File name: Pandora114s1_BuenosAires_20200217_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T104355.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200217_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200217T120226.4Z 7352.501695 151 1 12.84 2 59.73 83.80 17.43 318.27 0.00 1 0.00 1 0 17 1.057e-02 5.971e-03 6.911e-03 2.930e-03 2.213469e-01 1.470672e-03 2.378676e-03 -6.000000e+00 5.970459e-03 229.45 -2.00 3.16 -2.00 316.75 0.00e+00 7.342822e-04 1.858555e-04 6.004728e-05 -6.000000e+00 2.693338e-04 288.84 -2.00 20.00 -2.00 315.91 0.00e+00 1.976 0.000 302.00 328.00 3 4.0463e+00 3.8620e-03 2.2170e-02 -6.0000e+00 1.4867e-02 2.4701e-02 4.3319e-03 1.0366e-02 -6.0000e+00 1.6123e-02 -4.2148e-04 2.5293e-03 5.0051e-03 -6.0000e+00 9.6236e-03 -1.0556e-02 1.2064e-03 1.4671e-03 -6.0000e+00 4.1134e-03 1.0189e-03 3.0844e-04 8.2146e-05 1.5150e-05 -6.0000e+00 2.7531e-04 1.1486e-02 -7.3001e-05 12 1 1 12 1 1 99.86 22.65 0.32 0.01149 0.01380 8 7 1 5 0 1406.640 26.51 20.01 22.65 644 1925 -2312 -1914 -2882 -4414 -1201 3073 -292 -3789 -1918 -128 173 -576 1227 1238 1413 652 -291 1249 176 1902 930 711 1396 -180 936 -1508 511 -230 636 1316 1323 -1414 -2354 -1853 -2501 -400 -179 -997 -663 -960 -495 -663 402 -1117 -489 -881 -610 122 341 731 1323 539 -84 891 593 680 276 -158 1386 356 1190 1301 -171 -435 -449 -219 1019 1121 684 464 -293 925 827 159 202 -1398 -863 -260 -1126 -1051 -2436 -1187 -788 -727 -38 154 545 57 964 215 -380 -170 -110 386 82 513 240 -193 318 -880 -663 -91 -262 -793 -960 -605 -455 443 762 563 97 158 206 264 -93 105 550 365 -337 -512 234 77 234 630 -39 566 560 131 -10 -39 -356 -122 129 -239 -252 571 103 -207 -63 -379 -304 73 108 337 -414 -307 -418 -641 -185 516 -55 -750 -363 -25 38 -133 313 337 395 190 -89 388 56 584 295 238 491 -66 332 -511 159 -71 205 457 494 -546 -852 -653 -971 -180 -88 -572 -411 -622 -327 -442 265 -744 -317 -555 -373 74 216 493 938 403 -60 642 436 498 216 -123 1089 279 1005 1170 -158 -372 -348 -174 840 964 654 468 -279 912 770 135 166 -1079 -667 -221 -1007 -1041 -2443 -1230 -862 -855 -44 187 666 69 1161 239 -412 -171 -112 395 93 643 306 -253 399 -1098 -762 -103 -318 -977 -1243 -814 -636 649 1108 851 146 225 287 338 -122 139 717 514 -508 -737 351 112 325 831 -52 722 725 183 -14 -57 -527 -183 202 -374 -415 957 178 -359 -108 -623 -481 113 SS 20200217T121019.0Z 7352.507165 154 1 50.10 2 58.12 82.56 18.52 313.65 0.00 1 0.00 1 0 17 8.405e-03 5.404e-03 1.238e-03 5.164e-04 2.117477e-01 2.585812e-04 2.298558e-03 -6.000000e+00 4.747509e-03 229.45 -2.00 3.16 -2.00 316.79 0.00e+00 2.733988e-04 3.307119e-05 7.506921e-05 -6.000000e+00 2.141939e-04 288.84 -2.00 20.00 -2.00 315.94 0.00e+00 1.887 0.000 302.00 328.00 3 2.0208e+00 6.7859e-04 2.1203e-02 -6.0000e+00 1.1822e-02 1.6051e-02 7.6007e-04 9.9538e-03 -6.0000e+00 1.2821e-02 -1.0139e-03 4.4484e-04 4.8133e-03 -6.0000e+00 7.6526e-03 -8.7556e-03 2.1371e-04 1.3337e-03 -6.0000e+00 3.2706e-03 8.6143e-03 2.2339e-04 1.4551e-05 1.5122e-05 -6.0000e+00 2.1896e-04 1.1810e-02 -9.6217e-05 10 0 0 10 0 0 99.59 22.67 0.47 0.01181 0.01349 261 51 1 5 0 191.902 26.51 20.00 22.67 211 -646 -2071 -2531 -2828 -1522 -544 1398 4 -1450 -1792 -556 -136 301 965 -460 559 342 818 1084 98 1268 696 988 1021 441 -192 -469 -308 344 1063 1370 1214 -1532 -2433 -1884 -2299 -148 -76 -554 -848 -636 -579 -1000 -43 -489 -514 -750 -959 90 431 549 927 919 316 926 561 238 265 100 862 999 1584 1447 379 76 -470 -487 1065 1000 390 490 166 322 215 -121 -351 -943 -359 -773 -1070 -1175 -2111 -1422 -918 -623 67 194 397 251 536 425 -226 90 434 51 174 684 92 -198 -135 -614 -632 218 -307 -993 -502 -718 -336 275 496 455 345 376 -93 150 261 119 213 133 -300 -277 82 -13 384 650 -53 511 631 109 190 -90 -377 -153 212 -8 -137 255 184 -181 73 -121 -559 -237 35 -112 -356 -393 -395 -207 -80 231 1 -271 -327 -105 -29 72 257 -132 163 103 254 347 32 403 228 341 338 151 -71 -162 -99 107 347 482 459 -598 -888 -670 -899 -61 -37 -317 -527 -411 -382 -666 -28 -322 -330 -468 -581 54 269 366 650 673 239 711 403 171 203 77 670 759 1297 1263 336 63 -385 -379 853 832 361 477 163 308 195 -100 -282 -704 -268 -640 -919 -1119 -2180 -1526 -1038 -698 80 241 496 308 620 486 -235 87 422 54 203 810 119 -264 -173 -723 -746 253 -384 -1247 -658 -984 -477 409 726 691 519 575 -131 193 322 148 282 189 -456 -429 124 -19 540 867 -67 667 833 143 266 -131 -561 -231 334 -12 -224 427 314 -312 122 -198 -883 -367 SS 20200217T121615.3Z 7352.511288 157 1 50.54 2 56.91 81.61 19.40 310.48 0.00 1 0.00 1 0 17 4.411e-02 1.715e-02 5.570e-02 1.756e-02 2.219911e-01 8.792284e-03 2.527097e-03 -6.000000e+00 2.492906e-02 229.45 -2.00 3.16 -2.00 317.60 0.00e+00 -3.546937e-04 1.346590e-03 6.197353e-04 -6.000000e+00 1.124010e-03 288.84 -2.00 20.00 -2.00 316.69 0.00e+00 1.826 0.000 302.00 328.00 3 6.8357e+00 2.3470e-02 2.1070e-02 -6.0000e+00 6.2079e-02 9.1310e-02 2.6507e-02 1.1085e-02 -6.0000e+00 6.7313e-02 -9.8259e-03 1.5887e-02 5.0691e-03 -6.0000e+00 4.0177e-02 -7.9869e-03 7.8240e-03 1.6521e-03 -6.0000e+00 1.7180e-02 7.0513e-05 3.2766e-04 5.1145e-04 1.9479e-05 -6.0000e+00 1.1488e-03 1.0269e-02 4.4688e-06 12 9 8 11 8 0 99.91 22.70 3.18 0.01027 0.01273 26 5 1 5 0 1943.509 26.62 20.00 22.70 -678 8937 -4503 3733 7952 4711 -2544 3472 4499 4825 -20021 2655 -6583 9052 21154 157 16852 -9915 -7876 6139 -3111 215 -6181 -3093 15707 -3741 3504 4499 1250 -4303 -1662 -6838 2838 -1115 -7610 -178 -5896 4358 387 2828 -4637 -1436 2862 -8773 414 2629 357 -465 -4114 3019 -1206 -929 2456 2860 -480 563 2137 1839 -1025 -16 2774 2899 4889 3920 1624 -2612 1118 -1430 2454 -2345 1024 -783 2984 1140 -2209 -152 3122 -1795 -1141 507 87 -2286 -617 -1445 -2312 -1390 3336 -629 -177 641 -988 -1288 462 -636 -3675 -1002 -1041 -239 -1524 -1145 545 -363 -361 -2378 -571 -2225 -128 485 -790 2763 1968 749 1384 382 891 1600 1231 1317 193 369 -572 -700 449 -55 -2472 976 -1476 -28 1087 2041 -798 135 -393 -793 2193 -1402 -1575 -23 16 374 -17 1487 -937 -58 -84 1059 -598 410 749 450 -287 421 591 640 -3314 364 -1108 1485 3441 34 3126 -2476 -1989 1393 -781 52 -1614 -830 3698 -1100 935 1104 294 -1044 -450 -1932 853 -351 -2370 -50 -1918 1513 168 1383 -2429 -758 1613 -5572 239 1473 200 -254 -2255 1532 -667 -548 1479 1794 -320 378 1440 1240 -696 -10 1827 2031 3638 3137 1340 -2086 778 -968 1665 -1888 881 -723 2676 1013 -1915 -117 2071 -1151 -729 351 68 -2032 -580 -1433 -2444 -1564 3817 -782 -221 779 -1150 -1373 436 -562 -3387 -973 -1118 -281 -1977 -1518 680 -420 -385 -2554 -644 -2753 -162 638 -1093 3893 2963 1185 2154 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