582 1007 519 589 492 323 288 306 169 428 1014 1160 1272 149 103 -444 -604 1075 687 331 423 140 193 194 -129 -660 -601 -493 -852 -1031 -1175 -2124 -1648 -952 -675 211 3 750 461 874 731 -457 -115 244 33 452 819 558 -495 -248 -916 -586 669 -475 -1143 -932 -934 -618 577 558 751 432 340 -168 133 491 129 348 311 -436 13 408 -86 460 1100 -309 546 898 64 6 -553 -752 -241 740 -313 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