File name: Pandora114s1_BuenosAires_20200207_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T104348.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200207_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200207T101332.0Z 7342.426065 282 1 50.05 2 80.25 102.06 125.42 275.66 0.00 1 0.00 1 0 17 3.054e-01 8.486e-03 2.775e-01 6.226e-03 5.733399e-01 3.299654e-03 5.980273e-03 -6.000000e+00 1.739652e-01 229.70 -2.00 3.16 -2.00 321.33 0.00e+00 2.637026e-03 1.665162e-03 2.183763e-03 -6.000000e+00 7.789483e-03 288.81 -2.00 20.00 -2.00 320.67 0.00e+00 5.633 0.002 302.00 328.00 3 1.7251e+00 1.1831e-02 6.2876e-02 -6.0000e+00 4.3379e-01 7.3751e-02 1.6157e-02 3.0439e-02 -6.0000e+00 4.7065e-01 -1.2916e-01 1.5325e-02 1.5989e-02 -6.0000e+00 2.7966e-01 4.5015e-02 7.2599e-03 4.9176e-03 -6.0000e+00 1.1893e-01 2.0653e-04 1.2658e-04 1.8096e-04 7.1407e-05 -6.0000e+00 8.1013e-03 1.2391e-02 -9.9950e-05 11 8 0 10 0 0 -6.78 23.03 0.74 0.01239 0.01334 58 11 1 5 0 862.813 26.94 20.00 23.03 -114334 -125653 -80057 8257 -78420 -76819 900000 -18944 -89574 -135665 -61691 -97596 7979 132886 -29981 -64699 -44425 -48010 6853 -31036 2799 17848 -23809 4514 -55285 -16167 -35977 -30076 18847 -37950 -14136 -10506 -3246 -11541 -19017 -18149 -28436 14338 -315 -8133 12124 -5631 2881 1454 -1950 -6060 2649 -564 11227 8395 10718 1324 425 3051 -3623 7348 1386 6036 -569 353 1928 1615 3940 2534 870 2659 4363 1646 367 1384 3931 3201 2692 978 163 1391 -3561 -1901 -2324 -661 -1047 -2173 -1572 -2272 -1013 -84 667 2084 1431 453 1456 -146 1312 -953 -789 -556 -45 -474 138 -835 -827 -165 -1285 -123 -1654 -1813 -1371 -1572 -329 277 884 1071 -60 98 -508 -357 246 -240 510 -66 -284 394 582 -161 753 764 -14 505 1005 -95 -230 307 -572 226 245 -158 203 98 145 -368 400 53 -663 -296 -1010 -1387 -574 50 -476 -466 900000 -115 -890 -2247 -511 -1347 48 807 -414 -1464 -907 -1113 98 -685 45 246 -526 82 -1984 -410 -1112 -847 355 -1360 -472 -402 -132 -533 -901 -849 -1640 653 -20 -677 920 -547 269 141 -199 -659 269 -61 1111 907 1249 190 67 509 -684 1298 268 1118 -110 66 368 338 914 669 248 727 1126 441 109 470 1454 1261 1071 380 59 448 -1103 -567 -751 -246 -460 -1107 -882 -1370 -642 -57 475 1529 1068 334 1007 -95 791 -578 -515 -414 -38 -465 151 -964 -922 -167 -1184 -108 -1566 -1858 -1474 -1792 -396 368 1295 1698 -99 158 -783 -518 345 -346 773 -108 -479 655 930 -250 1127 1103 -19 680 1425 -154 -417 598 -1180 485 561 -353 475 236 353 -901 939 129 -1544 -671 SS 20200207T102149.1Z 7342.431818 286 1 50.13 2 78.58 100.94 127.04 274.63 0.00 1 0.00 1 0 17 2.343e-01 8.848e-03 1.741e-01 5.009e-03 5.063328e-01 2.585942e-03 5.213681e-03 -6.000000e+00 1.324170e-01 229.70 -2.00 3.16 -2.00 320.89 0.00e+00 1.635073e-03 1.128652e-03 6.438231e-04 -6.000000e+00 5.971250e-03 288.81 -2.00 20.00 -2.00 320.19 0.00e+00 4.878 0.001 302.00 328.00 3 2.2295e+00 8.5825e-03 5.4055e-02 -6.0000e+00 3.2993e-01 3.3983e-02 1.1188e-02 2.4582e-02 -6.0000e+00 3.5780e-01 -9.2180e-02 1.0055e-02 1.2425e-02 -6.0000e+00 2.1352e-01 3.3764e-02 4.9163e-03 3.9044e-03 -6.0000e+00 9.1166e-02 2.7449e-04 -3.6759e-04 1.4550e-04 4.5396e-05 -6.0000e+00 6.1066e-03 1.3631e-02 -1.5667e-04 11 8 0 10 0 0 98.83 23.03 0.62 0.01363 0.01087 58 11 1 5 0 864.094 26.83 20.00 23.03 -109346 -67952 33076 -102805 -23489 -131999 -10588 -101291 -9196 -39853 -59538 1685 -83843 8771 -15347 4591 -18405 14533 4821 -11783 21166 -32627 2761 -18803 -3532 -5360 -24517 -13671 -33899 -6764 -3604 10825 -2085 -11538 4991 -17410 10490 -10024 14123 -1938 776 1008 -2729 5764 -2705 9692 -724 2124 -807 564 592 -1464 7609 4168 5808 1455 1775 3734 -2874 3324 -2442 4459 964 1828 2772 2891 2537 -1555 2133 958 2305 24 594 1361 -250 781 -1590 -651 -2288 -622 441 -2546 -1835 -3441 -550 -850 884 0 -75 1910 839 370 1121 186 236 -612 1224 360 651 -1440 40 -1157 -556 -28 -1634 -577 -2275 -837 -941 805 264 -49 768 208 208 -521 267 -69 -262 -36 -310 398 -23 640 359 815 -16 295 1198 45 365 -18 -474 -19 742 484 -254 56 -369 -127 -178 84 76 -544 -1797 -815 162 -1644 -156 -2638 -71 -1935 -78 -478 -899 16 -2272 117 -314 88 -482 297 116 -351 461 -1217 84 -772 -135 -217 -1198 -574 -1706 -274 -164 497 -123 -778 271 -1174 595 -842 1145 -218 94 131 -383 758 -391 1260 -105 305 -122 88 102 -285 1472 898 1297 353 443 916 -736 788 -630 1170 294 615 971 979 819 -523 749 393 1040 12 290 635 -110 308 -583 -229 -871 -270 221 -1498 -1181 -2396 -396 -659 718 0 -65 1590 668 274 767 125 168 -499 1122 379 761 -1793 47 -1266 -548 -27 -1679 -634 -2677 -1024 -1229 1132 411 -75 1189 347 327 -775 382 -100 -407 -60 -536 681 -38 1024 557 1211 -22 407 1719 73 655 -35 -962 -36 1492 1045 -580 130 -880 -302 -412 184 156 -1221 SS 20200207T102902.1Z 7342.436829 289 1 26.11 2 77.12 99.98 128.44 273.72 0.00 1 0.00 1 0 17 1.317e-01 6.965e-03 9.675e-02 4.420e-03 4.592410e-01 2.268606e-03 4.784267e-03 -6.000000e+00 7.440615e-02 229.70 -2.00 3.16 -2.00 320.38 0.00e+00 1.366104e-03 8.259679e-04 7.339367e-04 -6.000000e+00 3.356807e-03 288.81 -2.00 20.00 -2.00 319.62 0.00e+00 4.365 0.001 302.00 328.00 3 2.4053e+00 7.0084e-03 4.8515e-02 -6.0000e+00 1.8538e-01 5.9400e-03 8.7292e-03 2.2251e-02 -6.0000e+00 2.0107e-01 -2.8978e-02 7.4612e-03 1.1089e-02 -6.0000e+00 1.1999e-01 5.0488e-03 3.7706e-03 3.2883e-03 -6.0000e+00 5.1215e-02 3.9157e-04 -5.0237e-04 1.2838e-04 3.9164e-05 -6.0000e+00 3.4331e-03 1.4110e-02 -2.4871e-04 12 9 1 12 1 1 99.99 23.03 0.65 0.01411 0.01033 29 11 1 5 0 863.456 26.83 20.00 23.03 -28896 12743 -55259 -26177 -50128 -54187 -42341 -38086 -45939 -37482 -27854 -50548 -18314 -23630 16376 3566 -14077 -2047 -10525 24895 -10317 7814 -18642 -5934 -2242 -12676 -2516 -15080 3376 -1026 -1680 -698 -7177 585 -4310 -391 -7781 193 -1222 -3734 3849 -3013 -828 -86 7067 3836 -4713 2051 629 3363 -3070 3167 3307 135 3534 722 55 -3422 2868 1279 3876 2134 616 2540 503 3037 -1906 -943 1360 266 1688 -378 1056 151 607 -116 -1390 945 -1800 -1057 -1971 -486 -1464 -1687 -844 -86 759 -4 1188 265 684 572 -881 483 -119 -101 -615 604 105 169 -226 -1431 -343 -861 -202 -1041 -960 -996 -177 -90 -73 616 256 383 -102 -113 -171 81 643 -149 142 -358 270 852 -82 1055 -563 569 583 480 328 -365 -326 -693 70 -114 220 246 437 -186 289 -131 -718 -269 -328 115 -1000 -327 -735 -841 -657 -657 -951 -743 -516 -1329 -426 -713 395 111 -564 -79 -467 816 -489 310 -1013 -310 -122 -798 -142 -923 167 -56 -105 -50 -616 48 -351 -30 -728 20 -159 -584 619 -552 -155 -16 1255 714 -961 394 125 677 -717 769 869 39 1044 228 18 -1161 894 400 1215 740 243 1084 228 1291 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