File name: Pandora114s1_BuenosAires_20200219_L2Fit_fout2c14d20181227p1-8.txt File generation date: 20241126T105502.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Marcelo Raponi Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 114 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora114_of_v6d20170314.txt Instrument calibration file used: Pandora114s1_CF_v14d20181227.txt Level 1 file used: Pandora114s1_BuenosAires_20200219_L1_smca1c14d20181227p1-8.txt Full location name: CITEDEF Buenos Aires Short location name: BuenosAires Country of location: Argentina Location latitude [deg]: -34.5554 Location longitude [deg]: -58.5062 Location altitude [m]: 20 Local noon date: 20200219 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 209 352 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2480 305.3875 305.5270 305.6664 305.8059 305.9454 306.0848 306.2242 306.3636 306.5031 306.6425 306.7818 306.9212 307.0606 307.1999 307.3393 307.4786 307.6179 307.7572 307.8965 308.0358 308.1751 308.3143 308.4536 308.5928 308.7320 308.8712 309.0104 309.1496 309.2888 309.4280 309.5671 309.7063 309.8454 309.9845 310.1236 310.2627 310.4018 310.5409 310.6799 310.8190 310.9580 311.0971 311.2361 311.3751 311.5141 311.6530 311.7920 311.9310 312.0699 312.2089 312.3478 312.4867 312.6256 312.7645 312.9033 313.0422 313.1811 313.3199 313.4587 313.5975 313.7363 313.8751 314.0139 314.1527 314.2914 314.4302 314.5689 314.7076 314.8464 314.9851 315.1237 315.2624 315.4011 315.5397 315.6784 315.8170 315.9556 316.0942 316.2328 316.3714 316.5100 316.6485 316.7871 316.9256 317.0641 317.2026 317.3411 317.4796 317.6181 317.7565 317.8950 318.0334 318.1719 318.3103 318.4487 318.5871 318.7254 318.8638 319.0022 319.1405 319.2788 319.4172 319.5555 319.6938 319.8320 319.9703 320.1086 320.2468 320.3850 320.5233 320.6615 320.7997 320.9379 321.0760 321.2142 321.3524 321.4905 321.6286 321.7667 321.9048 322.0429 322.1810 322.3191 322.4571 322.5952 322.7332 322.8712 323.0092 323.1472 323.2852 323.4232 323.5611 323.6991 323.8370 323.9749 324.1128 324.2507 324.3886 324.5265 324.6643 324.8022 324.9400 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-240: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 241-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200219T102823.6Z 7354.436384 287 1 21.15 2 79.40 96.60 34.10 80.29 0.00 1 0.00 1 0 17 3.580e-01 1.527e-02 3.312e-01 1.163e-02 5.337182e-01 6.134839e-03 5.716547e-03 -6.000000e+00 2.021259e-01 229.35 -2.00 3.16 -2.00 320.95 0.00e+00 2.235525e-03 2.727876e-03 2.653304e-03 -6.000000e+00 9.287376e-03 288.79 -2.00 20.00 -2.00 320.24 0.00e+00 5.221 0.001 302.00 328.00 3 2.8558e+00 2.0649e-02 5.8967e-02 -6.0000e+00 5.0310e-01 8.0976e-02 2.6588e-02 3.0315e-02 -6.0000e+00 5.4624e-01 -1.1413e-01 2.3854e-02 1.3983e-02 -6.0000e+00 3.2623e-01 4.4531e-02 1.1718e-02 3.5923e-03 -6.0000e+00 1.3928e-01 1.0025e-04 -6.4218e-04 3.4242e-04 5.5785e-05 -6.0000e+00 9.4790e-03 2.1703e-02 -2.3850e-04 12 9 9 12 9 1 35.91 21.85 0.78 0.02170 0.01688 6 3 1 5 0 2995.230 25.90 20.01 21.85 44299 -149729 -14134 900000 -99383 -68591 -195423 -17437 117644 -79659 -24409 -84444 -31643 -78560 900000 126032 39438 -54078 -53160 75612 -23466 52951 -49173 53753 5334 48149 93333 60514 27386 -32571 22567 -15908 -13056 -20362 14015 14049 1477 -1643 35538 -792 16265 -2591 15005 9146 -6882 21131 1914 20302 13739 3428 -16781 19091 13990 6491 671 8243 -462 -2391 -2145 -4043 10736 -2239 6543 3503 -1066 2515 -5671 5384 3315 8351 7746 -2466 4504 -2191 -2695 -3019 1511 -157 -1158 -460 1446 454 -5114 -1968 1562 97 -1020 -2020 2640 -811 918 -1656 -1572 995 -2451 -836 480 318 534 -109 -1571 -1647 -547 -545 -918 -2657 -1248 270 322 422 736 716 -187 998 293 616 982 -746 -73 -358 -718 928 68 546 1536 819 -2 1243 -1178 1107 -156 556 -706 -109 238 34 -762 -168 0 286 585 58 -906 -226 502 -3549 -160 900000 -1229 -778 -7250 -198 1334 -1231 -277 -1654 -457 -2267 900000 1429 581 -2006 -2082 943 -798 840 -2286 975 169 1037 1270 1098 683 -1588 742 -902 -814 -1408 651 653 87 -121 2216 -84 1604 -329 1667 1099 -983 2324 258 2325 1729 505 -3329 2943 2474 1332 154 1822 -115 -604 -528 -999 2361 -614 1855 1140 -381 838 -1961 1678 1154 3191 3310 -1230 2099 -1046 -1198 -1212 529 -55 -439 -202 728 263 -3450 -1367 1116 75 -853 -1779 2239 -696 731 -1254 -1110 672 -1842 -703 458 314 587 -125 -1760 -1680 -550 -534 -961 -3051 -1487 304 387 559 1073 1124 -303 1554 433 855 1317 -1044 -108 -565 -1177 1482 106 817 2202 1138 -2 1756 -1639 1690 -269 1019 -1369 -220 507 79 -1837 -412 1 709 1397 132 -1963 -477 SS 20200219T103105.1Z 7354.438254 289 1 50.22 2 78.85 96.23 33.56 79.78 0.00 1 0.00 1 0 17 3.258e-01 1.030e-02 2.171e-01 7.256e-03 5.184794e-01 3.796026e-03 5.402228e-03 -6.000000e+00 1.837411e-01 229.35 -2.00 3.16 -2.00 321.00 0.00e+00 9.731599e-04 1.673065e-03 1.808253e-03 -6.000000e+00 8.303253e-03 288.79 -2.00 20.00 -2.00 320.30 0.00e+00 4.986 0.001 302.00 328.00 3 2.6590e+00 1.2768e-02 5.5888e-02 -6.0000e+00 4.5739e-01 8.8639e-02 1.6506e-02 2.7481e-02 -6.0000e+00 4.9634e-01 -1.1357e-01 1.4636e-02 1.3006e-02 -6.0000e+00 2.9629e-01 4.0128e-02 7.1693e-03 3.4730e-03 -6.0000e+00 1.2645e-01 1.5506e-04 -2.4623e-04 2.1403e-04 4.6810e-05 -6.0000e+00 8.4938e-03 2.0695e-02 -1.7223e-04 12 8 8 10 0 0 93.86 21.86 0.88 0.02070 0.01885 39 8 1 5 0 1287.577 25.90 20.00 21.86 -62151 -139445 -100587 -108928 -74316 -125511 -33035 -45147 -115410 12869 -80306 200802 -64326 23566 -15760 -43558 18765 -37112 -21120 -30026 16451 -16920 -21106 1976 -2176 25208 -36399 24489 -24606 10248 11479 -11839 -1030 -1717 4022 -6038 475 -12135 2035 10830 -4120 6081 1125 -2405 9714 4645 5467 876 7959 10051 2601 1389 5038 8049 -2826 5487 1879 2652 -1639 -1243 3965 6397 4463 2253 2266 -86 1359 -2139 -219 1829 258 3176 1995 -550 -636 20 1091 -1813 -615 -1103 2748 -3252 -2595 -2400 -1396 967 -36 847 -380 926 1464 -912 -1703 -1835 -842 -1612 -971 288 605 -395 -523 -683 -1627 1019 -1479 -1531 -879 -1193 -257 792 1031 225 355 533 -105 81 1172 541 -284 114 -563 -644 169 611 1340 611 614 -837 562 -93 523 620 -632 215 -179 -222 -716 536 457 -255 258 -810 133 -167 -640 -3409 -1683 -1822 -813 -2342 -276 -494 -2822 91 -1498 1421 -1449 273 -324 -1345 338 -1266 -652 -1063 370 -533 -733 60 -74 749 -1803 693 -1115 348 447 -679 -60 -103 216 -359 30 -1039 186 1065 -522 740 150 -337 1217 621 731 125 1082 1408 431 258 984 1641 -676 1258 460 644 -405 -301 937 1612 1289 738 776 -29 432 -707 -78 731 116 1468 935 -253 -272 8 376 -626 -225 -472 1319 -1885 -1644 -1612 -988 717 -28 697 -319 751 1113 -658 -1154 -1218 -593 -1297 -889 296 689 -471 -600 -715 -1559 927 -1469 -1642 -985 -1414 -323 1078 1545 365 587 855 -160 115 1602 762 -428 182 -941 -1067 268 936 1968 870 835 -1120 782 -146 905 1150 -1238 435 -386 -513 -1740 1318 1143 -642 624 -1873 288 -357 SS 20200219T103333.1Z 7354.439966 291 1 50.21 2 78.34 95.89 33.07 79.30 0.00 1 0.00 1 0 25 2.310e-01 8.911e-03 2.219e-01 6.463e-03 4.981649e-01 3.333189e-03 5.210897e-03 -6.000000e+00 1.302393e-01 229.35 -2.00 3.16 -2.00 320.77 0.00e+00 1.225100e-03 1.410509e-03 1.349696e-03 -6.000000e+00 5.990345e-03 288.79 -2.00 20.00 -2.00 320.05 0.00e+00 4.787 0.001 302.00 328.00 3 2.8675e+00 1.0865e-02 5.3361e-02 -6.0000e+00 3.2410e-01 3.6749e-02 1.4064e-02 2.5305e-02 -6.0000e+00 3.5177e-01 -3.7027e-02 1.2571e-02 1.2312e-02 -6.0000e+00 2.0998e-01 7.2633e-03 6.1915e-03 3.3368e-03 -6.0000e+00 8.9728e-02 1.5592e-04 -5.2319e-04 1.8711e-04 4.3526e-05 -6.0000e+00 6.1130e-03 2.2381e-02 -2.3855e-04 11 8 0 10 0 0 98.99 21.87 0.52 0.02238 0.01845 23 5 1 5 0 2174.254 26.00 20.00 21.87 -52381 -136969 -86276 900000 659 113291 -63734 89941 -9498 -23255 -13515 -59606 16021 -77717 -7758 -27328 -30774 650 -30268 39327 -3676 1055 -20374 -9479 -7754 -12140 -19604 -18587 6110 -24574 3380 -502 18757 21614 -6973 1626 -17215 -1673 -5916 -387 -3529 -3992 -750 -1451 9447 -4368 -674 6764 430 483 5631 2148 1222 -1942 831 3907 3673 2448 6288 -3149 -1206 1628 4044 -385 3110 4731 1201 763 -218 2918 1323 1188 1543 1633 -66 520 -418 -731 1900 743 -268 367 -2937 -535 -2437 -1035 -662 -517 441 220 1820 114 244 -312 -549 -1201 -329 1174 -390 -684 -1242 -1091 -1149 245 18 -1671 -601 -1573 -460 -128 1117 360 528 1245 -182 425 -377 275 886 -459 127 -781 539 -313 522 569 160 1081 893 -264 -29 169 -90 177 671 -196 97 -476 -90 -343 -374 148 -31 10 -480 -3218 -1236 900000 4 714 -730 567 -82 -240 -132 -1059 165 -2538 -151 -736 -935 17 -1058 793 -116 32 -809 -370 -323 -551 -951 -855 216 -1255 151 -27 946 1090 -444 95 -1367 -138 -626 -46 -476 -576 -109 -217 1280 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