File name: Pandora114s1_BuenosAires_20200121_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T104251.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200121_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200121T174835.5Z 7325.742077 514 1 50.97 2 27.12 295.99 59.11 263.77 0.00 1 0.00 1 0 17 1.012e-02 7.203e-03 5.060e-03 2.976e-03 1.350496e-01 1.491864e-03 1.476401e-03 -6.000000e+00 5.721084e-03 229.90 -2.00 3.16 -2.00 315.73 0.00e+00 6.525356e-04 1.504540e-04 6.474144e-05 -6.000000e+00 2.575827e-04 288.58 -2.00 20.00 -2.00 314.96 0.00e+00 1.123 0.000 302.00 328.00 3 5.7946e+00 3.8715e-03 1.2826e-02 -6.0000e+00 1.4262e-02 4.7029e-02 4.3219e-03 6.3413e-03 -6.0000e+00 1.5467e-02 2.4226e-03 2.4685e-03 3.0554e-03 -6.0000e+00 9.2272e-03 -1.1891e-02 1.1141e-03 8.9764e-04 -6.0000e+00 3.9358e-03 4.7882e-04 4.3567e-04 8.2317e-05 9.9242e-06 -6.0000e+00 2.6370e-04 1.7576e-02 -6.1713e-05 11 8 0 10 0 0 99.43 23.06 0.83 0.01758 0.02085 16 3 1 5 0 3184.699 26.94 20.01 23.06 2362 1272 -713 -2925 117 -2049 3084 699 179 -1781 -724 120 49 296 0 -209 -440 -1887 2328 33 761 337 992 -4 570 1458 61 -900 474 442 1011 2233 473 -1793 -3265 -3139 -1426 -407 -96 -273 -629 -1297 -1526 -723 -570 -479 -587 -705 -448 -846 1432 -153 1007 432 56 379 1016 497 858 1087 899 1504 1778 1413 735 444 44 -1223 1599 947 654 766 1143 838 552 352 -914 -841 -1161 -867 -1005 -731 -2607 -1466 -1076 -1016 -138 -139 105 304 201 325 -297 -459 539 -532 223 706 360 -411 275 -855 -833 129 -670 -1075 -514 -614 -450 442 724 484 267 472 -124 49 156 94 194 321 92 -332 70 -67 578 1004 239 336 310 1 588 -274 -679 529 371 -51 -197 195 260 -132 371 -628 -582 -296 667 374 -206 -767 27 -463 721 189 52 -528 -203 34 15 104 0 -84 -179 -792 959 14 328 143 425 -2 267 689 28 -428 205 185 434 1002 228 -874 -1486 -1396 -682 -227 -58 -187 -463 -992 -1190 -559 -438 -364 -432 -497 -301 -617 1056 -111 751 336 45 303 819 400 675 848 722 1278 1619 1357 704 389 38 -1008 1332 895 620 761 1139 817 561 325 -758 -637 -878 -715 -928 -739 -2859 -1504 -1164 -1183 -170 -179 136 384 239 385 -317 -451 526 -565 258 808 446 -523 331 -1052 -955 147 -825 -1434 -649 -806 -609 622 1065 731 396 653 -173 62 189 116 252 450 125 -465 97 -98 803 1319 299 398 370 2 784 -380 -952 741 542 -79 -293 296 402 -207 567 -1036 -927 -464 SS 20200121T211202.1Z 7325.883357 612 1 4.15 2 68.21 260.26 96.99 237.69 0.00 1 0.00 1 0 17 4.983e-02 1.178e-02 5.141e-02 1.101e-02 3.049622e-01 5.500944e-03 3.255864e-03 -6.000000e+00 2.817044e-02 229.90 -2.00 3.16 -2.00 318.06 0.00e+00 -4.747408e-04 9.903101e-04 1.818838e-04 -6.000000e+00 1.268613e-03 288.59 -2.00 20.00 -2.00 317.20 0.00e+00 2.670 0.000 302.00 328.00 3 4.1670e+00 1.4866e-02 3.0150e-02 -6.0000e+00 7.0227e-02 2.7272e-03 1.6892e-02 1.4452e-02 -6.0000e+00 7.6160e-02 1.6365e-02 1.0682e-02 6.9454e-03 -6.0000e+00 4.5437e-02 -1.0806e-02 5.4765e-03 1.9543e-03 -6.0000e+00 1.9378e-02 4.0556e-04 2.1773e-04 3.1085e-04 2.0288e-05 -6.0000e+00 1.2988e-03 1.8128e-02 -9.1535e-05 12 9 9 12 1 1 999.00 23.02 0.61 0.01813 0.01976 1 5 1 5 0 1984.038 26.83 20.00 23.02 -1533 -3958 -837 -4629 -10831 9071 -16225 -5704 33523 14338 -7261 -10567 12394 -7638 8012 -6150 4089 -2961 10107 7388 -6405 5961 -11271 8904 5485 -3920 -1523 -2990 9971 -6888 4250 4206 -1517 3100 -6681 -812 -8621 2796 -3340 2028 1529 -3542 1315 1543 433 -5448 365 -80 -339 -1296 -1918 310 308 1456 -2097 3065 238 -2035 1189 -2726 4082 714 1628 1654 286 -252 554 2142 2401 1609 2510 -88 732 2393 977 -1874 317 -3167 -1832 -638 -1464 -575 -2282 -323 -2760 296 -297 -95 609 -738 590 -26 1530 -1616 -1202 1235 201 896 396 -562 -130 204 -1350 554 21 -569 -1574 -358 847 991 576 -606 -872 687 320 -213 747 -21 -1415 196 -24 -209 382 -409 -201 775 1239 2080 -279 32 367 -570 243 535 603 -862 -468 759 264 436 -343 -973 -329 -246 -109 -306 -62 -323 -733 507 -1307 -478 2089 1109 -694 -1124 1212 -1067 1093 -955 659 -489 1683 1318 -1207 1089 -2312 1770 1098 -892 -332 -619 1885 -1547 927 924 -385 760 -1690 -192 -2442 847 -1305 871 661 -1690 614 725 206 -2751 171 -37 -156 -609 -965 165 176 866 -1338 1913 156 -1367 757 -1784 2562 499 1139 1247 222 -184 400 1477 1756 1248 2137 -81 672 2094 814 -1451 234 -2269 -1330 -475 -1252 -544 -2205 -322 -2991 334 -336 -112 718 -863 687 -28 1473 -1633 -1160 1280 235 1082 525 -773 -170 244 -1616 643 26 -721 -2111 -496 1214 1421 889 -933 -1424 1052 455 -300 1000 -28 -2083 287 -38 -325 578 -604 -302 1104 1668 2656 -374 46 538 -885 383 860 1018 -1478 -837 1377 489 811 -626 -1715 -552 -405 SS 20200121T214239.0Z 7325.904618 621 1 49.96 2 74.38 256.36 101.95 232.96 0.00 1 0.00 1 0 25 8.220e-02 6.100e-03 2.463e-02 1.770e-03 4.089748e-01 8.984182e-04 4.368017e-03 -6.000000e+00 4.646270e-02 229.90 -2.00 3.16 -2.00 319.87 0.00e+00 1.899306e-03 2.756871e-04 8.775256e-04 -6.000000e+00 2.092878e-03 288.59 -2.00 20.00 -2.00 319.07 0.00e+00 3.647 0.000 302.00 328.00 3 2.0252e+00 2.6382e-03 4.1161e-02 -6.0000e+00 1.1583e-01 1.6029e-02 3.1631e-03 1.9835e-02 -6.0000e+00 1.2562e-01 -1.3784e-02 2.4902e-03 9.9384e-03 -6.0000e+00 7.4946e-02 -4.8347e-03 1.2901e-03 3.0337e-03 -6.0000e+00 3.1956e-02 1.1799e-03 -2.2374e-04 5.1131e-05 3.6426e-05 -6.0000e+00 2.1426e-03 1.8319e-02 -1.4557e-04 10 0 0 10 0 0 94.31 23.00 0.51 0.01832 0.01664 108 21 1 5 0 462.473 26.83 20.00 23.00 -13505 -17535 -26667 -17247 -50656 -10123 -39240 -19704 -27967 -27016 -742 -27982 -301 -10247 426 -14424 3729 -2654 -6918 3700 -7548 2046 -9367 4260 -2220 -6248 251 -6093 -2547 -8615 -1918 -2807 -578 -2874 -1328 -182 -4444 1233 -2397 594 -969 1291 1133 -1130 2591 -1840 -205 160 93 939 1269 2055 -134 2140 367 1637 880 281 998 -1307 2160 1424 2740 2716 808 1370 -63 691 200 1529 564 688 1025 -130 656 -1074 -744 -2208 -768 -1079 -802 -481 -2233 -1290 -1268 -398 -295 120 346 11 1108 50 -264 -642 272 -229 -12 673 -533 -287 -398 -914 -653 -14 -316 -1463 -759 -1027 -76 313 635 495 528 584 -167 356 284 275 157 -164 -175 -312 167 -100 634 627 -19 783 772 171 -56 -175 -362 126 305 -151 -240 90 152 -308 41 -155 -412 85 -261 -384 -644 -348 -1311 -176 -1023 -486 -825 -816 -18 -971 -10 -437 19 -846 196 -159 -457 231 -534 131 -703 301 -180 -547 20 -502 -196 -732 -172 -290 -65 -338 -145 -20 -553 174 -428 120 -219 303 276 -287 639 -480 -52 41 24 248 361 637 -46 761 139 631 351 113 388 -515 846 611 1289 1399 438 703 -31 329 103 891 368 430 705 -87 408 -613 -383 -1102 -396 -638 -546 -367 -1723 -1042 -1088 -364 -287 122 352 11 1033 43 -232 -544 240 -207 -12 766 -678 -376 -500 -1056 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